File name: Pandora183s1_LondonderryNH_20241011_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20241012T043728.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20241011_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20241011 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241011T112734.2Z 9050.477479 57 1 49.56 2 84.98 104.82 162.99 2.43 0.00 1 0.00 1 0 25 6.071e-01 8.307e-02 5.265e-01 6.586e-02 1.014844e+00 3.847926e-02 1.205540e-02 -6.000000e+00 3.552683e-01 225.97 -2.00 3.55 -2.00 322.18 0.00e+00 -2.347278e-02 1.311819e-02 3.477859e-03 -6.000000e+00 1.617361e-02 282.63 -2.00 20.00 -2.00 321.57 0.00e+00 9.785 0.018 302.00 328.00 3 -6.4196e-01 1.2875e-01 1.1789e-01 -6.0000e+00 8.8820e-01 2.2574e+00 1.5178e-01 8.3454e-02 -6.0000e+00 9.7574e-01 -2.3249e+00 8.4234e-02 2.6372e-02 -6.0000e+00 5.6952e-01 7.5838e-01 4.7066e-02 1.8848e-02 -6.0000e+00 2.3680e-01 1.9908e-05 -3.7928e-04 1.7748e-03 1.9112e-04 -6.0000e+00 1.6984e-02 3.7802e-03 -9.4826e-05 12 8 8 10 0 0 21.14 22.85 0.96 0.00378 0.00093 30 6 1 5 0 1651.570 26.51 20.01 22.85 11.54 30.5 913.08 4189 137765 -10974 137364 -8862 -19124 900000 -42521 900000 -36530 22472 -8637 900000 154352 -28110 900000 -6863 900000 158494 104010 900000 -12308 291589 63838 136257 29521 62847 4295 -48977 33768 76561 -17208 1645 900000 -51523 900000 900000 900000 -11604 75426 900000 72115 900000 -33436 116080 53139 156569 53211 11449 900000 -213 139718 -37420 24394 25942 87619 69216 9494 2616 -30114 22998 -7180 -46599 52742 162279 200670 -24963 900000 -67441 27606 23336 34751 21278 11177 109942 -14872 132020 -46989 28115 1182 39585 -13113 -7631 46638 21755 46053 -1638 22001 57160 -3513 9432 -37604 -3150 1386 33479 -12624 10069 8723 -4612 9348 -16704 26137 -954 8584 -509 -3148 27846 -6547 20172 -7777 10494 -3252 3698 15400 -13310 6393 7859 -2793 -2273 11632 -4248 -4694 7924 -3608 2597 -9664 -10390 -3380 7300 4517 -3725 7652 -8401 3538 -5097 2261 -694 1050 -88 5718 -34 -4253 2719 594 8824 -1607 8798 -873 -1790 900000 -5866 900000 -5579 1882 -979 900000 9886 -4570 900000 -947 900000 10152 6662 900000 -1274 18677 4089 8727 2836 4025 413 -6535 2163 4904 -1837 158 900000 -7700 900000 900000 900000 -1487 4831 900000 5389 900000 -6246 7435 3404 10028 3408 1039 900000 -25 8949 -7590 3125 3474 6633 6449 1548 411 -5787 2410 -1045 -11125 5221 10394 12853 -5523 900000 -26703 4822 4620 6273 4213 2213 7042 -2858 8456 -11765 3765 248 6684 -4352 -2666 10048 6334 10994 -649 6918 12315 -1309 2856 -17298 -1027 468 9552 -6763 5042 5130 -3410 6042 -13034 11719 -500 4049 -281 -1888 14268 -4689 13825 -7517 10755 -3825 4642 17164 -19182 7370 9061 -3757 -3203 14528 -5987 -6253 8933 -4460 2944 -12070 -12911 -4286 9912 7436 -7563 15243 -21309 8680 -14789 6414 -2068 3106 -260 15017 -86 -10459 6060 SS 20241011T113916.4Z 9050.485607 60 1 49.70 2 82.92 106.87 162.73 10.88 0.00 1 0.00 1 0 25 5.126e-01 1.919e-02 3.660e-01 9.983e-03 9.031142e-01 5.693883e-03 1.024906e-02 -6.000000e+00 2.890033e-01 225.97 -2.00 3.55 -2.00 322.38 0.00e+00 6.840645e-03 3.659593e-03 5.327641e-03 -6.000000e+00 1.335373e-02 282.63 -2.00 20.00 -2.00 321.94 0.00e+00 7.453 0.008 302.00 328.00 3 -3.5779e-01 2.4080e-02 9.1293e-02 -6.0000e+00 