File name: Pandora183s1_LondonderryNH_20240830_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240831T045439.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240830_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240830 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240830T105113.5Z 9008.452239 178 1 49.78 2 83.13 84.45 44.11 96.95 0.00 1 0.00 1 0 25 4.867e-01 2.818e-02 4.042e-01 1.895e-02 8.988888e-01 1.110014e-02 9.845838e-03 -6.000000e+00 2.834100e-01 230.49 -2.00 3.55 -2.00 322.43 0.00e+00 -5.388571e-03 6.839027e-03 1.022856e-03 -6.000000e+00 1.377792e-02 287.20 -2.00 20.00 -2.00 321.96 0.00e+00 7.639 0.008 302.00 328.00 3 3.5923e-01 4.7439e-02 9.0508e-02 -6.0000e+00 7.0875e-01 1.1776e+00 6.1532e-02 5.0450e-02 -6.0000e+00 7.7081e-01 -1.6302e+00 4.6572e-02 2.5555e-02 -6.0000e+00 4.5691e-01 6.4243e-01 2.1957e-02 7.5734e-03 -6.0000e+00 1.9342e-01 8.0787e-05 -1.4208e-03 5.3027e-04 9.9573e-05 -6.0000e+00 1.3560e-02 3.6857e-03 6.8809e-07 12 8 8 10 0 0 31.65 23.07 0.64 0.00369 -0.00699 52 11 1 5 0 957.180 26.73 20.00 23.07 15.65 30.7 936.99 -44803 -87621 900000 7174 900000 41366 900000 -104019 2279 41175 26517 900000 -105059 198488 -37909 57037 9145 900000 44497 -37312 900000 -32331 60521 -12154 303552 -20295 -47604 -21684 16740 900000 3205 900000 -69960 87293 2213 11703 24632 96231 900000 9389 900000 24973 121731 75949 6973 9216 -2954 67320 -28468 103 22173 119754 75993 7222 82401 37903 88539 -1628 112104 33137 7822 29821 2956 40884 44574 15393 5411 38410 1387 32668 46449 14190 37320 804 18132 -11718 34526 13142 -13816 22419 -12064 11594 8742 7825 6043 7974 11517 3847 10382 -3480 4298 -12124 -507 -8107 -6996 -3040 -1637 -4349 -5063 2368 -4814 -1088 -1992 -6676 356 -4805 -2297 -1168 3657 -2987 59 -355 -376 -580 -4005 2707 -4618 2169 -373 1631 2612 1836 6529 -2686 2570 -1612 2001 1361 -361 927 539 922 374 856 -1590 -41 954 567 356 -178 -549 -1086 -1587 -1335 -4350 900000 132 900000 763 900000 -3984 42 759 489 900000 -5216 3660 -1456 1052 267 900000 957 -1778 900000 -1292 1116 -411 5598 -811 -2414 -766 360 900000 89 900000 -5376 1610 82 392 743 1775 900000 535 900000 1424 2653 2547 444 556 -198 2257 -2577 7 1413 3212 3440 702 4006 2987 4305 -191 3947 2389 708 2300 337 3633 4110 1884 726 3864 223 4436 6074 2664 5443 156 2645 -2024 3473 1675 -2617 3571 -3236 2857 2477 2388 1996 2740 3997 1477 4078 -1508 1609 -5053 -185 -3394 -3341 -1660 -1042 -3320 -4332 1913 -3933 -765 -1267 -4408 236 -3562 -1762 -963 3230 -3273 72 -476 -521 -796 -5495 3375 -6285 2904 -543 2403 3723 2506 8164 -3587 3161 -2009 2355 1727 -545 1610 1058 1962 859 2108 -4331 -115 2718 1641 1022 -488 -1392 -2562 -3624 SS 20240830T111632.6Z 9008.469822 189 1 27.24 2 78.50 88.72 39.67 102.01 0.00 1 0.00 1 0 17 4.528e-01 7.964e-03 1.325e-01 2.808e-03 6.430090e-01 1.511353e-03 7.743938e-03 -6.000000e+00 2.591555e-01 230.48 -2.00 3.55 -2.00 321.23 0.00e+00 3.703315e-03 7.469693e-04 4.104012e-03 -6.000000e+00 1.154255e-02 287.20 -2.00 20.00 -2.00 320.58 0.00e+00 4.850 0.002 302.00 328.00 3 6.0403e-01 5.2810e-03 6.2026e-02 -6.0000e+00 6.4721e-01 5.9422e-02 7.2618e-03 4.2565e-02 -6.0000e+00 7.0148e-01 -7.6095e-02 7.1840e-03 2.1384e-02 -6.0000e+00 4.1816e-01 