File name: Pandora183s1_LondonderryNH_20240913_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240914T045025.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240913_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240913 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240913T112755.2Z 9022.477722 65 1 49.74 2 79.09 95.40 159.58 312.95 0.00 1 0.00 1 0 25 4.972e-01 2.110e-02 3.267e-01 1.240e-02 6.262892e-01 6.790450e-03 7.117840e-03 -6.000000e+00 2.854701e-01 229.23 -2.00 3.55 -2.00 321.52 0.00e+00 8.603216e-04 3.471937e-03 2.407650e-03 -6.000000e+00 1.338163e-02 286.06 -2.00 20.00 -2.00 320.93 0.00e+00 5.088 0.002 302.00 328.00 3 2.7501e+00 2.4530e-02 6.1555e-02 -6.0000e+00 7.1292e-01 2.6717e-01 3.2934e-02 3.7502e-02 -6.0000e+00 7.7464e-01 -4.2057e-01 2.9376e-02 1.8298e-02 -6.0000e+00 4.6091e-01 1.6771e-01 1.3793e-02 5.0063e-03 -6.0000e+00 1.9547e-01 1.1652e-04 -5.2956e-04 3.6725e-04 7.0105e-05 -6.0000e+00 1.3408e-02 1.3075e-03 6.6535e-05 12 8 8 10 0 0 91.48 22.98 0.71 0.00131 -0.00267 22 5 1 5 0 2260.450 26.62 19.99 22.98 20.84 31.1 971.72 11943 -179581 900000 -153681 900000 -180516 -143458 57299 -146617 900000 -150211 -68468 -169739 -4447 36657 -3510 900000 -76048 230448 -39526 167354 -13499 900000 82607 -50544 86271 -53093 29011 -28502 42673 44174 -2618 3160 9105 32494 -48364 1552 52592 32069 13394 31065 34674 11436 40806 -12333 20642 1964 26002 7927 10696 30286 12912 38801 13011 28762 12638 11652 13588 474 21222 4641 9385 17159 17465 5597 7778 4614 3007 269 4073 4215 2708 2534 -259 -3772 9878 4637 3637 2276 3084 -8322 -2576 1935 -3536 -1924 -3886 -151 -1251 3826 -2048 204 3205 -3835 -2670 -3433 -1101 -3428 2283 385 -3215 48 -2761 1942 -3857 -2537 -2242 937 -486 -846 493 -1056 1492 -85 -39 -951 -759 54 1790 311 -1542 1623 560 1764 1155 -262 1811 1833 1341 1211 -408 575 182 -764 316 -768 508 -64 1505 344 -410 -467 -1259 -1295 144 -5340 900000 -3713 900000 -4697 -2666 692 -3838 900000 -4537 -965 -7860 -54 443 -57 900000 -3062 2784 -1234 2022 -326 900000 998 -2086 1042 -2405 555 -918 750 873 -98 128 380 1035 -3293 68 1617 1479 897 1979 2285 992 2689 -1382 1678 194 2056 775 1069 2727 1546 3920 1843 3696 1985 1907 2179 84 2960 775 1618 3091 3529 1352 1794 1064 717 72 1208 1389 952 888 -88 -1222 2495 1136 895 687 992 -3519 -1177 931 -1906 -1199 -2403 -95 -903 2625 -1440 131 1859 -2274 -1597 -2302 -834 -3073 2215 417 -3628 49 -2625 1612 -3416 -2397 -2243 958 -538 -1029 663 -1597 2329 -135 -59 -1386 -1056 75 2565 482 -2544 2580 869 2610 1664 -368 2398 2343 1796 1832 -706 1078 364 -1617 703 -1850 1271 -164 3875 893 -1029 -1105 -2828 -2830 SS 20240913T113358.4Z 9022.481927 68 1 49.90 2 77.99 96.46 160.32 315.96 0.00 1 0.00 1 0 25 3.250e-01 9.328e-03 3.265e-01 6.593e-03 5.991990e-01 3.570231e-03 7.148274e-03 -6.000000e+00 1.853573e-01 229.23 -2.00 3.55 -2.00 321.34 0.00e+00 3.951838e-03 1.803916e-03 3.799970e-03 -6.000000e+00 8.511833e-03 286.06 -2.00 20.00 -2.00 320.73 0.00e+00 4.657 0.002 302.00 328.00 3 2.3322e+00 1.2644e-02 5.8534e-02 -6.0000e+00 4.6267e-01 6.3391e-02 1.7542e-02 3.9134e-02 -6.0000e+00 5.0237e-01 -9.0397e-02 1.7450e-02 2.0647e-02 -6.0000e+00 2.9882e-01 2.4921e-02 8.2378e-03 6.1294e-03 -6.0000e+00 