File name: Pandora183s1_LondonderryNH_20240831_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240901T045127.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240831_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240831 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240831T125344.6Z 9009.537322 211 1 49.83 2 61.12 106.62 34.18 118.42 0.00 1 0.00 1 0 17 3.679e-02 8.664e-03 2.619e-02 4.710e-03 2.824523e-01 2.364600e-03 3.374969e-03 -6.000000e+00 2.106067e-02 230.39 -2.00 3.55 -2.00 318.69 0.00e+00 1.228370e-03 4.841944e-04 4.818921e-04 -6.000000e+00 9.378242e-04 287.11 -2.00 20.00 -2.00 317.82 0.00e+00 2.060 0.000 302.00 328.00 3 4.5501e+00 6.5190e-03 2.5301e-02 -6.0000e+00 5.2586e-02 5.3128e-02 7.4557e-03 1.4915e-02 -6.0000e+00 5.6986e-02 -9.9118e-04 4.8438e-03 7.3262e-03 -6.0000e+00 3.3972e-02 -7.8442e-03 2.4914e-03 2.1266e-03 -6.0000e+00 1.4363e-02 5.0308e-04 1.7634e-04 1.3928e-04 2.3851e-05 -6.0000e+00 9.7125e-04 1.3560e-04 1.2549e-04 11 8 0 10 0 0 99.99 22.97 0.49 0.00014 0.00146 45 9 1 5 0 1107.070 26.62 20.01 22.97 26.41 31.5 1009.85 -2982 -13016 4010 -21596 6564 -10765 -8228 8580 1659 6052 -925 -11354 -20773 2849 -1038 1284 -430 1113 4611 788 -39 7399 431 864 1258 444 336 -1004 -855 -268 -842 1543 -3329 147 -2155 2326 -6125 -3109 2181 986 -674 -1384 -1701 -940 325 609 -1285 -100 1144 -622 128 -629 2299 2139 698 1416 729 1010 -879 726 381 1557 2293 2790 491 -2137 664 -129 860 -740 1215 969 838 1066 1113 -1193 -966 -934 73 -2579 -2424 -2142 -2066 -1019 -854 -853 670 279 1611 1649 -2 332 -1301 -736 -554 -462 906 438 57 -128 -656 -1445 -1654 -306 -932 -1024 -840 -415 60 982 1448 802 719 256 -545 -596 -392 -591 726 -127 450 598 583 669 150 -694 -25 3 227 76 46 -86 -377 -277 -26 -141 637 711 343 66 -639 -606 -613 -156 -855 253 -1711 349 -626 -479 470 110 412 -68 -921 -2052 259 -114 155 -56 149 623 115 -6 1034 65 136 209 78 59 -188 -148 -45 -149 292 -723 33 -464 455 -1384 -788 631 342 -264 -576 -734 -409 139 262 -555 -42 463 -256 55 -293 1104 1086 373 766 406 560 -486 391 211 910 1454 1895 346 -1442 401 -76 526 -522 929 779 677 830 809 -798 -579 -528 46 -1731 -1838 -1795 -1857 -948 -847 -909 744 322 1839 1819 -2 313 -1253 -679 -539 -497 973 525 74 -163 -787 -1760 -1897 -356 -1185 -1380 -1182 -554 84 1453 2256 1279 1107 406 -798 -820 -536 -845 1099 -206 744 973 922 1013 216 -962 -33 4 319 116 73 -142 -634 -484 -48 -275 1265 1441 701 132 -1234 -1124 -1114 SS 20240831T130807.2Z 9009.547306 220 1 49.03 2 58.61 109.55 31.99 122.87 0.00 1 0.00 1 0 17 9.422e-02 2.029e-02 8.287e-02 1.539e-02 2.708764e-01 7.737899e-03 3.245474e-03 -6.000000e+00 5.391739e-02 230.39 -2.00 3.55 -2.00 318.28 0.00e+00 5.817200e-04 1.462920e-03 6.552594e-04 -6.000000e+00 2.401147e-03 287.11 -2.00 20.00 -2.00 317.46 0.00e+00 1.913 0.000 302.00 328.00 3 6.0772e+00 2.1043e-02 2.3802e-02 -6.0000e+00 1.3463e-01 9.1536e-02 2.3937e-02 1.4435e-02 -6.0000e+00 1.4591e-01 2.4472e-03 1.5085e-02 6.9191e-03 -6.0000e+00 8.6979e-02 -1.0019e-02 7.7654e-03 1.8837e-03 -6.0000e+00 3.6761e-02 1.2579e-04 3.6131e-04 4.4553e-04 1.8697e-05 -6.0000e+00 2.4876e-03 3.9681e-04 4.9571e-05 12 9 8 11 8 0 99.42 22.97 0.15 0.00040 0.00311 15 3 1 5 0 3267.720 26.62 20.00 