File name: Pandora183s1_LondonderryNH_20240827_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240828T045839.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240827_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240827 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240827T125551.0Z 9005.538785 306 1 3.27 2 59.96 105.63 23.06 235.76 0.00 1 0.00 1 0 17 1.785e-02 8.500e-03 1.597e-02 5.088e-03 2.679834e-01 2.574423e-03 3.206345e-03 -6.000000e+00 1.022548e-02 230.75 -2.00 3.55 -2.00 317.19 0.00e+00 6.062373e-04 3.628959e-04 2.245716e-04 -6.000000e+00 4.554227e-04 287.44 -2.00 20.00 -2.00 316.36 0.00e+00 1.989 0.000 302.00 328.00 3 3.3082e+00 6.8299e-03 2.4225e-02 -6.0000e+00 2.5551e-02 8.7611e-03 7.6664e-03 1.4027e-02 -6.0000e+00 2.7685e-02 1.8155e-02 4.5691e-03 6.8048e-03 -6.0000e+00 1.6502e-02 -1.1849e-02 2.2417e-03 1.8743e-03 -6.0000e+00 6.9702e-03 1.9423e-03 -1.1890e-04 1.4428e-04 2.0293e-05 -6.0000e+00 4.7127e-04 9.6730e-04 2.7975e-05 12 9 1 12 1 1 999.00 23.05 0.33 0.00097 0.00007 2 10 1 5 0 1088.440 26.73 20.00 23.05 27.11 31.5 1015.48 62 -1859 -4146 -310 -4924 -727 -10825 -2767 -2787 -3663 -6098 -1503 -421 1223 1325 1935 -187 -74 440 802 908 1618 3267 -359 -289 3100 -1191 -1168 -1187 -3834 2379 2381 1660 -2137 -2356 -3798 -3255 2165 -1768 -463 -1294 -693 122 238 514 -743 -1415 -846 -2193 -648 417 2102 763 1892 2959 909 137 97 0 1288 1786 1732 1343 2430 663 -484 -557 -1891 320 1112 115 1055 820 1375 24 -932 -533 -1586 -770 -935 -1253 -1575 -2105 -2042 -1116 -839 -442 204 1129 669 789 138 -753 -387 -725 145 1125 -34 137 -52 -303 -769 -1181 -1143 -769 -973 -948 189 -99 167 1483 464 399 496 -256 -544 162 302 634 150 31 920 680 173 486 289 -360 668 183 627 -360 -407 -213 314 227 -291 179 558 -171 -610 -109 -37 -1012 6 -215 -514 -36 -530 -69 -1176 -310 -354 -505 -862 -203 -62 205 256 418 -44 -18 111 209 244 430 859 -103 -88 957 -388 -363 -342 -1098 671 731 560 -718 -828 -1287 -1169 776 -795 -243 -698 -392 71 140 301 -441 -834 -484 -1246 -362 242 1290 504 1305 2093 671 104 74 0 938 1326 1377 1079 2076 583 -400 -424 -1524 265 960 111 982 768 1334 22 -778 -431 -1223 -609 -771 -1170 -1519 -2187 -2220 -1285 -967 -537 255 1402 807 881 151 -760 -404 -743 163 1299 -45 178 -67 -389 -909 -1416 -1412 -960 -1290 -1315 254 -140 252 2198 705 584 717 -341 -729 215 417 880 223 47 1373 989 243 687 390 -463 857 253 868 -530 -615 -327 500 362 -489 307 975 -302 -1057 -182 -58 -1597 SS 20240827T130536.1Z 9005.545557 312 1 12.88 2 58.25 107.60 24.53 239.49 0.00 1 0.00 1 0 17 1.560e-02 7.633e-03 9.665e-03 2.698e-03 2.616086e-01 1.361079e-03 3.117262e-03 -6.000000e+00 8.945331e-03 230.75 -2.00 3.55 -2.00 317.56 0.00e+00 8.634164e-04 2.107020e-04 3.374442e-04 -6.000000e+00 3.983127e-04 287.44 -2.00 20.00 -2.00 316.73 0.00e+00 1.893 0.000 302.00 328.00 3 3.5549e+00 3.6316e-03 2.3253e-02 -6.0000e+00 2.2353e-02 3.1132e-02 4.0989e-03 1.3651e-02 -6.0000e+00 2.4213e-02 6.6655e-03 2.4728e-03 6.6498e-03 -6.0000e+00 1.4433e-02 -9.8805e-03 1.2264e-03 1.8746e-03 -6.0000e+00 6.1010e-03 1.6689e-03 5.9905e-04 7.6780e-05 1.9272e-05 -6.0000e+00 4.1192e-04 -2.9114e-04 1.7667e-04 12 9 1 12 1 1 99.97 23.04 0.19 -0.00029 0.00421 13 11 1 5 0 919.020 26.73 