File name: Pandora183s1_LondonderryNH_20240721_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240722T050109.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240721_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240721 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240721T101155.2Z 8968.424945 203 1 50.41 2 83.30 68.40 100.21 244.36 0.00 1 0.00 1 0 25 4.638e-01 4.036e-02 4.655e-01 3.570e-02 9.488855e-01 2.062188e-02 1.073748e-02 -6.000000e+00 2.771086e-01 232.78 -2.00 3.55 -2.00 322.35 0.00e+00 7.365133e-03 1.062881e-02 2.446107e-03 -6.000000e+00 1.270997e-02 287.95 -2.00 20.00 -2.00 321.84 0.00e+00 7.799 0.009 302.00 328.00 3 6.7463e-01 8.2405e-02 9.2941e-02 -6.0000e+00 6.9292e-01 1.7587e+00 9.8373e-02 5.0612e-02 -6.0000e+00 7.5071e-01 -2.1439e+00 5.5864e-02 2.5121e-02 -6.0000e+00 4.4862e-01 8.1905e-01 3.0222e-02 8.3017e-03 -6.0000e+00 1.8754e-01 3.7917e-05 -1.7872e-03 9.4316e-04 1.4497e-04 -6.0000e+00 1.2454e-02 3.8732e-03 -5.3250e-05 12 8 8 10 0 0 33.96 22.96 0.58 0.00387 -0.00956 28 6 1 5 0 1800.000 26.62 20.00 22.96 23.97 30.9 1006.44 93950 70900 78653 43827 104419 -80074 20827 -46348 -21034 -31283 39689 75102 -57587 12553 7749 90469 56222 29709 42528 900000 900000 16328 173180 -54339 43044 122923 900000 76235 11028 -6776 -71280 10631 114174 26502 7302 -48138 -1186 81585 36365 -11618 40973 900000 152997 67893 744 130232 -12728 900000 23311 -9692 83311 80252 113867 58155 900000 8335 57034 3134 44753 110921 17392 900000 -14701 13478 -10821 62631 72665 64648 48274 58633 43471 15133 23158 841 18464 -8941 -15082 43260 5279 30822 14303 16824 4447 8094 -8979 4472 20374 -6394 14709 781 -5615 5653 -5726 -14648 -20186 1183 -9749 5860 -3954 190 -8581 -6013 -199 -5968 6782 -10855 -8437 -1159 7697 1669 450 4162 -2179 2887 -4295 51 -600 879 -801 -524 -1290 1002 9107 -610 -680 4431 3554 1139 975 -300 -2378 3122 -1561 1247 -1427 -429 -680 2273 1329 642 847 -2751 -2730 3518 3603 3576 2461 3630 -9851 835 -3471 -1181 -1841 1380 2611 -4774 638 497 3145 2706 2066 2587 900000 900000 993 6021 -5982 1746 4274 900000 2650 447 -334 -7847 616 3969 1536 465 -4742 -72 2836 1896 -1111 2493 900000 5319 3433 71 4528 -1328 900000 1768 -1072 3950 4312 4678 4411 900000 1080 4506 406 3536 4207 1649 900000 -2323 1832 -2018 5543 5742 5721 5493 6857 6457 3061 4172 173 2801 -1554 -2574 4239 868 4773 3119 4147 1377 2558 -3547 1626 6568 -2748 5067 296 -2112 1787 -1991 -5926 -10017 569 -6224 3760 -3124 146 -6780 -4515 -125 -3901 4173 -8453 -6805 -947 6502 1747 549 5368 -3098 3874 -5987 66 -799 1216 -1194 -801 -1933 1386 11113 -797 -863 5192 4115 1453 1467 -536 -4904 6653 -3744 3139 -3975 -1244 -2007 6574 3835 1763 2134 -6608 -6283 SS 20240721T102317.0Z 8968.432835 206 1 49.72 2 81.36 70.23 102.00 246.09 0.00 1 0.00 1 0 17 5.864e-01 1.491e-02 3.656e-01 8.776e-03 8.267684e-01 5.011225e-03 9.157586e-03 -6.000000e+00 3.384904e-01 232.78 -2.00 3.55 -2.00 322.16 0.00e+00 1.973036e-03 3.177477e-03 2.729582e-03 -6.000000e+00 1.582733e-02 287.95 -2.00 20.00 -2.00 321.66 0.00e+00 6.272 0.005 302.00 328.00 3 7.8338e-01 2.1343e-02 7.8433e-02 -6.0000e+00 8.5043e-01 4.6972e-01 3.1891e-02 4.9618e-02 -6.0000e+00 9.2028e-01 -6.7985e-01 3.1202e-02 2.6333e-02 -6.0000e+00 5.4760e-01 2.7016e-01 1.3786e-02 8.0818e-03 -6.0000e+00 2.3221e-01 2.1431e-04 -6.8971e-04 2.4305e-04 1.2012e-04 -6.0000e+00 1.5636e-02 1.6351e-03 2.8681e-05 12 8 8 10 0 0 31.56 22.92 0.49 0.00164 -0.00355 77 16 1 5 0 645.560 26.51 20.00 22.92 24.95 30.8 1013.82 -114732 900000 90822 89071 -216984 -263735 -210551 -96074 -194829 -117765 900000 -203341 -176781 -154455 8855 -48099 14165 -114368 -43100 -88868 -53817 -65814 -73291 -56557 -105673 -11584 -42139 -31328 -54364 8091 -42662 -64587 81357 -5759 -15660 -35452 11106 -5085 47247 58399 16822 41336 -13666 42823 623 113459 54091 63640 29871 -10431 63440 21248 16089 5408 34441 23480 1493 28374 4738 14672 7623 24292 10133 16208 18814 1350 3545 801 13169 12113 17168 7739 7645 1836 -2783 3030 -410 -4260 344 2599 732 -1064 -1511 506 -540 -2022 3677 2690 4677 3808 286 -4658 -2306 -1043 -4274 -1507 194 631 -1430 -1401 -925 -860 -3279 -2032 -3874 -2395 -1645 275 -1742 -123 891 218 393 -1029 4 -1338 967 -490 653 -241 679 819 1901 767 345 642 1117 1305 490 172 -17 53 17 -324 -130 -293 557 648 -108 258 -301 -496 -1173 -982 900000 777 762 -2713 -4860 -2552 -822 -2500 -1007 900000 -3479 -2899 -2643 76 -446 121 -2609 -522 -1774 -767 -1032 -1254 -887 -2938 -132 -661 -463 -972 82 -863 -2009 696 -130 -378 -993 207 -131 882 1181 589 1222 -733 1332 30 1765 1557 1732 1208 -681 2220 1289 1139 467 2384 1899 156 2251 457 1232 694 2040 1127 1954 2400 205 524 127 2048 2214 3325 1727 1689 403 -636 581 -76 -838 74 658 225 -388 -617 216 -249 -1007 1818 1383 2353 1864 135 -2184 -1030 -484 -2344 -952 142 535 -1372 -1360 -839 -697 -2452 -1491 -3115 -2014 -1453 258 -1859 -148 1205 321 589 -1534 6 -1852 1324 -716 1000 -384 1053 1207 2661 1053 459 824 1391 1726 755 307 -34 114 38 -800 -344 -818 1570 1848 -308 699 -760 -1167 -2689 SS 20240721T103743.1Z 8968.442860 211 1 49.68 2 78.85 72.54 104.31 248.26 0.00 1 0.00 1 0 25 5.464e-01 8.461e-03 1.625e-01 2.772e-03 6.871746e-01 1.506642e-03 8.211885e-03 -6.000000e+00 3.153657e-01 232.78 -2.00 3.55 -2.00 321.53 0.00e+00 3.399342e-03 8.196055e-04 5.413137e-03 -6.000000e+00 1.397277e-02 287.95 -2.00 20.00 -2.00 320.93 0.00e+00 4.988 0.002 302.00 328.00 3 5.3611e-01 5.6008e-03 6.7429e-02 -6.0000e+00 7.9189e-01 8.4744e-02 8.0605e-03 5.1118e-02 -6.0000e+00 8.5658e-01 -1.2000e-01 8.1971e-03 2.4377e-02 -6.0000e+00 5.0986e-01 3.5796e-02 3.7889e-03 6.0212e-03 -6.0000e+00 2.1455e-01 1.0822e-03 -3.7064e-04 7.7326e-05 1.2286e-04 -6.0000e+00 1.4435e-02 1.1176e-03 2.5077e-05 11 8 0 10 0 0 15.92 22.93 0.33 0.00112 -0.00167 197 41 1 5 0 252.020 26.51 20.01 22.93 26.59 31.0 1025.45 -232910 -163085 -138147 -207884 -186148 -196716 -187573 -88652 -163325 -150005 -141213 -134324 -132849 -105176 -2335 -47318 -34899 -40074 -63526 -51709 -36684 -51631 -40089 -31017 -44739 -18329 -46044 -14607 -54216 -18593 -34911 -31665 -12643 -3776 -22783 -17606 -19523 -10013 -5144 3257 -2883 3481 6940 1309 3856 -1572 -5628 6277 3507 -569 -1686 4499 845 4787 2141 1780 2407 4280 2141 1114 4323 3768 5117 6070 3966 3054 2806 625 2565 1198 2783 3054 1120 1976 540 -100 -1027 -4605 -871 -2727 -599 -53 -1769 -1301 -591 -394 368 1296 1370 1464 413 542 -1853 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