File name: Pandora183s1_LondonderryNH_20240801_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240802T045959.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240801_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240801 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240801T102246.2Z 8979.432479 164 1 50.15 2 83.12 72.02 50.12 86.54 0.00 1 0.00 1 0 17 5.561e-01 2.763e-02 4.713e-01 2.243e-02 8.661182e-01 1.295092e-02 9.483827e-03 -6.000000e+00 3.248609e-01 232.37 -2.00 3.55 -2.00 322.39 0.00e+00 -1.945102e-03 7.796342e-03 4.480103e-03 -6.000000e+00 1.477165e-02 288.18 -2.00 20.00 -2.00 321.91 0.00e+00 7.624 0.008 302.00 328.00 3 6.1181e-01 5.4700e-02 9.3403e-02 -6.0000e+00 8.1590e-01 1.0985e+00 7.3248e-02 6.1443e-02 -6.0000e+00 8.8483e-01 -1.5494e+00 5.5055e-02 2.8279e-02 -6.0000e+00 5.2273e-01 6.1788e-01 2.5227e-02 7.3699e-03 -6.0000e+00 2.1897e-01 6.6217e-05 -4.8755e-04 6.2719e-04 9.9916e-05 -6.0000e+00 1.5096e-02 1.6110e-03 -1.9694e-06 12 9 8 11 8 0 -18.34 22.83 0.60 0.00161 -0.00205 42 9 1 5 0 1193.740 26.41 20.00 22.83 28.94 31.3 1035.63 -20291 66043 -26234 900000 35402 900000 -73027 900000 70118 2898 -167298 -92985 -95269 37513 83583 -12804 -34388 -45903 11978 -45748 122184 -13625 64585 900000 -54259 283552 170157 30824 4472 4725 80630 35471 900000 240895 13898 -18924 -32068 -15414 108583 45221 41669 55240 11112 164263 25485 16132 74551 9741 16575 19004 28629 99598 22385 55335 -154 18287 69293 199324 13882 36338 46774 28818 31941 11166 41236 21773 51779 7920 49072 9577 10803 15645 28032 12363 11725 15133 -13175 4434 2131 10942 17305 616 11320 2288 1091 4962 -4459 3395 5342 8227 3605 -4890 -6740 -1939 -6242 -1182 -1517 -7822 -4159 -4289 -658 -4295 -4077 -6308 253 -2376 -6256 767 -3187 -162 1537 -422 1207 551 160 -1997 869 -704 1275 -537 623 2888 1432 166 -1046 5983 1324 1765 2822 -37 -157 -542 105 -750 -543 -201 2279 794 74 -431 -609 -1389 -1448 -443 1443 -661 900000 774 900000 -1841 900000 1532 63 -12093 -3282 -4004 820 1827 -420 -1503 -2341 349 -2333 2670 -447 1411 900000 -2866 6196 3718 674 106 112 1762 840 900000 5264 456 -793 -1577 -796 2373 1797 1904 2305 729 3590 1367 929 2370 600 988 1170 1763 3364 1779 3408 -17 1780 4130 4356 1324 2599 2974 2347 2855 1398 4096 2595 4526 1117 5069 1693 2082 2984 4622 2210 1887 2074 -2225 643 360 2043 3610 176 3238 764 392 1824 -1887 1362 2091 3308 1418 -1977 -2725 -792 -3069 -656 -998 -6393 -3636 -3805 -530 -3200 -2735 -4315 175 -1791 -5208 647 -3141 -179 1907 -581 1680 762 214 -2654 1141 -990 1869 -829 930 4014 1943 222 -1374 7113 1615 2299 4242 -66 -316 -1188 245 -1899 -1481 -575 6475 2318 216 -1198 -1569 -3344 -3373 SS 20240801T103406.0Z 8979.440347 167 1 49.77 2 81.13 73.87 48.10 88.31 0.00 1 0.00 1 0 17 5.969e-01 1.431e-02 3.164e-01 6.529e-03 7.509011e-01 3.668929e-03 8.873738e-03 -6.000000e+00 3.440617e-01 232.37 -2.00 3.55 -2.00 322.00 0.00e+00 4.427625e-03 2.234468e-03 7.024857e-03 -6.000000e+00 1.557347e-02 288.18 -2.00 20.00 -2.00 321.46 0.00e+00 6.132 0.004 302.00 328.00 3 6.0728e-01 1.5078e-02 8.1580e-02 -6.0000e+00 8.6304e-01 3.4409e-01 2.2138e-02 6.2374e-02 -6.0000e+00 9.3382e-01 -5.0339e-01 2.1484e-02 2.9807e-02 -6.0000e+00 5.5609e-01 1.9724e-01 