7.1467e-01 9.3196e-01 3.4026e-02 5.5150e-02 -6.0000e+00 7.7811e-01 -1.2333e+00 3.2181e-02 2.9827e-02 -6.0000e+00 4.6463e-01 4.8418e-01 1.4499e-02 1.0506e-02 -6.0000e+00 1.9843e-01 1.9534e-04 -1.1021e-03 2.7050e-04 2.1604e-04 -6.0000e+00 1.3552e-02 1.1276e-03 1.5819e-05 12 9 8 11 8 0 63.30 22.85 0.30 0.00113 -0.00715 114 24 1 5 0 435.870 26.51 20.01 22.85 12.33 30.7 920.48 -164808 900000 -140739 26027 -37031 -172195 -217389 -91465 -143042 -145641 -154952 -38676 900000 -64130 -89191 -13588 -64033 -48942 -9919 -31546 57554 10305 -21731 120185 900000 -48053 -25679 -44019 2593 -4118 4417 31493 -15946 96578 -53371 -17546 30393 152656 46838 86696 83236 15470 102254 5844 23503 44097 -17694 90406 2874 62842 11425 46783 32621 80468 29765 30149 31687 29548 26438 22650 61469 35196 16798 18073 37612 7612 20849 24519 15280 18063 18284 14613 10477 -1520 5545 -8646 4543 -144 2666 1034 2568 4546 124 2343 4313 7291 795 1828 4437 833 564 -2038 -8088 -6039 -3455 -3799 -1904 -942 -422 -572 -2135 -2887 -2105 -3385 -4754 -4255 -2911 -885 -60 -1014 112 -523 -8 -750 -2276 -316 -802 -212 585 2293 1232 1830 2772 1593 2717 -512 1037 122 736 531 168 630 -488 -692 -405 -178 861 1179 -64 474 -627 -1962 -692 -3577 900000 -2950 253 -360 -3480 -6671 -890 -2436 -2598 -3016 -376 900000 -884 -2025 -176 -1558 -1111 -161 -639 560 125 -352 1169 900000 -1091 -458 -892 32 -62 74 501 -480 1025 -2408 -512 565 1485 994 1457 1620 629 1809 274 915 1404 -1064 1919 155 2001 677 2193 1933 3203 2080 2160 2270 2117 1848 1563 2882 2335 1545 1902 3560 976 2342 2776 2095 2780 3105 2676 1956 -296 987 -1565 672 -23 480 231 680 1376 44 862 1649 2866 349 815 1917 359 228 -797 -3305 -2574 -1664 -2199 -1288 -740 -369 -509 -1811 -2191 -1411 -2260 -3446 -3259 -2334 -757 -57 -1138 143 -733 -11 -1075 -3191 -421 -1091 -302 876 3469 1833 2560 3680 2081 3403 -643 1255 161 1127 951 340 1381 -1160 -1775 -1114 -514 2499 3447 -187 1308 -1615 -4731 -1585 SS 20241011T115017.2Z 9050.493254 63 1 49.70 2 81.00 108.84 162.22 18.51 0.00 1 0.00 1 0 25 6.678e-01 1.124e-02 2.213e-01 3.236e-03 7.708429e-01 1.765421e-03 9.255842e-03 -6.000000e+00 3.758320e-01 225.97 -2.00 3.55 -2.00 321.87 0.00e+00 7.431948e-03 1.029220e-03 5.668848e-03 -6.000000e+00 1.669722e-02 282.63 -2.00 20.00 -2.00 321.36 0.00e+00 6.055 0.004 302.00 328.00 3 -4.1897e-01 6.7908e-03 7.6445e-02 -6.0000e+00 9.3008e-01 2.8045e-01 1.0374e-02 5.1601e-02 -6.0000e+00 1.0122e+00 -3.5368e-01 1.1132e-02 3.0614e-02 -6.0000e+00 6.0390e-01 1.3006e-01 5.0231e-03 1.1180e-02 -6.0000e+00 2.5643e-01 9.4449e-04 -7.5545e-04 8.8034e-05 1.9880e-04 -6.0000e+00 1.7612e-02 7.8203e-04 9.9671e-06 12 8 8 10 0 0 3.00 22.87 0.33 0.00078 -0.00489 272 57 1 5 0 182.690 26.51 20.01 22.87 13.80 30.7 930.28 -281238 -147363 -184493 -183202 -143756 -260368 -141143 -250133 -149849 -241344 -171266 -193881 -145085 -79903 -144922 41159 -92023 -30711 -79521 -63945 -65035 -73973 -5192 -76170 111578 -69117 -41850 -54513 -43925 -10889 -51606 -1891 -43477 27335 -31598 -24861 -2339 -9686 13670 1357 -1641 8833 18585 5135 16090 3712 3421 15898 4814 14618 9624 9139 10108 11312 12389 7272 10247 3543 8504 -295 7237 8247 5387 11888 5265 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