File name: Pandora183s1_LondonderryNH_20241115_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20241116T044829.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20241115_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20241115 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241115T121411.4Z 9085.509854 279 1 49.98 2 85.04 121.27 98.39 307.18 0.00 1 0.00 1 0 25 4.735e-01 4.865e-02 4.778e-01 4.646e-02 8.763599e-01 2.627699e-02 1.062345e-02 -6.000000e+00 2.693296e-01 222.77 -2.00 3.55 -2.00 322.21 0.00e+00 -2.041146e-02 1.044154e-02 1.251228e-03 -6.000000e+00 1.310924e-02 278.24 -2.00 20.00 -2.00 321.68 0.00e+00 9.893 0.018 302.00 328.00 3 -7.6472e-01 9.0131e-02 1.0874e-01 -6.0000e+00 6.6638e-01 1.6681e+00 1.0853e-01 5.3210e-02 -6.0000e+00 7.3027e-01 -1.9224e+00 7.2111e-02 2.3872e-02 -6.0000e+00 4.3358e-01 7.1141e-01 3.8508e-02 1.8110e-02 -6.0000e+00 1.8529e-01 2.8980e-05 -1.4770e-03 1.3407e-03 2.8939e-04 -6.0000e+00 1.2953e-02 -1.5797e-03 6.9383e-05 12 8 8 10 0 0 41.97 22.85 1.15 -0.00158 -0.01268 37 8 1 5 0 1350.450 26.51 20.00 22.85 0.86 29.3 851.65 64254 134663 102314 -33443 173266 -10750 19321 -33556 222911 900000 900000 -78779 -20335 900000 -7192 16361 82468 900000 900000 -36893 900000 66712 900000 75579 18771 75054 -10044 96987 -40052 900000 -24589 900000 -9315 55402 76124 -36215 67176 900000 1612 -11318 45847 36411 47651 40871 2700 44895 51765 900000 141832 54288 77036 54732 -37392 19107 82429 9746 79910 11551 124912 59829 38664 50753 30588 18854 -5033 14827 -57786 11214 65093 45322 47039 23573 36576 17774 31997 70132 11555 -5861 -2316 17023 5094 -15935 -9147 -7948 -8092 -445 22464 -9420 3298 8223 12656 8029 -5423 18364 -31 -6357 -11030 524 -1224 -90 -3259 -1292 -2849 -2698 -6085 -8888 -4383 13148 4110 -2863 4114 4852 1192 3879 -5351 -1627 -4940 422 2813 -4270 4792 3117 2554 -2546 -6367 -1484 2780 5867 -357 4843 -2458 -1286 985 -911 -657 -2494 2296 672 4042 440 962 -2348 -3677 2905 6089 4626 -3490 7834 -598 874 -2684 10079 900000 900000 -11782 -1768 900000 -625 1195 3729 900000 900000 -4235 900000 3016 900000 3417 1415 3394 -1022 4385 -3924 900000 -1946 900000 -772 2505 3442 -3411 3037 900000 146 -1407 3628 3293 3770 3234 285 2876 2926 900000 6413 3347 4117 4050 -7531 2356 5760 1482 6241 1757 5648 4673 3496 4172 3395 2635 -952 2255 -17815 1798 6689 6520 7347 4845 6465 3507 4866 6342 1710 -1036 -438 3149 1256 -5633 -3384 -3104 -3360 -181 7572 -4453 1356 3076 4214 2640 -2006 5661 -13 -3371 -7163 351 -926 -68 -2411 -839 -1686 -1732 -3952 -6953 -3468 9452 3623 -3133 4818 6187 1633 5139 -7501 -2126 -6723 570 3931 -6622 6651 4186 3314 -3397 -8578 -1852 3244 7056 -532 7992 -4912 -2768 2222 -2261 -1757 -7184 6437 1939 11186 1201 2413 -5637 -8612 