File name: Pandora183s1_LondonderryNH_20240904_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240905T045702.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240904_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240904 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240904T112005.7Z 9013.472289 67 1 49.69 2 78.79 90.97 93.71 85.06 0.00 1 0.00 1 0 17 4.121e-01 7.613e-03 1.009e-01 2.043e-03 6.219255e-01 1.088938e-03 7.427946e-03 -6.000000e+00 2.354644e-01 230.04 -2.00 3.55 -2.00 321.30 0.00e+00 3.108804e-03 5.511225e-04 4.325202e-03 -6.000000e+00 1.048653e-02 286.79 -2.00 20.00 -2.00 320.69 0.00e+00 4.962 0.002 302.00 328.00 3 1.5154e-01 3.8558e-03 6.2684e-02 -6.0000e+00 5.8748e-01 5.8781e-02 5.3756e-03 4.3117e-02 -6.0000e+00 6.3701e-01 -7.7853e-02 5.3745e-03 2.1210e-02 -6.0000e+00 3.7977e-01 1.5003e-02 2.5341e-03 5.5140e-03 -6.0000e+00 1.6050e-01 1.7905e-03 -4.7173e-04 5.8026e-05 1.0375e-04 -6.0000e+00 1.0881e-02 2.4632e-03 2.2159e-05 11 8 0 10 0 0 -3.78 22.98 0.30 0.00246 -0.00108 312 65 1 5 0 159.240 26.62 20.01 22.98 17.63 31.2 950.55 -150580 -144981 -95843 -141442 -155669 -85089 -158405 -137490 -133225 -130320 -112398 -79333 -82045 -68805 -65883 -57220 -31464 -32458 -17840 -21092 -28869 -20878 -27472 -15703 -20474 -17439 -16708 -20200 -23571 -38453 -18929 -5484 -12762 -1567 -9081 -13773 -12379 -8099 -3201 1802 -2847 2095 -671 -1840 1991 -2540 4926 -3472 830 -937 4349 227 4159 2349 4282 3970 2182 644 776 1093 1108 3063 4172 3819 2435 2489 1104 143 -120 1817 1906 1595 2045 1526 -574 -614 -2775 -3742 -1989 -1783 -960 -354 -2052 -1488 -592 222 892 970 1496 1133 662 -578 -1308 -1214 -746 -1204 33 1100 252 -181 -632 -1895 -1840 -805 -1518 -1352 -1174 -796 213 732 1062 408 596 -39 -526 -172 158 86 687 98 396 778 867 357 211 -713 -350 857 -127 -99 -433 -711 -418 -112 -164 -193 327 714 133 23 -19 -367 -212 -950 -1059 -477 -1127 -1318 -339 -1394 -1119 -1195 -1255 -952 -575 -758 -723 -859 -840 -410 -476 -249 -325 -502 -337 -488 -270 -404 -357 -351 -432 -508 -1010 -480 -147 -432 -53 -321 -494 -473 -351 -163 106 -201 168 -59 -169 179 -244 451 -356 85 -104 507 31 603 379 723 703 407 123 144 198 207 613 939 977 673 674 295 39 -36 625 731 646 822 586 -207 -198 -847 -1152 -666 -707 -443 -186 -1207 -924 -390 155 653 734 1127 828 454 -374 -812 -768 -524 -982 31 1162 294 -213 -699 -1909 -1696 -741 -1520 -1433 -1309 -946 273 1046 1673 683 994 -63 -805 -250 232 132 1118 167 671 1267 1360 544 309 -1015 -480 1212 -204 -179 -859 -1502 -839 -239 -375 -463 800 1770 331 55 -44 -785 -487 SS 20240904T112559.1Z 9013.476378 70 1 49.72 2 77.71 91.98 92.67 86.06 0.00 1 0.00 1 0 17 3.203e-01 6.942e-03 5.912e-02 1.479e-03 5.774844e-01 7.782881e-04 6.748246e-03 -6.000000e+00 1.830359e-01 230.03 -2.00 3.55 -2.00 321.03 0.00e+00 2.228155e-03 3.597530e-04 2.936422e-03 -6.000000e+00 8.151552e-03 286.79 -2.00 20.00 -2.00 320.38 0.00e+00 4.560 0.002 302.00 328.00 3 8.1347e-02 2.5994e-03 5.6035e-02 -6.0000e+00 4.5668e-01 3.0097e-02 3.5099e-03 3.5590e-02 -6.0000e+00 4.9516e-01 -4.3958e-02 3.4191e-03 1.7841e-02 -6.0000e+00 2.9521e-01 2.9154e-03 1.6504e-03 4.8857e-03 -6.0000e+00 1.2477e-01 2.9438e-03 -3.3583e-04 4.2410e-05 6.5574e-05 -6.0000e+00 