19.99 23.04 27.66 31.5 1019.55 1165 -712 284 242 -8068 -4236 -221 4553 -3329 965 -6400 -3078 -1150 -2461 1376 761 -2806 -342 307 1326 185 138 -105 2486 -126 707 1523 -1485 -171 -3196 734 1279 2681 -1267 -3754 -2340 -3310 -1412 -1118 -460 -1117 -862 -93 -436 199 308 -863 -973 -760 -372 890 1103 807 928 626 706 1053 393 -162 667 1000 2141 2128 2255 1258 -27 -517 -681 666 1113 306 1029 380 1533 876 -89 -651 -2596 -1317 -1684 -2034 -1672 -1978 -1048 -700 -833 -101 115 682 362 559 -80 -867 -420 -371 -719 388 987 194 -274 -463 -1451 -749 -382 -1133 -1072 -551 -438 219 493 933 534 253 556 -237 -436 150 -88 604 260 348 522 611 121 722 62 -374 820 428 327 35 -533 -343 -163 44 -212 420 704 293 -293 -239 -831 -787 97 -68 28 23 -751 -383 -20 431 -385 115 -820 -380 -153 -383 238 148 -600 -74 69 305 45 33 -25 610 -34 196 422 -405 -43 -792 183 344 775 -401 -1156 -674 -1023 -495 -470 -207 -560 -454 -50 -240 109 168 -469 -516 -394 -191 472 628 489 593 415 477 724 272 -111 445 682 1543 1672 1898 1083 -22 -386 -490 496 937 287 922 344 1447 779 -72 -474 -1813 -938 -1354 -1852 -1679 -1957 -1075 -764 -979 -124 147 868 447 638 -84 -906 -420 -391 -769 456 1281 250 -379 -602 -1746 -842 -442 -1434 -1437 -767 -589 307 735 1462 852 390 794 -338 -585 199 -122 897 382 522 771 877 181 1020 84 -482 1049 589 483 51 -790 -516 -255 74 -370 750 1279 537 -527 -414 -1391 -1292 SS 20240827T130947.6Z 9005.548468 315 1 50.66 2 57.52 108.46 25.17 240.99 0.00 1 0.00 1 0 17 1.289e-02 7.126e-03 7.674e-04 2.155e-04 2.561729e-01 1.085427e-04 3.087087e-03 -6.000000e+00 7.384048e-03 230.75 -2.00 3.55 -2.00 317.61 0.00e+00 7.383687e-04 1.691784e-05 3.694622e-04 -6.000000e+00 3.288585e-04 287.44 -2.00 20.00 -2.00 316.77 0.00e+00 1.855 0.000 302.00 328.00 3 -5.0994e-02 2.8952e-04 2.2826e-02 -6.0000e+00 1.8451e-02 3.8017e-03 3.2662e-04 1.3460e-02 -6.0000e+00 1.9990e-02 3.6327e-03 1.9783e-04 6.5495e-03 -6.0000e+00 1.1916e-02 -7.3653e-03 9.8407e-05 1.8105e-03 -6.0000e+00 5.0340e-03 6.5261e-02 3.5156e-05 6.1935e-06 1.9004e-05 -6.0000e+00 3.4024e-04 9.7912e-04 7.9029e-05 11 8 0 10 0 0 99.57 23.02 0.25 0.00098 0.00124 1813 377 1 5 0 27.390 26.62 19.99 23.02 28.09 31.7 1023.60 -1300 -1292 -1571 -3528 -4518 -4254 -2454 -1075 -1124 -2156 -4005 -3586 -2461 -1481 25 27 -404 528 588 1201 898 397 1217 1096 662 475 -25 -835 -1352 -547 448 625 1314 -758 -3601 -3397 -3573 -1953 -631 -324 -727 -376 -321 -384 226 168 -191 -247 -805 -519 543 717 1044 1144 769 1119 923 394 249 385 1072 1755 2038 2474 746 17 -541 -868 794 682 639 893 536 724 320 -455 -1069 -1856 -1011 -1166 -1329 -1410 -2357 -1523 -803 -614 -154 360 826 670 384 -87 -836 -362 -498 -490 301 884 58 -314 -646 -1365 -983 -351 -1200 -1074 -727 -713 184 672 998 584 541 187 -222 144 154 112 511 292 190 471 736 445 701 -165 -42 880 233 87 -230 -431 -310 -13 -27 -96 281 556 80 -123 -173 -741 -689 -112 -125 -160 -353 -406 -385 -224 -108 -128 -266 -501 -445 -331 -228 4 5 -84 112 130 274 212 93 285 270 174 130 -7 -223 -337 -130 110 167 378 -235 -1086 -970 -1088 -677 -260 -157 -357 -194 -171 -207 121 90 -101 -128 -450 -288 312 402 618 714 499 738 622 267 166 253 717 1247 1573 2040 632 14 -395 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