File name: Pandora183s1_LondonderryNH_20241111_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20241112T044112.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20241111_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20241111 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241111T123730.4Z 9081.526046 123 1 25.81 2 80.58 124.96 143.29 357.46 0.00 1 0.00 1 0 17 4.280e-01 2.282e-02 3.978e-01 1.815e-02 6.110361e-01 9.716515e-03 7.394638e-03 -6.000000e+00 2.386187e-01 223.06 -2.00 3.55 -2.00 321.43 0.00e+00 1.208304e-02 4.636835e-03 2.037249e-03 -6.000000e+00 1.140080e-02 278.73 -2.00 20.00 -2.00 320.91 0.00e+00 5.816 0.004 302.00 328.00 3 2.2641e+00 3.2925e-02 6.5450e-02 -6.0000e+00 5.8714e-01 3.9288e-01 4.3434e-02 3.3136e-02 -6.0000e+00 6.4106e-01 -4.4575e-01 4.1596e-02 2.1152e-02 -6.0000e+00 3.8244e-01 1.7186e-01 2.0088e-02 1.3734e-02 -6.0000e+00 1.6585e-01 9.1229e-05 -1.3840e-03 5.3573e-04 1.6155e-04 -6.0000e+00 1.1595e-02 -2.1989e-03 8.3777e-05 12 9 9 12 1 1 99.51 22.83 0.45 -0.00220 -0.01260 10 4 1 5 0 2345.300 26.51 20.00 22.83 17.66 31.1 966.80 900000 37869 900000 -113898 900000 -169564 -167388 -94314 -52667 6792 -163937 900000 101989 89563 86698 15807 11109 -1840 82062 -28192 52340 -20022 57359 -20771 -13520 -21948 122368 211971 8697 -61658 6569 -62611 -16910 -18552 -29463 22013 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350 -2065 -1218 -437 908 2077 820 -1160 -2017 -1298 -1679 -3881 -446 -452 1946 2452 -4076 922 -3327 -801 -334 1933 -2153 -551 -579 -1846 2568 -1028 745 1375 734 -1087 -920 1877 -3365 87 1140 -506 2536 3286 2706 -1403 -816 520 -457 1328 4055 -565 -1985 -877 -2799 1277 -5550 3838 2705 3516 1939 -174 -1503 -5515 SS 20241111T124732.9Z 9081.533019 129 1 4.71 2 79.09 126.87 143.26 1.45 0.00 1 0.00 1 0 25 4.305e-01 3.641e-02 3.603e-01 2.631e-02 5.565523e-01 1.374100e-02 7.974716e-03 -6.000000e+00 2.445335e-01 223.06 -2.00 3.55 -2.00 320.75 0.00e+00 9.233466e-04 5.226033e-03 7.302156e-03 -6.000000e+00 1.067721e-02 278.73 -2.00 20.00 -2.00 320.15 0.00e+00 5.092 0.002 302.00 328.00 3 2.5787e+00 4.2286e-02 6.8243e-02 -6.0000e+00 6.0456e-01 3.5316e-01 5.1812e-02 5.6898e-02 -6.0000e+00 6.6247e-01 -5.0810e-01 4.1919e-02 2.0896e-02 -6.0000e+00 3.9305e-01 2.1755e-01 2.1001e-02 4.6762e-03 -6.0000e+00 1.6586e-01 1.4738e-04 -2.1182e-03 7.7267e-04 9.7230e-05 -6.0000e+00 1.1669e-02 -2.0621e-03 -7.5050e-06 12 9 9 12 1 1 999.00 22.83 0.40 -0.00206 -0.01798 1 4 1 5 0 2351.450 26.51 20.00 22.83 17.90 31.3 968.13 900000 -117401 148350 -79882 22461 -65596 -85858 900000 -129386 -129106 -111139 151331 96066 -92373 93779 900000 900000 33009 900000 -43745 151969 61724 114793 25828 81679 95479 32125 65257 -46330 24832 67189 -8382 -46227 6228 14860 -42729 6010 -26992 13504 28993 43545 8566 -15777 50181 32383 8181 -4770 34733 34345 31876 9146 24685 -2286 14453 24405 13372 24462 18819 16468 4005 20390 5953 6687 18518 -1966 4482 21829 -2251 12493 4688 -1106 -1421 15241 -5947 5517 -222 -17413 10424 10378 -6116 1683 1512 -2140 -2600 4760 -2368 -1490 -435 -70 -5461 -3763 743 -5389 890 -10547 -2736 -2280 -1595 -716 -3233 868 -4294 -3687 -4850 -2849 -1285 -2574 -2838 722 5675 -1427 4262 -795 2058 -1201 -385 -372 -426 1222 2329 1262 1004 2232 2700 1439 1729 3080 1844 -992 780 2261 2455 -1397 -1868 269 -2118 650 -17 2223 -1159 476 -1223 -2644 900000 -6770 3802 -3242 576 -1821 -2934 900000 -8291 -8824 -6992 3879 2462 -6887 2404 900000 900000 1154 900000 -3567 3895 1726 2942 1083 2093 2447 1422 1977 -3994 1041 2035 -625 -5709 493 1039 -4978 493 -3208 1419 3121 4576 1361 -3014 5531 4233 1363 -905 4451 4489 4412 1711 4365 -574 3297 5317 3359 5643 4582 3968 1057 4599 1663 2074 5695 -786 1631 6378 -836 4291 1995 -556 -754 6836 -3140 2390 -91 -7721 3420 3671 -2979 884 907 -1464 -1893 3428 -1960 -1173 -350 -57 -4955 -3135 548 -3991 621 -9029 -2482 -2152 -1706 -833 -3894 946 -4462 -3828 -5096 -2881 -1362 -2909 -3425 912 7577 -2254 6722 -1318 3188 -1805 -545 -526 -630 1894 3756 2064 1598 3391 3951 2045 2357 3976 2475 -1525 1319 4104 4702 -2897 -4108 566 -4818 1472 -38 5039 -2620 1088 -2683 -5699 SS 20241111T125203.3Z 9081.536149 132 1 43.82 2 78.43 127.73 143.20 3.23 0.00 1 0.00 1 0 17 2.478e-01 7.408e-03 8.334e-02 2.214e-03 5.371323e-01 1.129818e-03 6.305083e-03 -6.000000e+00 1.379545e-01 223.06 -2.00 3.55 -2.00 320.87 0.00e+00 3.360166e-03 4.810265e-04 2.210224e-03 -6.000000e+00 6.096373e-03 278.73 -2.00 20.00 -2.00 320.32 0.00e+00 4.826 0.002 302.00 328.00 3 5.8760e-01 3.5732e-03 5.5450e-02 -6.0000e+00 3.3963e-01 5.0702e-02 4.7243e-03 3.0102e-02 -6.0000e+00 3.7056e-01 -4.6088e-02 4.7642e-03 1.7145e-02 -6.0000e+00 2.2106e-01 5.3195e-03 2.3510e-03 6.1576e-03 -6.0000e+00 9.4155e-02 1.4660e-03 -6.0356e-04 6.4016e-05 7.6621e-05 -6.0000e+00 6.5285e-03 -2.0373e-03 3.6799e-05 12 9 1 12 1 1 99.94 22.83 0.26 -0.00204 -0.00657 181 43 1 5 0 240.690 26.51 20.00 22.83 17.93 31.3 969.06 -115427 -90549 -43817 -69515 -48791 -122824 -50570 -100566 -85722 -62972 -59023 -30649 -54271 -12681 -50947 -5216 -23662 -16892 -2961 -4921 9902 -22715 6468 -21767 -2456 -13047 -16244 -5858 -18837 -6928 -14326 2703 -976 -2117 -9723 -7795 -4772 -8667 2605 -3234 -1089 -1456 2956 366 1129 2648 -3855 3904 -3097 647 -1138 3471 1709 1494 3317 709 2831 -2061 215 -650 484 3189 3558 4363 1483 1625 -212 1 2943 1631 2386 1086 1539 594 -449 -1581 -2099 -2991 -2742 -1222 -1940 -801 -2463 -1147 -817 -562 1096 613 2062 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