22.97 27.33 31.5 1016.59 10324 -21294 14388 -10172 7479 -14232 20201 31251 -38139 54931 18800 39775 17944 774 27163 -9293 -5890 -17622 10088 4108 -3742 -1384 5252 8260 -6649 6900 -905 12219 5222 3846 -11374 4674 9618 -2025 -12012 8085 6219 -4307 -5514 4186 -6072 33 375 2207 -2111 -1572 3299 -5740 -4505 -403 1442 8247 3287 3524 -464 -1693 690 -305 2592 865 -915 1299 4198 6005 4997 -2326 1109 -3678 3683 -2533 1814 -547 -683 4440 721 -2510 905 -3257 -3633 -3946 -2889 -2988 -2651 -1664 364 -2470 2542 -485 4168 2 620 -491 -3486 1009 -1648 -624 682 -506 2847 -249 1590 -2484 -143 -281 -2073 -2746 -2008 1050 1126 2154 801 1458 -531 -125 -1325 -425 -1059 -2766 3354 1648 1645 212 -1073 565 522 -1635 -92 2227 -699 -239 -253 -1784 -550 -951 -410 438 1638 -90 1559 1407 -873 -419 -2033 587 -1873 926 -807 441 -962 1073 1660 -4581 2791 1368 2343 1451 86 2666 -1470 -952 -3317 1503 674 -683 -245 873 1402 -1390 1315 -188 2117 899 702 -2533 965 2058 -512 -3171 1659 1385 -1234 -1925 1566 -2788 15 175 1024 -1019 -755 1486 -2758 -2091 -179 659 3787 1682 1896 -269 -1013 411 -183 1479 496 -546 811 2773 4177 3545 -1647 697 -2338 2290 -1902 1437 -465 -582 3467 594 -1919 600 -2121 -2459 -3016 -2464 -2822 -2671 -1735 397 -2973 3074 -625 5131 2 706 -514 -3426 913 -1615 -668 803 -668 3866 -343 2016 -3001 -159 -322 -2629 -3707 -2809 1489 1677 3387 1347 2465 -881 -191 -1885 -561 -1403 -3896 4765 2538 2585 332 -1656 821 719 -2189 -115 2739 -948 -347 -385 -2827 -876 -1584 -722 802 3033 -174 2958 2600 -1587 -727 -3518 SS 20240831T131233.0Z 9009.550382 223 1 49.77 2 57.85 110.47 31.33 124.34 0.00 1 0.00 1 0 17 2.416e-02 8.150e-03 1.375e-02 2.978e-03 2.570747e-01 1.501752e-03 3.087333e-03 -6.000000e+00 1.383134e-02 230.39 -2.00 3.55 -2.00 318.37 0.00e+00 8.137900e-04 2.782785e-04 5.043789e-04 -6.000000e+00 6.158659e-04 287.11 -2.00 20.00 -2.00 317.48 0.00e+00 1.872 0.000 302.00 328.00 3 3.8796e+00 4.0984e-03 2.3008e-02 -6.0000e+00 3.4536e-02 3.6769e-02 4.6652e-03 1.3612e-02 -6.0000e+00 3.7423e-02 6.6195e-03 2.9288e-03 6.6139e-03 -6.0000e+00 2.2310e-02 -1.1515e-02 1.4807e-03 1.8221e-03 -6.0000e+00 9.4338e-03 1.2388e-03 2.1579e-04 8.9242e-05 2.0483e-05 -6.0000e+00 6.3776e-04 -7.0759e-04 1.3573e-04 11 8 0 10 0 0 99.98 22.97 0.48 -0.00071 0.00091 189 39 1 5 0 263.280 26.62 19.99 22.97 27.68 31.5 1018.87 648 -9678 3153 -11264 2167 -8180 -1551 -119 -8051 3864 -9157 -1823 -7202 2056 -2415 3947 -4769 -1136 1497 -2306 4056 -3391 2837 411 -1030 -322 215 1569 -5087 4053 -2549 -86 2268 171 -1004 -3406 708 -2792 467 -502 -1075 -775 -784 540 -740 1259 -1038 355 -1236 305 772 327 1652 1162 1336 348 1245 813 236 904 -459 2799 1777 2673 789 133 -668 -2042 1359 250 799 762 998 1009 498 66 -976 -2355 -1450 -695 -1923 -1016 -2721 -1580 -538 -545 151 389 928 706 758 12 -1264 -212 -1485 -165 -408 1010 142 -756 -216 -1890 -1065 -1055 -1163 -1603 -172 -456 171 654 755 797 395 403 -514 -60 212 -51 972 215 207 362 693 107 468 48 -276 1462 -27 237 -64 -281 -499 -101 -79 -370 454 538 501 -107 -12 -904 -847 41 -770 231 -1000 149 -574 -104 -9 -727 333 -897 -165 -755 226 -320 550 -767 -182 244 -405 689 -616 486 76 -204 -66 44 332 -1066 747 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