File name: Pandora183s1_LondonderryNH_20241002_L2Fit_fwvt1c1d20210421p1-8.txt File generation date: 20241003T044448.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20241002_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20241002 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1612 1761 Nominal wavelengths inside fitting window [nm]: 492.0175 492.1392 492.2609 492.3825 492.5042 492.6258 492.7474 492.8690 492.9906 493.1121 493.2337 493.3552 493.4767 493.5982 493.7197 493.8411 493.9626 494.0840 494.2054 494.3268 494.4482 494.5695 494.6909 494.8122 494.9335 495.0548 495.1761 495.2973 495.4186 495.5398 495.6610 495.7822 495.9033 496.0245 496.1456 496.2668 496.3879 496.5090 496.6300 496.7511 496.8721 496.9932 497.1142 497.2351 497.3561 497.4771 497.5980 497.7189 497.8398 497.9607 498.0816 498.2024 498.3233 498.4441 498.5649 498.6857 498.8065 498.9272 499.0479 499.1687 499.2894 499.4100 499.5307 499.6514 499.7720 499.8926 500.0132 500.1338 500.2544 500.3749 500.4954 500.6159 500.7364 500.8569 500.9774 501.0978 501.2183 501.3387 501.4591 501.5794 501.6998 501.8201 501.9405 502.0608 502.1811 502.3013 502.4216 502.5418 502.6621 502.7823 502.9025 503.0226 503.1428 503.2629 503.3830 503.5032 503.6232 503.7433 503.8634 503.9834 504.1034 504.2234 504.3434 504.4634 504.5833 504.7032 504.8232 504.9431 505.0629 505.1828 505.3026 505.4225 505.5423 505.6621 505.7819 505.9016 506.0214 506.1411 506.2608 506.3805 506.5002 506.6198 506.7395 506.8591 506.9787 507.0983 507.2178 507.3374 507.4569 507.5764 507.6959 507.8154 507.9349 508.0543 508.1738 508.2932 508.4126 508.5320 508.6513 508.7707 508.8900 509.0093 509.1286 509.2479 509.3671 509.4864 509.6056 509.7248 509.8440 509.9632 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241002T113749.6Z 9041.484602 63 1 50.54 2 81.21 103.70 79.08 104.88 0.00 1 0.00 1 0 15 4.363e-03 4.302e-03 2.166e-03 2.156e-03 4.352110e+03 1.410809e+02 3.018309e+02 -6.000000e+00 2.466227e+02 283.75 -2.00 20.00 -2.00 505.33 0.00e+00 8.671570e-04 6.006539e-05 4.535991e-05 -6.000000e+00 1.234496e-04 283.75 -2.00 20.00 -2.00 500.36 0.00e+00 7.177206e-01 4.301090e-02 3.231317e-02 -6.000000e+00 8.657047e-02 227.03 -2.00 3.55 -2.00 502.01 0.00e+00 6.183 0.004 489.00 513.00 1 7.2315e+00 3.3006e-03 9.2483e-03 -6.0000e+00 6.6512e-03 1.9688e-02 8.3458e-04 8.9514e-04 -6.0000e+00 1.7055e-03 5.5207e-04 2.3618e-04 2.1668e-04 3.2434e-05 -6.0000e+00 4.5577e-04 -1.2604e-03 1.2901e-04 11 8 0 10 0 0 98.94 22.90 1.03 -0.00126 0.00038 19 4 1 4 0 2659.070 26.51 20.00 22.90 17.08 31.0 947.80 -1120 -520 -422 -252 -162 85 313 -199 779 143 -12 123 17 -237 -206 -485 -221 90 -119 193 130 279 -12 -130 549 556 683 387 -317 20 -490 -103 -371 153 -224 421 307 -131 157 -51 -85 -238 335 593 152 111 386 353 -83 -253 -673 -796 -744 -172 130 2 215 93 30 32 53 965 125 379 487 371 459 282 -543 -144 -226 222 3 -265 342 -934 -516 -467 114 -610 -575 -720 -491 -84 -608 -491 172 181 191 -162 688 586 1180 98 533 157 -141 68 -322 -277 -906 -620 -401 310 -582 -611 311 -583 -62 214 -1 -309 800 231 398 718 790 596 -212 337 62 -268 667 499 -279 18 265 -178 239 -405 -175 -580 -437 197 -673 715 -390 -199 -284 710 -109 175 404 613 346 -301 -359 -635 -862 -144 -1076 -502 -418 -258 -170 91 342 -221 856 157 -13 131 18 -246 -213 -503 -231 96 -130 214 145 311 -13 -136 572 579 706 396 -344 21 -508 -106 -393 154 -233 440 319 -135 159 -52 -86 -242 343 613 159 117 401 362 -84 -250 -648 -750 -694 -162 125 2 216 94 31 33 54 977 128 386 491 369 449 273 -523 -136 -213 209 3 -257 330 -906 -490 -436 105 -566 -535 -676 -464 -80 -586 -476 166 175 184 -158 670 578 1167 97 521 150 -132 62 -289 -246 -812 -567 -379 301 -580 -608 303 -568 -60 208 -1 -311 805 235 407 736 813 613 -217 339 61 -264 651 489 -277 18 261 -176 235 -399 -170 -557 -414 185 -642 685 -385 -200 -289 720 -112 180 391 591 333 -288 -360 -626 -844 -141 SQ 20241002T132307.3Z 9041.557723 126 1 1.80 2 63.64 124.30 62.35 125.73 0.00 1 0.00 1 0 15 2.850e-03 2.845e-03 4.198e-04 4.192e-04 1.779416e+03 2.495672e+01 1.260550e+02 -6.000000e+00 1.610757e+02 283.74 -2.00 20.00 -2.00 505.26 0.00e+00 4.092432e-04 1.161605e-05 2.083060e-05 -6.000000e+00 8.063355e-05 283.74 -2.00 20.00 -2.00 500.46 0.00e+00 1.159507e-01 8.266014e-03 1.388117e-02 -6.000000e+00 5.656164e-02 227.02 -2.00 3.55 -2.00 502.05 0.00e+00 2.239 0.000 489.00 513.00 1 2.4178e+00 6.3481e-04 3.4140e-03 -6.0000e+00 4.3454e-03 1.3133e-02 1.6255e-04 3.6377e-04 -6.0000e+00 1.1147e-03 1.2538e-01 4.9108e-04 4.2605e-05 1.5513e-05 -6.0000e+00 2.9771e-04 8.5389e-04 9.0937e-05 12 1 1 12 1 1 93.16 22.90 0.81 0.00085 0.00426 42 139 1 4 0 40.730 26.51 20.00 22.90 20.08 31.1 967.62 -507 -568 -442 -253 -272 193 419 308 333 259 261 31 -252 -262 -310 -435 -286 -29 -28 -214 66 251 212 449 500 418 441 292 -188 -264 -53 -237 -128 336 119 -161 234 137 -43 -108 21 -12 34 186 309 262 240 175 63 -319 -477 -517 -527 -378 -131 -192 -205 -48 85 345 374 463 415 336 323 204 220 18 -177 -280 -80 -130 -62 46 -43 -293 -262 -213 -188 -437 -348 -413 -352 -143 -73 -229 -144 -19 11 162 278 466 356 263 353 331 30 -246 -429 -552 -410 -316 2 -67 -426 -294 -225 -203 6 101 -21 89 218 268 408 617 566 308 127 35 114 87 261 130 -85 132 129 220 283 117 -124 -182 -153 -320 -93 26 -108 -148 95 106 139 364 316 227 48 -168 -562 -495 -435 -364 -498 -565 -440 -254 -281 199 438 325 352 272 270 32 -259 -266 -313 -441 -293 -30 -29 -223 69 262 221 468 523 437 459 300 -194 -271 -53 -239 -128 347 123 -169 243 141 -45 -112 22 -13 35 192 322 273 249 179 64 -321 -477 -505 -510 -369 -130 -193 -210 -48 86 347 377 467 421 340 323 206 219 18 -177 -275 -79 -128 -61 45 -42 -287 -258 -207 -181 -421 -337 -404 -347 -139 -72 -226 -143 -19 11 160 278 462 356 264 349 328 29 -240 -410 -521 -388 -305 2 -65 -426 -293 -222 -202 6 98 -20 89 216 267 409 619 570 309 126 35 113 85 254 127 -84 130 127 215 276 114 -120 -176 -146 -305 -89 25 -104 -146 92 104 137 360 315 226 48 -164 -553 -476 -414 -348 SQ 20241002T132810.3Z 9041.561231 129 1 49.88 2 62.88 125.43 61.63 126.87 0.00 1 0.00 1 0 15 3.275e-03 3.262e-03 7.915e-04 7.885e-04 1.743294e+03 4.709364e+01 1.265078e+02 -6.000000e+00 1.851009e+02 283.74 -2.00 20.00 -2.00 505.20 0.00e+00 4.900970e-04 2.164509e-05 2.363341e-05 -6.000000e+00 9.266626e-05 283.74 -2.00 20.00 -2.00 500.31 0.00e+00 1.161950e-01 1.557887e-02 1.257156e-02 -6.000000e+00 6.501565e-02 227.02 -2.00 3.55 -2.00 501.91 0.00e+00 2.182 0.000 489.00 513.00 1 6.3810e+00 1.1935e-03 3.3166e-03 -6.0000e+00 4.9947e-03 1.5939e-02 3.0886e-04 3.3974e-04 -6.0000e+00 1.2816e-03 2.3991e-03 8.9156e-04 8.0314e-05 1.6917e-05 -6.0000e+00 3.4216e-04 2.2115e-03 6.4170e-05 10 0 0 10 0 0 99.87 22.91 0.80 0.00221 0.00840 72 15 1 4 0 692.660 26.51 20.00 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