File name: Pandora183s1_LondonderryNH_20240807_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240808T050244.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240807_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240807 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240807T131131.5Z 8985.549670 156 1 5.23 2 53.56 102.28 86.02 87.17 0.00 1 0.00 1 0 17 1.401e-02 8.320e-03 9.462e-03 3.951e-03 2.318491e-01 2.008946e-03 2.774843e-03 -6.000000e+00 8.068589e-03 232.15 -2.00 3.55 -2.00 316.62 0.00e+00 3.704036e-04 2.466830e-04 1.837411e-04 -6.000000e+00 3.588159e-04 288.30 -2.00 20.00 -2.00 315.82 0.00e+00 1.679 0.000 302.00 328.00 3 3.6894e+00 5.2932e-03 2.0692e-02 -6.0000e+00 2.0226e-02 2.7051e-02 5.9221e-03 1.2169e-02 -6.0000e+00 2.1886e-02 3.5882e-03 3.4310e-03 5.8706e-03 -6.0000e+00 1.3037e-02 -7.1345e-03 1.6174e-03 1.5901e-03 -6.0000e+00 5.4968e-03 1.8933e-03 -1.4227e-04 1.1096e-04 1.7715e-05 -6.0000e+00 3.7004e-04 -1.4817e-03 -1.8685e-05 12 9 1 12 1 1 89.01 22.97 0.26 -0.00148 -0.00255 3 8 1 5 0 1304.670 26.62 20.00 22.97 25.37 31.0 1006.34 -1156 1735 1006 -3993 -1840 -7314 -3731 757 1576 -378 -2635 -3410 -1889 -1928 620 -314 2373 845 1939 -396 1168 -568 1451 4083 545 843 -2307 1544 -2190 -73 1658 796 149 1540 -2285 -2296 -478 -2324 -440 -385 -148 42 -705 -728 -365 219 -950 -1094 -537 -1631 339 -123 843 1093 737 880 1261 269 -848 390 831 2469 1722 2151 556 -53 -797 -1181 1120 436 790 223 302 742 -7 -470 -1657 -2012 -1414 -1171 -2260 -1373 -2198 -871 -364 -136 883 511 1190 893 578 629 -672 398 -1163 -315 254 1091 84 -301 -275 -1202 -979 -868 -950 -1240 -610 -1072 207 810 807 1034 525 254 -316 -10 -207 -177 445 431 157 781 509 -61 734 -757 -85 820 452 10 -313 -571 -385 -180 -261 -71 515 465 870 -523 183 -725 -651 -172 282 171 -686 -274 -1054 -532 115 268 -70 -497 -641 -381 -443 158 -90 695 258 609 -132 393 -193 485 1392 185 298 -848 570 -774 -24 558 291 59 633 -922 -877 -191 -991 -222 -228 -89 26 -460 -481 -239 143 -615 -687 -355 -1082 229 -82 590 802 561 681 991 213 -667 300 651 2030 1429 1899 502 -48 -667 -951 922 378 754 224 306 724 -7 -424 -1354 -1543 -1107 -1023 -2073 -1378 -2379 -972 -401 -160 1093 657 1528 1112 669 712 -699 392 -1218 -359 297 1400 108 -384 -353 -1428 -1180 -1002 -1194 -1656 -790 -1456 291 1201 1179 1524 798 359 -439 -13 -267 -240 599 621 233 1139 724 -84 1013 -1009 -107 1020 602 14 -440 -821 -562 -273 -419 -113 832 768 1438 -856 287 -1179 -1037 SS 20240807T132930.6Z 8985.562160 165 1 18.46 2 50.37 105.97 82.86 90.19 0.00 1 0.00 1 0 17 1.513e-02 8.328e-03 7.489e-03 2.836e-03 2.151461e-01 1.438111e-03 2.604526e-03 -6.000000e+00 8.717269e-03 232.15 -2.00 3.55 -2.00 316.96 0.00e+00 7.801924e-04 1.892836e-04 2.487268e-04 -6.000000e+00 3.876338e-04 288.30 -2.00 20.00 -2.00 316.13 0.00e+00 1.565 0.000 302.00 328.00 3 4.2162e+00 3.8048e-03 1.9279e-02 -6.0000e+00 2.1852e-02 3.8751e-02 4.2601e-03 1.1345e-02 -6.0000e+00 2.3643e-02 3.3675e-03 2.4923e-03 5.4944e-03 -6.0000e+00 1.4084e-02 -7.1836e-03 1.1968e-03 1.5190e-03 -6.0000e+00 5.9401e-03 1.2796e-03 1.4158e-04 8.0723e-05 1.6229e-05 -6.0000e+00 3.9959e-04 -8.4099e-04 9.7643e-05 12 9 1 12 1 1 99.99 22.97 0.26 -0.00084 0.00022 13 8 1 5 0 1317.870 