1.2708e-01 2.7300e-04 -7.3996e-04 1.9317e-04 1.0324e-04 -6.0000e+00 8.5873e-03 1.6924e-03 3.2896e-05 11 8 0 10 0 0 75.66 22.98 0.39 0.00169 -0.00387 47 10 1 5 0 1061.550 26.62 20.00 22.98 21.24 31.1 974.73 -54689 900000 -139341 17733 -129391 -65725 -101476 -71210 -194091 900000 47414 -45934 -49205 45836 -57241 28284 3977 -37820 123374 -49487 -56554 -32521 26426 5416 258 43854 26506 -1272 -29111 -2444 4860 -21372 -17972 4341 39325 -30010 -2371 -16121 2219 -3730 -2472 4776 5333 -2592 -3483 865 8970 330 9735 6781 -133 2956 858 1892 3726 -5608 258 4226 -3466 6104 -148 3661 5271 3546 1768 2669 1390 654 3015 -2596 2353 2692 1235 -905 76 -1831 -1614 -1152 -431 -1537 -1472 -539 -313 -1303 -249 318 713 1331 2764 1699 493 454 -1258 -1522 -4 -2290 -146 -180 1121 21 -1238 -1497 -1015 -2418 -1688 -999 -937 -519 142 384 353 1180 -153 -388 -775 -305 520 -57 975 470 961 -166 1024 994 434 -1177 14 585 -93 -128 107 -846 -1069 -30 -281 220 636 974 -9 -231 -112 -404 -415 -352 900000 -1418 114 -1109 -422 -652 -458 -4054 900000 305 -295 -369 295 -766 197 40 -648 793 -1113 -1424 -645 324 89 5 564 418 -26 -765 -51 111 -762 -725 155 965 -1420 -91 -838 118 -255 -191 371 436 -238 -328 80 781 32 899 681 -16 382 124 295 607 -1045 47 741 -640 1006 -27 693 1115 862 466 682 349 185 905 -866 833 1001 511 -364 28 -613 -497 -351 -143 -611 -686 -284 -181 -808 -163 222 523 1004 2059 1237 339 290 -777 -957 -3 -1856 -133 -189 1268 24 -1352 -1476 -912 -2216 -1659 -1034 -1021 -601 179 536 544 1899 -249 -608 -1145 -429 729 -84 1517 769 1559 -263 1548 1451 612 -1620 19 793 -143 -221 201 -1694 -2245 -66 -664 544 1604 2493 -23 -575 -262 -896 -897 SS 20240913T113930.9Z 9022.485775 71 1 49.69 2 76.98 97.43 160.97 318.89 0.00 1 0.00 1 0 17 3.201e-01 8.844e-03 1.695e-01 4.067e-03 5.657350e-01 2.141132e-03 6.799620e-03 -6.000000e+00 1.823272e-01 229.23 -2.00 3.55 -2.00 321.05 0.00e+00 2.463784e-03 9.864594e-04 3.343792e-03 -6.000000e+00 8.119230e-03 286.06 -2.00 20.00 -2.00 320.41 0.00e+00 4.322 0.001 302.00 328.00 3 2.0106e+00 7.2012e-03 5.4545e-02 -6.0000e+00 4.5413e-01 4.4068e-02 9.6200e-03 3.6716e-02 -6.0000e+00 4.9280e-01 -6.9776e-02 9.2343e-03 1.7993e-02 -6.0000e+00 2.9386e-01 1.4752e-02 4.4562e-03 4.7249e-03 -6.0000e+00 1.2430e-01 5.3870e-04 -6.7904e-04 1.1787e-04 7.8864e-05 -6.0000e+00 8.4500e-03 2.3114e-03 -1.0336e-05 11 8 0 10 0 0 51.38 22.98 0.36 0.00231 -0.00279 75 16 1 5 0 662.370 26.62 20.00 22.98 21.71 31.1 978.69 -86647 -37203 -93115 -72054 -121428 -132739 -166932 -58605 -132395 -24684 -107547 -70791 -60243 -17358 -33961 -30115 -23333 -40151 39292 -25392 -21288 -10402 -50469 -7420 -40862 3116 -23387 -20284 -27094 -11032 -9774 -16544 -774 -5073 -3971 -10598 -3933 -6068 -12099 6565 -5823 5668 1851 8156 3447 1191 2881 576 2579 1061 3110 3419 6259 5604 2215 3854 -385 3112 -1640 1082 720 3250 3701 2804 2534 640 1172 -1531 3977 2164 1860 1740 1896 1217 -1755 1024 -2544 -3274 -2176 -2583 -1529 -2026 -270 -1863 -138 148 530 605 1466 1649 -748 -396 -2553 -993 -796 -1275 711 522 70 -673 -216 -2028 -1037 -662 -1885 -1429 -1082 124 -202 625 917 1141 454 292 -635 -584 -64 -65 491 397 399 335 507 841 302 -393 104 522 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