File name: Pandora183s1_LondonderryNH_20241031_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20241101T044229.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20241031_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20241031 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241031T120521.0Z 9070.503715 72 1 49.94 2 83.07 116.98 75.09 124.27 0.00 1 0.00 1 0 17 6.905e-01 3.264e-02 4.398e-01 2.214e-02 7.247568e-01 1.224239e-02 9.060923e-03 -6.000000e+00 3.937611e-01 224.06 -2.00 3.55 -2.00 322.06 0.00e+00 1.883450e-02 6.581956e-03 1.772376e-03 -6.000000e+00 1.795602e-02 280.12 -2.00 20.00 -2.00 321.58 0.00e+00 7.592 0.008 302.00 328.00 3 6.9308e-01 4.5470e-02 8.4979e-02 -6.0000e+00 9.7091e-01 9.7463e-01 5.6664e-02 4.7528e-02 -6.0000e+00 1.0610e+00 -1.2026e+00 4.5512e-02 2.1161e-02 -6.0000e+00 6.2942e-01 4.6434e-01 2.2324e-02 1.8210e-02 -6.0000e+00 2.6484e-01 6.8597e-05 -1.5692e-03 6.4492e-04 2.6942e-04 -6.0000e+00 1.8651e-02 8.9595e-04 5.5476e-05 12 8 8 10 0 0 74.90 22.74 0.61 0.00090 -0.01090 40 8 1 5 0 1248.190 26.41 19.99 22.74 19.25 31.5 976.04 -93159 88 -47437 117777 900000 900000 900000 -88152 8777 -95415 -78017 -109387 -66245 26768 42306 900000 -29273 900000 -96908 246750 13429 -66608 117755 72824 39587 283986 280660 -41457 34475 -65599 59479 62939 334115 36943 -25954 26188 -3183 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703 4735 1470 3865 -2201 -811 -31 722 429 1742 2222 -1118 -2647 -2698 -2114 -6626 -4514 -856 -5283 1140 -1925 -660 -3076 -988 -1868 775 744 -5028 2494 -2783 1531 -281 -1955 3631 -5591 -831 -1736 1361 -2226 1031 3681 2979 4142 2050 2971 793 1514 -3565 915 620 5798 4302 -2733 1621 -1642 3223 -211 2029 -1447 -1530 -423 -5903 -814 SS 20241031T121620.2Z 9070.511344 75 1 45.10 2 81.29 118.98 73.51 126.45 0.00 1 0.00 1 0 17 5.753e-01 1.216e-02 2.542e-01 5.334e-03 6.536804e-01 2.887968e-03 7.466327e-03 -6.000000e+00 3.236816e-01 224.06 -2.00 3.55 -2.00 321.73 0.00e+00 1.709866e-03 1.577796e-03 3.782857e-03 -6.000000e+00 1.431795e-02 280.11 -2.00 20.00 -2.00 321.22 0.00e+00 6.238 0.005 302.00 328.00 3 4.5840e-01 1.0582e-02 7.2833e-02 -6.0000e+00 7.9802e-01 1.3552e-01 1.5435e-02 4.3060e-02 -6.0000e+00 8.7017e-01 -2.0588e-01 1.6408e-02 2.2389e-02 -6.0000e+00 5.1757e-01 7.1932e-02 7.5737e-03 6.5182e-03 -6.0000e+00 2.1942e-01 4.0728e-04 -4.6939e-04 1.5755e-04 1.0524e-04 -6.0000e+00 1.5252e-02 -1.0655e-04 2.9271e-05 12 9 9 12 1 1 79.11 22.73 0.48 -0.00011 -0.00363 98 23 1 5 0 455.490 26.41 20.00 22.73 20.43 31.5 984.45 -211477 -217496 -163665 -127369 -190255 -182484 900000 -199613 -211940 -175648 -194207 -29853 -140822 155699 -68563 39233 -66361 -99474 -46896 -67463 41511 -56761 20474 -5603 -9942 -18142 -6323 -27866 -51412 