File name: Pandora183s1_LondonderryNH_20240722_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240723T050001.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240722_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240722 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240722T101237.5Z 8969.425434 198 1 49.82 2 83.33 68.65 88.36 238.21 0.00 1 0.00 1 0 25 5.942e-01 4.464e-02 5.184e-01 4.037e-02 8.743136e-01 2.343798e-02 1.085008e-02 -6.000000e+00 3.501663e-01 232.75 -2.00 3.55 -2.00 322.31 0.00e+00 1.801556e-02 1.288022e-02 4.916811e-03 -6.000000e+00 1.754090e-02 287.97 -2.00 20.00 -2.00 321.79 0.00e+00 7.822 0.009 302.00 328.00 3 8.2410e-01 9.5733e-02 9.1587e-02 -6.0000e+00 8.8167e-01 1.5482e+00 1.1434e-01 4.7628e-02 -6.0000e+00 9.5939e-01 -1.8006e+00 7.2012e-02 2.4959e-02 -6.0000e+00 5.6673e-01 6.6963e-01 3.7763e-02 1.3795e-02 -6.0000e+00 2.3855e-01 3.4272e-05 -1.2735e-03 1.1232e-03 3.0095e-04 -6.0000e+00 1.6775e-02 1.6977e-03 4.5881e-05 12 8 8 10 0 0 1.99 22.97 0.59 0.00170 -0.00787 26 5 1 5 0 1915.830 26.62 19.99 22.97 21.34 30.4 987.49 900000 45163 8900 12747 900000 -48280 -55597 -63796 -56530 -19666 900000 53970 900000 -15385 126554 -63776 900000 3365 -9111 -58309 111649 49115 159542 900000 9062 900000 175804 -79890 900000 45019 900000 900000 131867 58486 900000 -74091 208180 -3589 33830 79009 27230 111300 126651 51111 56957 211218 -30539 30152 149078 76479 -8585 -2187 287896 53409 65398 20989 79435 -2707 -17059 -42171 -23662 15856 16730 73742 107144 42838 21196 40270 54521 13845 -5096 33245 14886 9855 -7397 7064 -832 24609 -17282 -6921 55048 37787 7816 409 -188 8984 336 -3114 14104 -8315 246 -15387 10492 -349 -9667 13034 -9735 3144 -1899 9189 -15912 -4423 3884 203 -3566 -8107 -1667 -564 3894 -2213 447 139 1628 -4295 -2522 -1510 8450 -2333 -4231 3022 5456 -1653 6343 -1144 -2882 8000 1638 3818 -1633 1535 -577 -1162 -288 857 -890 -42 1145 -493 1385 770 978 -1399 -3444 900000 1774 430 539 900000 -2480 -2688 -3085 -2392 -773 900000 2120 900000 -604 4972 -6168 900000 193 -606 -6167 4386 1930 6268 900000 356 900000 6907 -6277 900000 1769 900000 900000 5181 2298 900000 -8247 8179 -211 1551 3104 1605 4373 4976 2510 2848 8298 -3708 2046 5857 3551 -1012 -266 11311 4197 4671 2324 4823 -358 -2437 -7380 -3465 1699 2032 5794 6505 4896 2952 4746 6036 2621 -1274 5818 3031 1936 -1532 1110 -131 3076 -3765 -1656 8454 7962 2457 146 -71 3273 139 -1368 5188 -3682 93 -6375 3260 -127 -4454 5726 -6397 2134 -1512 6663 -13924 -3064 2205 129 -2522 -6370 -1304 -474 3518 -2460 554 188 2226 -6142 -3409 -1963 10125 -3290 -6465 4441 7652 -2365 8025 -1515 -3759 9083 1937 4725 -2496 2647 -1142 -2515 -660 2091 -2377 -118 3211 -1424 3895 2071 2431 -3297 -7970 SS 20240722T102356.0Z 8969.433287 201 1 49.91 2 81.39 70.48 90.04 240.12 0.00 1 0.00 1 0 25 5.320e-01 1.858e-02 3.416e-01 9.018e-03 8.021243e-01 5.098231e-03 8.986398e-03 -6.000000e+00 3.071748e-01 232.74 -2.00 3.55 -2.00 322.09 0.00e+00 -3.504792e-03 3.175424e-03 7.798257e-03 -6.000000e+00 1.383819e-02 287.97 -2.00 20.00 -2.00 321.57 0.00e+00 6.291 0.005 302.00 328.00 3 8.2119e-01 2.1397e-02 8.9669e-02 -6.0000e+00 7.7095e-01 4.9928e-01 3.1034e-02 7.8242e-02 -6.0000e+00 8.3404e-01 -7.2375e-01 2.8870e-02 3.1460e-02 -6.0000e+00 4.9640e-01 2.8648e-01 1.2815e-02 7.4753e-03 -6.0000e+00 2.0907e-01 2.1070e-04 -3.2437e-04 2.5094e-04 1.1037e-04 -6.0000e+00 1.4297e-02 1.8712e-03 6.9870e-06 12 8 8 10 0 0 10.51 22.97 0.40 0.00187 -0.00057 77 16 1 5 0 648.040 26.62 20.00 22.97 21.96 30.4 992.07 -84818 -233078 -139426 -136011 900000 -53043 -126620 -68585 -204318 148048 -187972 -162086 -161183 -81782 -54387 32686 -11688 -68921 106474 -58757 -41710 -34954 -54000 -44044 -54698 -27937 -37904 10029 -62645 -129184 -55445 -36530 -9654 -27307 31417 -28587 37732 13551 37899 48598 51112 81275 56967 14595 14847 46947 22433 25311 43135 11704 59468 15995 35214 25721 39038 30272 20254 17597 18849 28584 9546 26590 4185 23766 25416 8680 10029 1715 5432 2369 8756 8688 15223 7017 -130 6966 -5467 -5218 -4628 3035 5263 489 724 -824 1983 -1530 3462 24 1596 1245 1203 -981 -3906 -1411 -6259 1055 -3772 790 -1485 -1717 -1652 -2682 -2383 -2095 -1042 -5113 159 -1837 -89 -60 -140 574 -315 35 -2290 -1338 646 219 1478 809 1629 1497 2727 769 854 -42 1302 1498 188 -41 -851 -706 93 -131 20 200 640 600 647 -427 -323 -1273 -963 -746 -5675 -1415 -1288 900000 -466 -1113 -603 -4641 1302 -4132 -2969 -3543 -1019 -638 287 -120 -1363 936 -1162 -703 -538 -1029 -839 -1283 -532 -805 136 -1515 -6815 -1640 -1080 -255 -939 578 -914 664 357 969 1360 1593 2014 1867 735 736 1689 1040 1173 1758 702 2472 1163 2336 2056 2933 2613 2007 1786 1808 2376 961 2444 549 2926 3312 1325 1499 291 986 515 1988 2069 3358 1576 -31 1384 -1144 -1110 -1107 809 1629 184 302 -373 933 -795 1799 13 866 652 589 -462 -1848 -684 -3632 670 -2945 683 -1448 -1694 -1528 -2243 -1800 -1579 -837 -4541 142 -1804 -95 -74 -194 851 -479 53 -3329 -1862 891 320 2255 1285 2519 2211 3826 1068 1144 -55 1634 1997 293 -74 -1709 -1524 211 -321 52 553 1793 1704 1824 -1157 -815 -3017 -2206 SS 20240722T103831.4Z 8969.443419 206 1 49.64 2 78.85 72.82 92.26 242.54 0.00 1 0.00 1 0 17 4.528e-01 9.607e-03 1.748e-01 2.707e-03 6.561450e-01 1.468080e-03 7.948894e-03 -6.000000e+00 2.613325e-01 232.74 -2.00 3.55 -2.00 321.44 0.00e+00 3.254927e-03 7.732945e-04 5.538048e-03 -6.000000e+00 1.171674e-02 287.97 -2.00 20.00 -2.00 320.83 0.00e+00 4.987 0.002 302.00 328.00 3 5.2947e-01 5.3551e-03 6.6705e-02 -6.0000e+00 6.5616e-01 9.1952e-02 7.5349e-03 5.0554e-02 -6.0000e+00 7.0977e-01 -1.3550e-01 7.4750e-03 2.3382e-02 -6.0000e+00 4.2276e-01 4.2671e-02 3.4863e-03 5.5155e-03 -6.0000e+00 1.7856e-01 1.1331e-03 -3.6092e-04 7.6631e-05 1.1674e-04 -6.0000e+00 1.1967e-02 1.4228e-03 3.2331e-05 12 8 8 10 0 0 6.73 22.98 0.30 0.00142 -0.00129 206 43 1 5 0 240.950 26.62 20.00 22.98 23.97 30.9 1006.49 -49497 -183089 900000 -230112 -69226 -184049 -134134 -105270 -175022 -31998 -158124 -75840 -127013 -57937 -93062 -63863 -34452 -54709 1663 -65708 -14442 -78848 -5634 -38810 -16361 -23384 -54151 -19397 -44913 -1130 -18712 -9311 -8954 -17442 -9555 -21495 5249 -14262 6866 -13879 11361 -1986 -690 2113 -5575 12145 -7015 8549 -667 8921 2371 5449 6801 3178 8589 359 7840 2865 2753 4304 -3515 5592 2455 7661 2818 3222 1610 336 1673 2994 4974 989 3235 450 2366 -1202 -3640 -2574 -1163 -1422 -1060 83 -2451 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