9.6009e-03 7.2422e-03 -6.0000e+00 2.3456e-01 3.2197e-04 -4.4467e-04 1.8543e-04 1.5606e-04 -6.0000e+00 1.5786e-02 5.5763e-04 3.0046e-05 12 8 8 10 0 0 42.10 22.84 0.41 0.00056 -0.00278 98 20 1 5 0 507.820 26.41 20.06 22.84 29.91 31.3 1041.76 -131028 -111867 -176912 -162183 -244868 -190843 -214042 -118128 -236375 -149025 -127340 -203534 900000 -150927 -3375 -107978 -68072 -99436 50208 -44213 -30190 77844 -56456 30176 -85765 -7390 -41739 27760 -64218 -32186 77571 -42450 23264 -48705 30095 -23438 -15038 -3500 18682 29632 5317 5505 4844 45968 940 18950 8682 13591 26894 18499 25398 22377 12556 13456 25894 19837 15352 4407 4561 20135 -26 11100 12174 12946 17052 2174 14241 1758 9014 2695 10226 3768 6781 6024 1811 2183 -2461 -3163 -4854 660 -2579 2109 -258 732 2233 -2489 2153 535 1128 1759 1599 -3818 -3614 -3562 -3156 -298 -1151 253 141 -2057 -1161 -3027 -1121 -3449 -1126 -1987 -1545 -1332 -349 622 -41 255 127 -40 -723 179 158 -393 375 515 938 1264 2201 1086 782 -242 -150 1607 -547 461 -40 -232 -164 -29 34 -305 610 347 22 -167 -159 -638 -636 -834 -712 -1819 -1430 -4807 -2025 -2952 -752 -5016 -1423 -1013 -3779 900000 -2722 -21 -2005 -975 -2163 320 -633 -384 496 -928 224 -2184 -98 -797 257 -1449 -559 539 -1204 404 -1917 523 -665 -418 -101 530 909 237 264 247 1596 52 888 462 716 1307 1049 1499 1541 1054 1223 2218 1883 1573 502 502 1841 -3 1240 1543 1866 2546 374 2143 310 1796 604 2367 977 1861 1569 447 479 -526 -693 -1221 189 -906 818 -114 340 1092 -1363 1186 309 648 970 826 -1952 -1783 -1828 -1830 -198 -902 227 139 -2103 -1105 -2631 -866 -2727 -938 -1772 -1451 -1346 -387 778 -58 385 195 -59 -1038 245 219 -578 580 827 1477 1901 3156 1525 1062 -321 -193 2149 -857 817 -80 -492 -370 -70 87 -832 1681 974 60 -449 -399 -1503 -1452 SS 20240801T104709.0Z 8979.449410 172 1 49.70 2 78.83 75.98 45.78 90.43 0.00 1 0.00 1 0 17 4.210e-01 7.413e-03 1.312e-01 2.392e-03 6.398553e-01 1.288553e-03 7.518749e-03 -6.000000e+00 2.426782e-01 232.37 -2.00 3.55 -2.00 321.38 0.00e+00 2.586767e-03 6.686529e-04 3.903552e-03 -6.000000e+00 1.077819e-02 288.18 -2.00 20.00 -2.00 320.76 0.00e+00 4.977 0.002 302.00 328.00 3 3.7069e-01 4.6585e-03 6.3118e-02 -6.0000e+00 6.0870e-01 6.4666e-02 6.5228e-03 4.2732e-02 -6.0000e+00 6.5859e-01 -8.9085e-02 6.4938e-03 2.0799e-02 -6.0000e+00 3.9220e-01 2.2338e-02 3.0456e-03 5.4011e-03 -6.0000e+00 1.6523e-01 1.3746e-03 -3.9616e-04 6.8106e-05 9.6459e-05 -6.0000e+00 1.1122e-02 6.1614e-04 2.8113e-05 11 8 0 10 0 0 92.40 22.91 0.34 0.00062 -0.00236 240 50 1 5 0 207.030 26.51 20.00 22.91 31.24 31.4 1050.86 -188435 -139993 -135221 -157721 -109757 -146261 -89990 -135332 -102762 -98809 -127520 -78061 -82677 -66296 -88940 -43796 -51166 -29157 -36250 -33618 -36867 -45824 -44847 -39111 -10873 -17345 -8017 -47481 -25912 -17855 -18622 -20729 -12899 -8467 -18497 -18620 -20131 -10208 2197 -1898 6836 -223 3781 5780 -2973 -2308 -1951 -754 -2324 -188 3027 2582 3988 4283 2084 3896 2001 2721 -312 -1496 962 1259 4932 3971 2689 2017 1005 376 2610 2550 2201 2223 1708 1232 -698 -574 -1712 -3596 -2192 -1680 -214 -906 -1749 -1600 -239 -14 967 732 1767 1094 845 -332 -1657 -1343 -1386 -723 86 865 198 -177 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