File name: Pandora183s1_LondonderryNH_20240927_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240928T044858.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240927_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240927 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240927T112232.9Z 9036.473992 230 1 49.95 2 82.89 99.32 28.58 126.94 0.00 1 0.00 1 0 17 4.838e-01 1.932e-02 3.554e-01 1.248e-02 7.677761e-01 7.005077e-03 9.355184e-03 -6.000000e+00 2.751149e-01 227.62 -2.00 3.55 -2.00 322.15 0.00e+00 1.324474e-02 4.333317e-03 5.318539e-03 -6.000000e+00 1.290141e-02 284.37 -2.00 20.00 -2.00 321.66 0.00e+00 7.430 0.008 302.00 328.00 3 1.7869e-01 2.8733e-02 8.6195e-02 -6.0000e+00 6.8200e-01 7.3581e-01 3.9300e-02 4.5561e-02 -6.0000e+00 7.4096e-01 -9.7042e-01 3.5371e-02 2.6671e-02 -6.0000e+00 4.4276e-01 3.8986e-01 1.6126e-02 1.2163e-02 -6.0000e+00 1.8916e-01 1.3588e-04 -1.4263e-03 3.5530e-04 2.3698e-04 -6.0000e+00 1.2833e-02 2.1468e-03 6.0095e-05 12 8 8 10 0 0 96.60 23.02 0.32 0.00215 -0.00857 65 14 1 5 0 768.300 26.62 19.98 23.02 20.84 31.4 973.94 -153541 900000 -26751 -114864 -158089 -188115 -143381 -165102 -177448 -149393 -98958 -31942 900000 -103355 -72890 -38394 -30212 103867 -19706 71746 26491 -24553 23737 -23845 101821 900000 -34266 -28851 -21136 900000 -18811 42851 -13594 96218 10346 27982 9411 -11345 30008 20268 1993 42472 35881 69348 1081 34376 36965 75241 67080 21923 19432 28892 60644 16048 14953 43730 21157 30343 36997 11961 22505 8141 11673 26450 24187 17201 8825 15874 1164 6668 18031 1371 -149 2054 6169 7628 -578 -602 4152 -374 3474 1100 1810 110 394 2457 -1342 877 4605 642 -2364 477 -2384 -5261 -4288 -1890 -4263 -287 -2039 -20 336 -3389 -3879 -3661 -4315 -2271 -1547 -2538 -661 109 1420 776 120 -1821 -801 -1585 -272 -42 1226 205 1445 1287 2738 1908 932 624 460 1791 398 1066 -824 289 -252 338 -1096 235 179 1423 412 46 -590 -893 -1778 -3592 900000 -325 -2257 -4142 -5809 -2683 -3862 -4815 -3332 -1304 -389 900000 -2515 -1700 -778 -643 1264 -439 873 376 -548 313 -508 1239 900000 -799 -614 -407 900000 -458 758 -496 1277 309 650 271 -452 929 807 106 1597 1508 2147 67 1559 1676 2413 2448 1333 1332 2013 3353 1491 1472 3289 2012 2584 2823 1138 1966 900 1433 3218 3263 2473 1357 2335 216 1350 3609 338 -37 463 1207 1308 -110 -116 869 -99 961 360 652 47 179 1163 -631 458 2319 326 -1156 212 -1056 -2496 -2295 -1170 -3195 -241 -1940 -19 298 -2799 -2897 -2703 -3449 -1892 -1357 -2433 -692 130 1886 1120 178 -2687 -1118 -2154 -370 -60 1842 323 2220 1895 3820 2607 1242 808 581 2362 613 1881 -1650 616 -574 817 -2889 642 500 3988 1160 124 -1495 -2116 -4106 SS 20240927T113318.4Z 9036.481463 233 1 49.65 2 80.96 101.20 27.10 131.07 0.00 1 0.00 1 0 25 5.464e-01 1.092e-02 1.906e-01 3.689e-03 6.663361e-01 2.012392e-03 7.885870e-03 -6.000000e+00 3.094664e-01 227.61 -2.00 3.55 -2.00 321.72 0.00e+00 4.637517e-03 1.120560e-03 4.818498e-03 -6.000000e+00 1.436975e-02 284.37 -2.00 20.00 -2.00 321.17 0.00e+00 6.029 0.004 302.00 328.00 3 -1.6635e-02 7.5844e-03 7.2618e-02 -6.0000e+00 7.6825e-01 1.7085e-01 1.0950e-02 4.5721e-02 -6.0000e+00 8.3500e-01 -2.2270e-01 1.1208e-02 2.4739e-02 -6.0000e+00 4.9804e-01 7.8046e-02 5.1532e-03 7.6869e-03 -6.0000e+00 2.1154e-01 7.5065e-04 -4.6383e-04 1.0715e-04 1.3699e-04 -6.0000e+00 1.4455e-02 2.5256e-03 7.5794e-06 12 8 8 10 0 0 99.76 23.01 0.32 0.00253 -0.00096 204 42 1 5 0 243.350 26.62 20.00 23.01 21.90 31.5 981.90 -250035 -156495 -192027 -208227 -56310 -197915 -121126 -217566 -172335 -200336 -105301 900000 -46244 -138677 -74589 10259 -52385 -43891 -43677 -21130 22942 -61208 -15908 -46063 -18802 -54289 -14414 -16311 -20416 2913 -23380 -12229 -42174 3679 -17332 -27013 -3659 -12019 4113 -1337 2241 7899 14899 9108 -262 14564 4105 15445 1476 8934 4264 15653 3166 9259 11661 3139 8961 1696 784 -762 5114 3811 5992 10543 5802 6975 1026 563 1897 2108 6459 4066 3712 794 -770 -1206 -1972 -7206 -1463 -1536 223 -164 -2372 -945 195 -693 1563 499 2188 804 49 -975 -1539 -2754 -2635 -1059 -237 640 -341 -788 -1065 -1113 -1879 -628 -1686 -1877 -720 -781 157 775 949 347 62 -1 -915 -702 -127 110 377 157 713 1400 1231 513 650 -314 70 129 130 -71 -48 -581 -366 -157 5 4 376 736 277 -122 90 -912 -634 -3747 -1126 -2187 -2808 -203 -2076 -617 -3260 -1860 -3122 -663 900000 -222 -2203 -805 58 -644 -553 -602 -269 195 -1201 -203 -858 -289 -1260 -231 -261 -334 40 -497 -284 -1558 95 -538 -892 -103 -432 155 -64 119 429 799 536 -17 848 272 949 110 657 365 1351 342 1026 1346 412 1146 257 116 -113 732 607 1069 2048 1267 1483 227 129 470 604 1975 1338 1219 254 -229 -323 -494 -1918 -411 -516 87 -74 -1205 -503 110 -421 979 326 1408 507 29 -547 -832 -1554 -1670 -770 -199 613 -362 -845 -1074 -1008 -1565 -520 -1523 -1803 -722 -842 184 1020 1388 542 97 -1 -1329 -978 -177 161 586 256 1140 2140 1819 739 900 -424 91 177 202 -125 -92 -1207 -800 -365 12 10 1002 1989 749 -319 221 -2118 -1432 SS 20240927T114450.3Z 9036.489472 238 1 26.28 2 78.89 103.25 25.61 135.89 0.00 1 0.00 1 0 17 3.049e-01 1.327e-02 3.029e-01 9.057e-03 5.768301e-01 4.805147e-03 7.260780e-03 -6.000000e+00 1.727539e-01 227.61 -2.00 3.55 -2.00 321.13 0.00e+00 5.050229e-03 2.217561e-03 4.665888e-03 -6.000000e+00 8.140835e-03 284.36 -2.00 20.00 -2.00 320.51 0.00e+00 5.007 0.002 302.00 328.00 3 2.1748e+00 1.6146e-02 6.1469e-02 -6.0000e+00 4.2868e-01 2.0531e-01 2.1296e-02 4.0349e-02 -6.0000e+00 4.6600e-01 -2.0988e-01 2.0087e-02 2.0615e-02 -6.0000e+00 2.7788e-01 7.4692e-02 9.7092e-03 5.8742e-03 -6.0000e+00 1.1812e-01 2.2721e-04 -9.6938e-04 2.6420e-04 1.1122e-04 -6.0000e+00 8.1978e-03 2.9509e-03 -4.9938e-05 12 9 9 12 1 1 99.96 22.98 0.49 0.00295 -0.00433 23 9 1 5 0 1094.650 26.62 20.00 22.98 22.75 31.4 985.27 -91438 -80483 -47400 -184146 900000 -55432 -61875 -121053 -71476 -12898 -10284 900000 -12574 66081 -120529 -40780 -31645 -25601 -29029 -6123 83812 -24514 -40332 9811 -31896 -35283 -16163 -3751 -17226 -18139 -22623 80856 -11234 -14145 -8847 -3642 11601 19917 25283 2836 -4401 14780 5532 20298 1577 15999 453 12789 9300 6553 10993 1847 2139 8459 9357 -2252 17196 1820 1400 734 -674 6149 1593 11016 3356 5608 2272 -661 -13 -1528 1437 -2081 5528 986 1336 -3380 -1554 -5783 -7835 -1479 -842 -626 -970 -922 -1016 -97 189 -1417 2267 -50 956 -940 -1552 -2710 -2742 -574 -16 1853 -707 533 -1417 -2481 -938 -525 -1401 -2083 -1164 4 800 313 938 923 571 52 -516 -499 42 605 80 1116 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