1.6968e-02 3.4092e-03 5.8318e-03 -6.0000e+00 1.7662e-01 1.2197e-03 -4.9983e-04 7.8557e-05 9.9875e-05 -6.0000e+00 1.1958e-02 2.6163e-03 1.8391e-05 12 9 1 12 1 1 46.75 23.06 0.26 0.00262 -0.00114 95 36 1 5 0 283.660 26.73 20.00 23.06 18.52 30.9 956.97 -138433 -138105 -133992 -173979 -161869 -169293 -163425 -144956 -97459 -95114 -121368 -103596 -127430 -65314 -78799 -4860 -65552 -14481 -12789 -39079 -34631 -52200 -39257 -25284 3223 -44209 -16750 -19519 -44407 -33885 -5150 -5236 -15075 2814 -8974 -6984 -7790 -15236 -3845 -1663 2628 -964 2374 -1415 -1103 4027 -2291 73 -1869 3769 500 5613 3111 -15 5786 -400 4917 1045 1769 194 2865 2260 2350 5364 3204 2098 628 885 852 1885 1859 2319 2719 1363 31 -914 -2813 -3058 -2488 -1349 -1294 -349 -1227 -1260 -173 -47 188 779 1741 505 549 72 -1285 -1047 -893 -711 -341 1246 -231 138 -934 -1683 -1309 -1022 -1595 -1681 -1232 -782 167 758 910 706 225 330 -754 308 215 297 376 187 201 343 1006 462 666 -446 -187 894 84 -63 -328 -341 -456 -61 -217 -304 373 484 209 -207 -26 -270 -152 -695 -851 -887 -1747 -1330 -1429 -1505 -1263 -607 -639 -1118 -877 -1713 -618 -1099 -40 -1142 -169 -162 -691 -612 -1105 -753 -460 48 -1134 -338 -398 -1139 -827 -112 -138 -518 99 -347 -256 -311 -776 -216 -111 193 -80 202 -129 -102 365 -227 7 -200 407 62 746 468 -3 989 -76 918 204 334 37 539 469 556 1399 912 593 176 253 268 680 748 977 1137 548 12 -309 -897 -980 -882 -562 -634 -194 -759 -828 -120 -35 147 625 1383 393 398 49 -845 -703 -669 -616 -342 1280 -263 158 -1009 -1811 -1282 -1004 -1701 -1902 -1330 -900 208 1053 1398 1149 369 519 -1132 438 308 446 600 311 332 545 1532 682 943 -615 -248 1229 132 -112 -636 -704 -988 -141 -489 -722 900 1187 512 -489 -64 -616 -337 SS 20240830T112130.0Z 9008.473263 192 1 49.72 2 77.60 89.56 38.81 103.07 0.00 1 0.00 1 0 17 3.573e-01 7.035e-03 6.155e-02 1.385e-03 6.036002e-01 7.316038e-04 6.999194e-03 -6.000000e+00 2.045173e-01 230.48 -2.00 3.55 -2.00 321.11 0.00e+00 2.018957e-03 3.504570e-04 2.969414e-03 -6.000000e+00 9.108993e-03 287.20 -2.00 20.00 -2.00 320.47 0.00e+00 4.521 0.002 302.00 328.00 3 -6.7573e-03 2.5101e-03 5.6802e-02 -6.0000e+00 5.1076e-01 2.9411e-02 3.4192e-03 3.7295e-02 -6.0000e+00 5.5358e-01 -3.7910e-02 3.3578e-03 1.8601e-02 -6.0000e+00 3.2999e-01 1.8017e-03 1.6088e-03 5.0666e-03 -6.0000e+00 1.3939e-01 3.2055e-03 -3.8582e-04 3.9269e-05 6.9356e-05 -6.0000e+00 9.4361e-03 2.7837e-03 4.1136e-05 11 8 0 10 0 0 33.31 23.05 0.26 0.00278 -0.00012 432 90 1 5 0 115.070 26.73 19.99 23.05 19.12 31.0 961.07 -136445 -114821 -118842 -109635 -135692 -111921 -128171 -115860 -92284 -100270 -102545 -64934 -78053 -66803 -55214 -40478 -30224 -25288 -11965 -9999 -13516 -17673 -17639 -29052 -19082 -17803 -13864 -22679 -18848 -13644 -13573 -14317 -3857 -9744 -11428 -10295 -8665 -4245 -1329 701 -3843 256 -454 1784 1637 1386 962 83 766 -1955 1959 854 2473 3288 1826 1454 1260 120 155 704 1111 2909 3246 4437 2605 820 329 93 833 1699 1286 2028 1192 1059 -334 -1184 -2058 -2990 -2075 -1570 -960 -1179 -1851 -1518 -301 101 550 887 1596 1394 767 -249 -1326 -794 -960 -538 372 1043 137 -246 -809 -1663 -1104 -583 -1566 -1352 -1035 -700 173 685 1127 578 464 167 -408 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