8.4580e-03 2.3815e-03 2.8803e-05 11 8 0 10 0 0 -4.97 22.98 0.23 0.00238 -0.00014 410 85 1 5 0 121.220 26.62 19.99 22.98 18.47 31.0 955.90 -126984 -121001 -90896 -86500 -104928 -103230 -109907 -110450 -79257 -93618 -80096 -92461 -72379 -56096 -44115 -27408 -20258 -23923 -21068 -27740 -19170 -25169 -14397 -11170 -18304 -15047 -17883 -16355 -20050 -18153 -9003 -6964 -1940 -4632 -7462 -10088 -8367 -7909 -665 1274 2336 1297 2659 1011 734 713 1113 -292 -315 2160 1632 873 2527 2597 1163 1630 981 974 410 137 1011 2134 2877 4200 2569 1257 -49 -838 1121 904 1658 1669 1018 731 105 -1174 -2185 -2804 -2130 -1580 -933 -658 -2029 -1194 -537 88 633 806 1277 1307 680 -23 -1044 -1041 -1032 -576 206 1084 172 -222 -612 -1646 -1321 -798 -1547 -1248 -974 -641 195 895 981 614 407 227 -444 -108 100 91 399 68 135 429 924 327 315 -518 -295 705 35 -91 -257 -550 -415 -190 -237 -231 288 697 155 99 -25 -461 -264 -962 -1048 -645 -593 -795 -732 -885 -1116 -676 -1019 -798 -1128 -883 -743 -654 -417 -327 -442 -415 -622 -412 -578 -306 -251 -483 -411 -518 -457 -563 -519 -272 -246 -76 -205 -331 -489 -431 -479 -46 105 219 133 284 113 84 83 132 -36 -40 283 237 143 448 500 242 352 221 221 91 30 225 513 777 1260 829 400 -15 -267 383 358 726 769 472 323 43 -437 -757 -970 -804 -699 -479 -384 -1318 -815 -390 68 514 675 1066 1054 514 -16 -708 -715 -785 -502 205 1220 213 -276 -716 -1755 -1290 -785 -1657 -1413 -1158 -810 266 1224 1473 973 642 344 -635 -162 150 143 608 109 215 659 1502 517 478 -760 -417 1025 57 -153 -468 -1059 -833 -405 -541 -554 703 1725 384 237 -56 -991 -554 SS 20240904T113127.9Z 9013.480184 73 1 49.72 2 76.71 92.93 91.71 86.98 0.00 1 0.00 1 0 17 2.295e-01 6.727e-03 4.215e-02 1.131e-03 5.414129e-01 5.950886e-04 6.393706e-03 -6.000000e+00 1.311432e-01 230.03 -2.00 3.55 -2.00 320.82 0.00e+00 2.182136e-03 2.549100e-04 2.656438e-03 -6.000000e+00 5.840453e-03 286.79 -2.00 20.00 -2.00 320.13 0.00e+00 4.239 0.001 302.00 328.00 3 1.3957e-02 1.9401e-03 5.2171e-02 -6.0000e+00 3.2720e-01 1.3864e-02 2.5175e-03 3.2890e-02 -6.0000e+00 3.5477e-01 -2.1810e-02 2.3566e-03 1.6325e-02 -6.0000e+00 2.1151e-01 -5.1669e-03 1.1599e-03 4.4690e-03 -6.0000e+00 8.9397e-02 4.4164e-03 -3.2379e-04 3.2944e-05 6.3111e-05 -6.0000e+00 6.0598e-03 2.2573e-03 3.6202e-05 11 8 0 10 0 0 -17.45 22.98 0.29 0.00226 -0.00018 511 106 1 5 0 97.280 26.62 20.00 22.98 19.19 31.0 962.14 -77604 -85821 -64668 -89387 -65118 -89138 -64516 -86102 -60325 -63047 -52210 -36071 -62414 -35402 -40916 -24407 -21446 -17985 -5238 -19805 -5992 -19759 -9885 -14593 -5523 -13809 -6536 -10985 -18679 -7928 -13072 -4676 -7169 -3920 -7226 -3454 -4623 -6802 205 -2997 584 321 -146 905 403 1593 238 460 -855 464 1001 1236 2403 955 2033 1168 1852 -220 -212 405 433 2092 2654 4080 1585 1225 -17 -511 1477 1231 1641 1163 1334 546 -22 -1021 -2083 -2783 -2146 -1303 -1048 -776 -2027 -1386 -591 -277 662 959 1451 1003 799 46 -981 -843 -960 -307 373 1027 -2 -266 -835 -1455 -941 -708 -1486 -1483 -738 -756 315 812 1008 568 359 149 -469 66 105 110 414 106 227 522 984 215 456 -596 -278 570 -28 -73 -428 -504 -372 -161 -202 -200 362 618 180 -65 -5 -399 -208 -506 -734 -493 -879 -461 -831 -498 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