8883 -33135 44073 -5357 3061 -2745 -8070 4485 -12681 11071 2080 12009 317 11559 2875 1067 18724 -4798 36757 5072 13485 7744 8048 16991 3452 12745 11806 15165 4550 3810 6853 635 4811 5934 15151 504 7807 -4407 520 -1178 968 4017 320 3428 1874 975 -2857 -536 -2741 -4505 -1576 -2339 643 -2549 -335 -766 -777 2177 156 3830 1164 1203 -2725 -1503 -2001 -3295 -547 -1683 2313 -887 725 -1183 -1909 -1861 -1990 -1666 -1762 -1195 -1301 885 612 791 1093 151 -82 -985 287 -502 22 -175 389 1266 566 1290 409 330 -1141 -43 893 -248 456 264 -38 -466 -183 -478 -413 821 570 146 -386 382 -657 -513 -2031 -2922 -1419 -773 -1979 -1661 900000 -2596 -3583 -2284 -3199 -155 -1831 810 -713 204 -949 -2199 -671 -1257 294 -1074 184 -72 -146 -309 -99 -527 -1191 118 -783 583 -137 80 -74 -221 117 -462 393 98 591 19 656 184 70 1054 -349 1825 362 944 637 746 1591 405 1458 1429 1843 618 506 948 95 758 1056 2798 116 1640 -1025 118 -299 279 1253 109 1131 596 287 -781 -133 -697 -1298 -526 -927 284 -1289 -176 -433 -471 1351 102 2420 731 706 -1555 -813 -1119 -2093 -393 -1422 2159 -939 760 -1189 -1737 -1545 -1662 -1499 -1686 -1201 -1405 1028 803 1154 1689 238 -125 -1430 395 -701 32 -273 628 2010 872 1906 590 459 -1556 -56 1213 -387 800 510 -78 -1018 -426 -1194 -1085 2182 1545 398 -1012 937 -1533 -1164 SS 20241031T123102.0Z 9070.521550 80 1 49.70 2 78.97 121.72 71.48 129.45 0.00 1 0.00 1 0 17 2.770e-01 6.982e-03 7.688e-02 1.823e-03 5.474162e-01 9.417970e-04 6.478560e-03 -6.000000e+00 1.547731e-01 224.06 -2.00 3.55 -2.00 321.01 0.00e+00 2.608869e-03 4.222833e-04 2.819571e-03 -6.000000e+00 6.853454e-03 280.11 -2.00 20.00 -2.00 320.46 0.00e+00 5.041 0.002 302.00 328.00 3 3.6562e-02 3.0672e-03 5.8362e-02 -6.0000e+00 3.8170e-01 2.7287e-02 4.1212e-03 3.3066e-02 -6.0000e+00 4.1610e-01 -4.1473e-02 4.1746e-03 1.7799e-02 -6.0000e+00 2.4825e-01 3.6136e-03 2.0309e-03 5.5490e-03 -6.0000e+00 1.0562e-01 2.0991e-03 -4.7812e-04 5.2858e-05 8.2964e-05 -6.0000e+00 7.3004e-03 -6.6421e-04 2.2838e-05 11 8 0 10 0 0 12.17 22.71 0.30 -0.00066 -0.00426 341 71 1 5 0 145.710 26.32 20.01 22.71 22.35 31.7 996.60 -89945 -65886 -98126 -62260 -122439 -99243 -80160 -102913 -26940 -94453 -71890 -91684 -45457 -54908 -39378 -13946 -25214 -2884 -28349 3608 -33899 -21758 -22494 -21812 -11955 -24104 -10342 -23463 -15270 -13237 -10002 -4079 -4725 -4171 -11366 -2673 -11641 -3691 -1002 -1495 -1722 -774 1355 -1016 2810 212 1752 -764 2881 2502 2294 1899 1837 2881 2061 2950 1694 327 1904 -547 801 2471 2358 3454 2158 2039 -594 332 423 1747 2124 1406 1368 583 647 -2062 -1945 -3711 -862 -1284 -1233 -508 -2202 -1643 -377 -133 108 1192 1033 1095 642 -498 -1145 -1387 -657 -861 362 899 238 -158 -530 -1595 -1235 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