File name: Pandora183s1_LondonderryNH_20240914_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240915T045139.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240914_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240914 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240914T111755.4Z 9023.470780 91 1 49.20 2 81.11 94.02 147.47 293.21 0.00 1 0.00 1 0 17 5.165e-01 3.227e-02 4.438e-01 2.346e-02 7.268557e-01 1.310873e-02 9.293834e-03 -6.000000e+00 2.971658e-01 229.14 -2.00 3.55 -2.00 321.93 0.00e+00 5.257153e-03 7.291266e-03 1.040752e-02 -6.000000e+00 1.451837e-02 285.98 -2.00 20.00 -2.00 321.38 0.00e+00 6.120 0.004 302.00 328.00 3 2.2388e+00 5.0434e-02 9.0369e-02 -6.0000e+00 7.4034e-01 7.0243e-01 6.5686e-02 7.9625e-02 -6.0000e+00 8.0576e-01 -9.2245e-01 5.3935e-02 3.0422e-02 -6.0000e+00 4.7857e-01 3.5418e-01 2.5455e-02 5.7682e-03 -6.0000e+00 2.0155e-01 6.0583e-05 -1.7300e-03 6.7934e-04 1.6943e-04 -6.0000e+00 1.3932e-02 4.2889e-03 -3.9451e-05 12 8 8 10 0 0 11.15 22.99 0.65 0.00429 -0.00871 24 5 1 5 0 2049.670 26.62 20.00 22.99 22.03 31.1 980.15 -45550 -93592 900000 -111938 -101744 -133378 38218 -66526 900000 -141602 -126948 -73512 -124277 -80605 -69443 247361 -25436 70198 61998 900000 -43009 -11783 102146 900000 900000 900000 -12114 900000 -10532 14662 -35270 56459 -65759 18384 174092 49168 114729 13193 62701 38694 137208 29792 120071 34337 -52054 72913 6802 8796 5179 27603 84138 13239 79987 43319 62652 34641 38262 -6309 19567 34207 35008 7250 10327 36780 4503 15662 24109 21288 13038 40 18380 11299 16999 351 520 -13050 4419 -962 3544 9311 9504 -338 -16094 1334 1952 5998 1356 11669 3718 1321 -2368 2676 -7059 -1539 2358 -10358 -3899 955 -6818 -2680 -571 1359 -8069 -2135 -8173 -5909 -1818 -3290 2351 2621 2288 563 476 2448 -3052 -1017 -2351 2498 1426 347 2101 4223 1559 -1867 2663 -2132 3963 3122 -1000 2038 -381 -1442 -254 -810 806 -506 -22 2065 -332 505 14 -1391 -2038 -1041 -2467 900000 -3541 -2504 -3985 873 -1520 900000 -5226 -4016 -1680 -4805 -2763 -2644 5652 -823 1604 1417 900000 -1883 -359 2334 900000 900000 900000 -392 900000 -301 335 -1545 1290 -5384 700 3978 1217 2621 603 2084 1929 3135 1918 3242 2211 -7893 3180 579 749 473 2121 4020 1430 4818 4049 5075 3814 4133 -1048 2398 3482 3563 1054 1652 5119 926 2830 3906 3626 2627 11 4467 3075 4308 99 132 -3361 881 -204 802 2379 2862 -129 -7956 587 908 2853 710 5672 1954 686 -1190 1315 -3343 -784 1304 -7621 -3145 849 -6572 -2755 -540 1131 -6674 -1659 -7264 -5455 -1703 -3368 2514 3174 3120 838 717 3524 -4415 -1387 -3282 3494 2144 548 3226 6089 2223 -2670 3511 -2850 4836 4045 -1544 3487 -738 -3032 -557 -1909 2008 -1343 -59 5539 -908 1310 35 -3213 -4586 SS 20240914T113202.0Z 9023.480579 96 1 49.48 2 78.54 96.47 149.66 297.27 0.00 1 0.00 1 0 17 3.630e-01 1.041e-02 2.671e-01 5.157e-03 6.114954e-01 2.793175e-03 7.270428e-03 -6.000000e+00 2.075885e-01 229.14 -2.00 3.55 -2.00 321.45 0.00e+00 4.383245e-03 1.446277e-03 3.811204e-03 -6.000000e+00 9.352473e-03 285.98 -2.00 20.00 -2.00 320.85 0.00e+00 4.863 0.002 302.00 328.00 3 1.7387e+00 1.0041e-02 6.0492e-02 -6.0000e+00 5.1642e-01 8.2190e-02 1.3927e-02 3.9517e-02 -6.0000e+00 5.6043e-01 -1.5096e-01 1.3806e-02 2.0838e-02 -6.0000e+00 3.3366e-01 4.8284e-02 6.4873e-03 6.2643e-03 -6.0000e+00 1.4096e-01 4.0989e-04 -5.5295e-04 1.5164e-04 1.0416e-04 -6.0000e+00 9.5882e-03 2.3879e-03 4.5424e-05 12 8 8 10 0 0 2.41 23.00 0.46 0.00239 -0.00177 82 17 1 5 0 603.220 26.62 20.00 23.00 23.07 31.1 986.32 -80766 -38674 -209665 111033 -133011 900000 -107388 71518 -100434 -96684 -57001 -131800 56715 -121042 -13447 -2884 -9813 -46093 -50126 -50003 -46170 2135 -38416 -20201 10498 -15310 5773 -65522 20401 -39607 -815 -8375 12089 2860 -4919 -4786 -29056 -8083 -18702 13724 -2971 4914 9288 -6398 9512 -5846 15452 -189 6322 -914 4901 15225 -112 7296 -920 11384 480 7966 4220 -5040 5604 696 11065 2733 7701 -2370 292 939 2231 3322 2163 3119 -412 1566 1848 -240 732 -4510 1862 -5935 865 -2148 -1035 -1390 -666 664 -549 719 1924 1997 0 -93 -1295 -2515 -1753 -1096 632 570 858 -635 -562 -2370 -2433 336 -2424 -1539 -1739 -576 365 299 1376 132 739 -106 -429 -26 243 -238 -65 824 -40 1041 695 598 175 -313 -65 393 688 -528 222 214 -460 -334 -585 -56 396 714 -245 321 -226 -514 -236 -406 -194 -4305 558 -1171 900000 -720 360 -800 -810 -334 -1767 285 -2333 -113 -27 -111 -831 -1029 -1090 -1098 31 -861 -406 168 -336 106 -2396 308 -1141 -19 -249 343 98 -178 -166 -1381 -366 -1154 740 -216 357 684 -570 735 -540 1180 -17 566 -93 520 1636 -15 1014 -148 1681 82 1260 675 -869 892 127 2074 630 1979 -659 77 250 639 1089 800 1201 -164 580 627 -74 208 -1347 577 -2355 376 -1102 -577 -826 -420 442 -391 522 1384 1389 0 -57 -769 -1542 -1186 -852 559 578 949 -717 -594 -2299 -2162 292 -2345 -1567 -1871 -655 449 411 2070 212 1180 -164 -627 -36 341 -351 -102 1342 -66 1626 1052 876 247 -428 -85 537 1057 -923 420 430 -976 -753 -1415 -141 1020 1868 -645 809 -540 -1165 -519 SS 20240914T113801.8Z 9023.484743 99 1 49.65 2 77.45 97.52 150.57 299.12 0.00 1 0.00 1 0 17 3.683e-01 9.139e-03 1.816e-01 3.399e-03 5.677920e-01 1.792930e-03 6.931633e-03 -6.000000e+00 2.097144e-01 229.14 -2.00 3.55 -2.00 321.14 0.00e+00 4.436671e-03 8.507212e-04 3.677344e-03 -6.000000e+00 9.338497e-03 285.98 -2.00 20.00 -2.00 320.51 0.00e+00 4.472 0.002 302.00 328.00 3 1.5659e+00 6.1068e-03 5.5729e-02 -6.0000e+00 5.2225e-01 2.6435e-02 8.1782e-03 3.6344e-02 -6.0000e+00 5.6674e-01 -8.1464e-02 7.9490e-03 1.9149e-02 -6.0000e+00 3.3796e-01 2.2238e-02 3.8275e-03 5.8336e-03 -6.0000e+00 1.4298e-01 7.4065e-04 -4.6600e-04 9.8556e-05 1.0017e-04 -6.0000e+00 9.7213e-03 2.2782e-03 1.5341e-05 11 8 0 10 0 0 9.23 23.00 0.34 0.00228 -0.00122 118 25 1 5 0 420.690 26.62 20.00 23.00 23.43 31.1 988.87 -100540 -134699 -30515 -160254 -32129 -100301 -92114 -124627 -21418 -72645 -112591 212638 -116586 1757 -70742 1810 -3410 -25370 36099 -36822 1560 -51821 -11511 -25697 -15739 -7617 -25125 -19014 -45101 922 -19186 7962 -12040 -3289 -8092 -19433 4749 -21641 6677 -1731 7271 2462 3763 3163 1200 8902 237 1867 -8775 593 -2470 1002 6053 1663 4619 3117 4490 119 4476 1351 -294 5246 1305 6074 3112 686 1587 1270 2191 1323 2184 1085 1388 607 356 -2305 -2549 -2346 -2729 -248 -1195 -802 -1926 -1094 -488 -422 1076 115 1714 1469 586 -312 -945 -1475 -2326 -431 -552 1664 152 -570 -1082 -1606 -821 -1329 -1216 -2272 -358 -866 501 626 440 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