File name: Pandora183s1_LondonderryNH_20240802_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240803T050044.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240802_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240802 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240802T104813.5Z 8980.450156 136 1 49.03 2 78.79 76.36 56.26 82.99 0.00 1 0.00 1 0 17 5.297e-01 1.559e-02 3.082e-01 9.146e-03 6.391736e-01 5.024466e-03 7.293058e-03 -6.000000e+00 3.083126e-01 232.34 -2.00 3.55 -2.00 321.50 0.00e+00 -3.204451e-03 2.606771e-03 4.349507e-03 -6.000000e+00 1.380392e-02 288.20 -2.00 20.00 -2.00 320.89 0.00e+00 4.964 0.002 302.00 328.00 3 2.3738e+00 1.8463e-02 6.5690e-02 -6.0000e+00 7.7365e-01 1.6668e-01 2.5557e-02 5.0780e-02 -6.0000e+00 8.3836e-01 -2.6913e-01 2.3619e-02 1.9693e-02 -6.0000e+00 4.9807e-01 1.0254e-01 1.0946e-02 6.6447e-03 -6.0000e+00 2.0838e-01 1.8946e-04 -7.6178e-04 2.6719e-04 5.9968e-05 -6.0000e+00 1.4013e-02 9.1716e-04 2.4427e-05 12 8 8 10 0 0 -2.66 22.96 0.66 0.00092 -0.00481 35 7 1 5 0 1400.470 26.62 19.99 22.96 28.30 31.2 1029.16 -247085 -152599 -154949 -189345 133982 900000 -142145 -127281 55629 -145373 -136182 -120703 -111885 -90357 248211 26061 -31548 900000 45662 -22471 8435 8363 -40459 11976 97128 -34037 -70165 -61407 -41025 7260 -7524 -25937 83 2602 -36854 36643 -12960 22497 -9153 12390 7804 966 21203 20708 34754 21177 16633 -4878 -7822 12922 30336 13354 -1080 14888 14636 15151 9811 10434 6369 -9844 7743 -697 3789 15290 16737 145 372 6397 2073 2268 1119 8398 2791 2718 909 -4343 2502 -8518 -2229 -2182 2553 -2872 -4546 862 724 -590 -1031 1291 749 703 -236 -624 -205 -1355 -768 -3262 872 368 647 -1340 -1672 -2082 -1691 508 -2502 -1429 -1299 -484 -157 1082 -194 -575 -615 -491 559 -777 424 395 1004 891 1029 818 1327 1462 1164 -180 -899 1183 463 92 -45 -452 -851 -328 -730 645 454 967 -73 223 -362 -349 -1297 -6609 -1884 -2125 -3636 1195 900000 -1690 -1513 496 -2700 -2428 -1973 -1995 -1611 2213 232 -516 900000 407 -417 119 118 -962 187 866 -1012 -3076 -2588 -1330 147 -201 -988 3 95 -1942 891 -557 802 -556 743 563 81 1512 1511 2197 1545 1281 -474 -812 1152 2508 1472 -151 1943 2052 2223 1582 1683 1038 -1827 1218 -129 755 3061 3514 35 87 1447 536 678 378 2784 977 905 283 -1402 694 -2620 -707 -817 1070 -1324 -2590 495 446 -394 -730 922 538 488 -155 -382 -119 -814 -510 -2566 760 369 708 -1504 -1770 -1996 -1477 437 -2398 -1438 -1376 -544 -192 1462 -293 -926 -995 -766 813 -1097 594 581 1560 1447 1660 1276 1988 2114 1622 -245 -1188 1595 708 160 -86 -913 -1813 -740 -1772 1627 1172 2528 -193 562 -863 -784 -2862 SS 20240802T105421.2Z 8980.454412 139 1 49.66 2 77.70 77.35 55.18 83.92 0.00 1 0.00 1 0 17 4.048e-01 1.078e-02 2.228e-01 5.366e-03 5.922203e-01 2.912858e-03 7.046868e-03 -6.000000e+00 2.332928e-01 232.34 -2.00 3.55 -2.00 321.29 0.00e+00 1.306134e-03 1.441589e-03 4.466334e-03 -6.000000e+00 1.044023e-02 288.20 -2.00 20.00 -2.00 320.65 0.00e+00 4.556 0.002 302.00 328.00 3 2.1448e+00 1.0288e-02 5.9817e-02 -6.0000e+00 5.8510e-01 5.8641e-02 1.4049e-02 4.4410e-02 -6.0000e+00 6.3311e-01 -1.1351e-01 1.3411e-02 1.9549e-02 -6.0000e+00 3.7727e-01 3.8601e-02 6.3411e-03 4.6611e-03 -6.0000e+00 1.5976e-01 3.6723e-04 -2.6236e-04 1.5759e-04 7.6550e-05 -6.0000e+00 1.0706e-02 1.6911e-03 4.0278e-05 12 8 8 10 0 0 10.32 22.96 0.41 0.00169 -0.00028 54 11 1 5 0 919.410 26.62 19.99 22.96 28.69 31.2 1032.19 -160063 900000 -80674 -98499 -112819 -163705 -66114 -130032 -185128 -129661 -166673 -57080 -43051 -54383 -71104 -33027 -10895 -22248 117284 -10115 -53345 -54711 8327 3372 -16208 19194 -24193 -29980 -25653 -1777 16666 -16050 -9783 -9530 7132 -12251 -23205 -1681 2145 2674 4919 3877 -1088 -715 14743 1241 7926 3679 7178 -603 9465 562 5835 1441 2644 1860 -194 7316 -732 2194 2366 4853 5546 7492 5623 -460 1238 475 241 4841 1129 1482 -47 3641 -192 1394 -2947 -2532 -3682 -3243 -270 -1421 -742 -2018 204 691 1152 535 1534 1177 259 130 -1854 -667 -2285 -566 84 208 586 -959 -509 -2629 -479 -1714 -1909 -2085 -419 -1528 462 577 446 109 -9 258 -454 -284 591 -57 904 414 634 730 1183 654 765 -350 -214 946 249 57 -590 -487 -471 -397 -238 -222 753 1099 200 -680 94 -687 -397 -1745 900000 -528 -773 -935 -2141 -346 -1474 -4198 -1866 -3634 -448 -357 -640 -1240 -475 -143 -359 614 -183 -1548 -1614 135 63 -401 356 -714 -913 -720 -41 365 -580 -386 -413 254 -513 -1170 -81 122 184 379 326 -101 -68 1220 120 728 361 703 -67 1054 77 830 233 450 334 -37 1295 -137 390 430 1031 1203 1972 1598 -135 346 136 76 1680 453 624 -20 1427 -72 461 -937 -796 -1287 -1330 -126 -764 -435 -1273 135 487 853 412 1171 871 180 84 -1165 -420 -1622 -455 77 219 668 -1112 -551 -2624 -430 -1576 -1902 -2207 -459 -1808 583 810 690 177 -14 401 -670 -399 829 -84 1413 681 1038 1154 1797 965 1080 -480 -283 1285 382 99 -1113 -971 -982 -877 -562 -551 1898 2808 514 -1698 219 -1531 -861 SS 20240802T105958.4Z 8980.458315 142 1 49.65 2 76.69 78.26 54.18 84.77 0.00 1 0.00 1 0 17 2.751e-01 8.545e-03 2.178e-01 4.290e-03 5.604400e-01 2.295384e-03 6.841160e-03 -6.000000e+00 1.596015e-01 232.34 -2.00 3.55 -2.00 321.06 0.00e+00 2.696347e-03 1.059748e-03 4.057447e-03 -6.000000e+00 7.044466e-03 288.20 -2.00 20.00 -2.00 320.39 0.00e+00 4.236 0.001 302.00 328.00 3 2.1159e+00 7.7923e-03 5.5199e-02 -6.0000e+00 4.0076e-01 3.4275e-02 1.0465e-02 3.9912e-02 -6.0000e+00 4.3384e-01 -4.8127e-02 9.9438e-03 1.8770e-02 -6.0000e+00 2.5736e-01 6.8718e-03 4.7760e-03 4.5349e-03 -6.0000e+00 1.0800e-01 5.2107e-04 -4.5078e-04 1.2530e-04 7.9596e-05 -6.0000e+00 7.3816e-03 7.5607e-04 3.2068e-05 11 8 0 10 0 0 89.82 22.95 0.46 0.00076 -0.00263 74 15 1 5 0 670.800 26.51 20.00 22.95 29.14 31.2 1036.40 -90151 -95457 -71426 -75363 -35958 -4550 -83895 900000 -102441 118316 -131967 4382 -45542 -88966 -36750 -59080 -4997 -21003 -4301 -32212 17164 -18322 -37065 -16758 -35892 -15384 -20764 -5180 -29786 -18319 -18088 -15643 22988 -16226 -9038 -8547 1387 -4039 8257 883 -533 487 -6053 8382 -1761 -612 3174 251 -1680 -2470 7329 -3111 4617 4288 4530 1168 1241 1923 -1509 4090 -1928 272 1942 5901 2556 1840 1820 989 4235 423 3676 2466 1046 878 -1701 482 -3821 -630 -1620 -1616 -1634 -1849 -2023 -2591 1304 -607 917 1239 585 793 169 758 -1927 -909 -1220 -558 2 1114 -57 -559 -671 -2304 -1150 -1176 -1547 -1044 -617 -1006 414 654 1043 539 445 427 -570 24 71 98 448 17 612 963 864 125 -159 -162 125 312 -43 -140 -340 -1006 -487 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