26.62 19.99 22.97 26.14 30.8 1010.36 -3268 89 -2239 -1977 1485 -9000 2654 -2604 919 -1100 -3554 823 -3185 -855 -2164 3242 -2131 1349 931 203 2676 382 2354 -1162 1435 194 307 -2202 -1704 -104 -447 1797 -158 1079 -2481 -2306 -4264 -1537 1303 -1382 670 -1007 -294 546 124 971 -670 156 -1837 -90 -638 193 360 1053 968 1174 1307 262 407 127 1344 1760 1975 3115 738 -222 -912 -870 662 1011 530 494 767 558 441 -1109 -944 -2164 -508 -1570 -1977 -763 -2616 -1467 -1002 76 30 367 1071 93 999 -927 -861 -952 -349 -476 207 759 311 -251 -475 -846 -851 -616 -967 -1291 -274 -894 303 570 1581 490 698 736 -553 214 -233 -189 223 9 61 643 897 462 547 -303 277 561 253 195 -145 -564 -378 40 -56 -46 233 764 113 -54 -232 -1137 -520 -436 13 -343 -291 186 -1145 337 -386 134 -176 -634 138 -602 -180 -524 824 -598 375 269 61 807 117 705 -376 477 68 108 -754 -535 -31 -136 574 -55 391 -879 -771 -1540 -622 614 -788 376 -602 -180 335 76 590 -406 100 -1162 -55 -408 131 234 713 676 831 941 190 290 89 960 1335 1619 2692 657 -184 -692 -693 543 849 494 483 751 531 394 -906 -757 -1639 -387 -1349 -1741 -732 -2731 -1581 -1148 92 39 447 1304 121 1190 -1022 -858 -904 -345 -516 247 995 399 -320 -621 -1019 -969 -722 -1238 -1757 -386 -1210 423 842 2429 768 1046 1021 -773 277 -302 -256 323 12 90 927 1369 678 760 -403 348 701 336 277 -216 -864 -586 64 -88 -76 391 1303 195 -92 -380 -1810 -807 SS 20240807T133756.0Z 8985.568009 168 1 1.21 2 48.89 107.79 81.37 91.61 0.00 1 0.00 1 0 17 1.572e-02 1.020e-02 1.061e-02 5.762e-03 2.105300e-01 2.959887e-03 2.566538e-03 -6.000000e+00 9.054482e-03 232.15 -2.00 3.55 -2.00 315.82 0.00e+00 7.340647e-04 3.035042e-04 1.778233e-04 -6.000000e+00 4.026605e-04 288.30 -2.00 20.00 -2.00 315.06 0.00e+00 1.518 0.000 302.00 328.00 3 2.9235e+00 7.7277e-03 1.8747e-02 -6.0000e+00 2.2697e-02 3.7012e-02 8.6043e-03 1.1062e-02 -6.0000e+00 2.4560e-02 4.3348e-03 4.9287e-03 5.3514e-03 -6.0000e+00 1.4630e-02 -1.2869e-02 2.2347e-03 1.4688e-03 -6.0000e+00 6.1686e-03 4.9300e-03 -1.8000e-04 1.6068e-04 1.7439e-05 -6.0000e+00 4.1522e-04 -9.0661e-04 2.0450e-05 12 9 9 12 1 1 999.00 22.97 0.42 -0.00091 -0.00226 1 17 1 5 0 595.770 26.62 20.00 22.97 26.77 31.1 1017.15 1193 -4810 -714 -4510 -2540 -270 1174 2446 615 -393 -1739 -2869 -3801 -314 -4669 339 -1304 897 4062 1905 2187 1143 2642 -390 2436 -604 1915 997 463 2078 2700 3963 684 225 -5540 -2115 -3058 -2547 -607 -1472 -476 -1636 -210 -916 -892 1250 -1588 -856 -432 671 -1285 899 1428 990 1839 291 2106 678 1 412 1140 1251 1623 3077 372 -504 -764 -419 509 775 -116 1635 1299 862 1565 -2231 -1469 -1467 -1191 -1163 -1417 -1750 -2709 -865 -382 -312 -464 792 -242 323 578 -908 -1063 -854 -351 -569 262 -5 426 29 -879 -1368 -510 57 -80 -2051 -490 -911 624 1191 1385 1472 50 727 54 358 173 -102 -88 357 86 513 931 129 1268 -102 364 683 -106 34 -235 -448 -193 -205 -539 323 -141 928 -477 -264 87 -924 -511 246 -1177 -174 -1097 -534 -56 244 557 146 -101 -447 -733 -1060 -96 -1696 130 -485 334 1520 752 885 463 1054 -167 1070 -284 885 441 190 873 1159 1798 316 109 -2688 -937 -1449 -1383 -357 -956 -338 -1232 -160 -712 -690 946 -1213 -628 -305 463 -936 685 1141 778 1477 241 1745 569 0 337 946 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