SS 20241115T122547.7Z 9085.517913 282 1 49.52 2 83.25 123.36 99.96 309.29 0.00 1 0.00 1 0 17 4.994e-01 1.864e-02 3.196e-01 8.979e-03 7.787844e-01 4.969941e-03 9.020942e-03 -6.000000e+00 2.777397e-01 222.77 -2.00 3.55 -2.00 322.17 0.00e+00 5.467880e-03 2.885656e-03 5.837962e-03 -6.000000e+00 1.257890e-02 278.24 -2.00 20.00 -2.00 321.72 0.00e+00 7.763 0.009 302.00 328.00 3 -6.0213e-01 1.9220e-02 9.0995e-02 -6.0000e+00 6.8347e-01 7.0009e-01 2.7400e-02 5.3408e-02 -6.0000e+00 7.4601e-01 -9.2864e-01 2.6942e-02 2.9251e-02 -6.0000e+00 4.4535e-01 3.6654e-01 1.2316e-02 9.5893e-03 -6.0000e+00 1.9104e-01 2.2868e-04 -1.0075e-03 2.5674e-04 1.8642e-04 -6.0000e+00 1.3190e-02 -1.2835e-03 1.0743e-05 12 8 8 10 0 0 43.12 22.85 0.38 -0.00128 -0.00885 124 26 1 5 0 399.290 26.51 19.99 22.85 1.71 29.5 859.52 -165723 900000 8253 -105655 -184456 -136558 -158574 176379 -111342 -159599 48619 -205924 900000 -134201 -41173 -31280 37841 13408 31124 46410 -81738 165861 -34283 66971 6893 -26517 13562 -13504 -32929 -17716 25571 -39995 38660 -4553 21334 -3160 559 45237 34520 76780 55370 12293 40966 8972 46328 9459 37059 36582 23388 34235 33820 38543 25357 26219 29001 31215 36141 17064 12454 15102 12500 13605 26440 10853 18864 11579 18150 14088 9165 19334 5364 12996 6246 13310 -389 -6775 -4032 6339 6352 -2856 2650 3087 999 -35 177 598 -2174 2863 -1928 3382 1472 -2480 -2208 -4407 -2457 -3871 -1040 -1161 -2375 -2520 -1930 -1667 -2588 644 -5539 -1829 -2498 -1604 -1126 -51 998 -6 1152 -718 -1601 -1027 199 1382 -585 1822 -254 2616 1925 2455 923 -151 737 739 285 30 93 401 -323 184 -105 160 120 480 -279 346 -352 -942 -967 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1.358153e-02 278.24 -2.00 20.00 -2.00 321.21 0.00e+00 6.434 0.005 302.00 328.00 3 -5.9489e-01 6.3972e-03 7.4318e-02 -6.0000e+00 7.5698e-01 2.3750e-01 9.3642e-03 4.1459e-02 -6.0000e+00 8.2617e-01 -2.8954e-01 1.0101e-02 2.5405e-02 -6.0000e+00 4.9282e-01 1.0597e-01 4.6863e-03 1.0110e-02 -6.0000e+00 2.0992e-01 9.0188e-04 -7.7074e-04 9.5070e-05 1.5797e-04 -6.0000e+00 1.4574e-02 -1.9456e-03 2.0181e-05 12 8 8 10 0 0 40.43 22.85 0.31 -0.00195 -0.00774 263 55 1 5 0 188.570 26.51 20.01 22.85 3.18 29.6 870.66 -244365 -136989 -193531 -84784 -183193 -182370 -150931 -198939 -137588 -193752 -135855 -147093 -126411 -120185 -76277 -47087 -60979 -53707 -30563 -16011 -72481 -20866 -22010 -36477 -20583 -41949 -9126 -59443 -21863 -53904 -12884 -20184 -4379 3931 -12950 30254 -30565 13151 -6174 -883 3354 6969 11792 6754 4651 1855 4876 6990 2360 8893 7102 10650 7862 11178 6869 4992 7722 -2096 7203 4469 8557 5194 6592 7116 4953 2238 2706 4412 2040 6432 3379 2525 4349 1407 1474 -2143 -4382 -5655 -1338 -2673 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