File name: Pandora183s1_LondonderryNH_20241118_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20241119T093814.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20241118_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20241118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241118T134614.0Z 9088.573773 329 1 50.12 2 72.88 139.51 78.66 297.65 0.00 1 0.00 1 0 25 6.018e-02 6.337e-03 7.157e-03 4.428e-04 4.191158e-01 2.201564e-04 5.002804e-03 -6.000000e+00 3.346970e-02 222.73 -2.00 3.55 -2.00 319.73 0.00e+00 1.819654e-03 6.451113e-05 1.050609e-03 -6.000000e+00 1.475803e-03 277.90 -2.00 20.00 -2.00 319.12 0.00e+00 3.348 0.001 302.00 328.00 3 -4.8612e-01 6.2488e-04 3.9357e-02 -6.0000e+00 8.2364e-02 1.5176e-02 7.4518e-04 2.1926e-02 -6.0000e+00 8.9894e-02 7.1523e-04 6.2702e-04 1.1465e-02 -6.0000e+00 5.3615e-02 -1.0740e-02 3.2901e-04 3.7067e-03 -6.0000e+00 2.2837e-02 1.9517e-02 -4.1600e-04 1.2821e-05 4.3328e-05 -6.0000e+00 1.5856e-03 -2.9848e-03 2.4359e-05 10 0 0 10 0 0 92.77 22.83 0.24 -0.00298 -0.00611 1262 262 1 5 0 39.360 26.51 20.00 22.83 13.39 30.5 940.74 -21901 -14358 -17084 -17907 -22561 -24247 -21926 -15586 -17286 -16361 -18754 -18031 -12535 -10633 -4691 -4758 -2333 -2828 -1253 -619 -999 -1182 -2100 -744 -2183 -2159 -2837 -3741 -4082 -4063 -1584 -831 751 -1378 -4440 -4647 -4689 -2733 -2022 -902 -1660 -1213 -929 -584 58 248 98 -436 -539 -735 771 823 1249 1389 893 1106 821 195 -271 79 924 1951 2540 2992 1519 559 -69 -646 971 1082 997 1239 682 1004 191 -393 -1321 -2100 -1073 -1159 -1138 -1242 -1989 -1433 -705 -314 53 545 998 987 622 94 -899 -537 -567 -509 412 846 115 -312 -594 -1417 -902 -337 -1336 -1282 -890 -741 117 603 918 468 399 27 -250 65 222 81 406 114 29 470 733 418 481 -290 -164 852 99 -77 -292 -498 -363 -89 -175 -153 241 642 132 3 -52 -518 -425 -359 -258 -341 -358 -428 -436 -400 -300 -387 -396 -477 -472 -361 -367 -185 -220 -116 -152 -71 -37 -68 -80 -146 -54 -175 -183 -248 -319 -332 -330 -138 -82 82 -167 -537 -538 -579 -385 -344 -182 -382 -297 -237 -153 15 66 26 -117 -145 -204 226 265 432 514 349 445 341 82 -111 32 378 853 1228 1587 851 302 -35 -328 518 659 676 881 489 689 122 -228 -703 -1086 -584 -727 -821 -1009 -1608 -1213 -632 -301 54 567 1036 991 583 82 -805 -472 -537 -494 449 1034 154 -416 -744 -1627 -954 -361 -1563 -1590 -1154 -1013 169 948 1424 754 631 44 -380 93 317 121 646 192 50 780 1176 649 711 -414 -223 1171 150 -129 -523 -853 -641 -165 -344 -317 511 1380 285 5 -103 -994 -795 SS 20241118T135616.2Z 9088.580743 332 1 50.26 2 71.72 141.67 80.21 299.12 0.00 1 0.00 1 0 17 4.809e-02 6.458e-03 5.210e-03 3.895e-04 3.975859e-01 1.922112e-04 4.739166e-03 -6.000000e+00 2.674185e-02 222.73 -2.00 3.55 -2.00 319.50 0.00e+00 1.606462e-03 5.242377e-05 9.260354e-04 -6.000000e+00 1.179126e-03 277.89 -2.00 20.00 -2.00 318.87 0.00e+00 3.147 0.001 302.00 328.00 3 -4.9619e-01 5.3801e-04 3.7027e-02 -6.0000e+00 6.5808e-02 1.3628e-02 6.3387e-04 2.0613e-02 -6.0000e+00 7.1823e-02 2.1167e-03 5.1154e-04 1.0685e-02 -6.0000e+00 4.2837e-02 -1.0621e-02 2.7037e-04 3.3886e-03 -6.0000e+00 1.8247e-02 2.4485e-02 -3.5696e-04 1.1300e-05 3.7209e-05 -6.0000e+00 1.2668e-03 -3.1361e-03 3.3988e-05 11 8 0 10 0 0 99.71 22.83 0.23 -0.00314 -0.00582 1450 301 1 5 0 34.250 26.51 20.00 22.83 14.52 30.8 950.22 -16452 -9793 -14398 -13791 -20171 -18935 -18769 -14152 -10675 -13518 -13407 -14643 -9036 -7666 -3183 -2687 -2537 -638 -952 406 -1296 -873 -634 -537 -1474 -1494 -1632 -3720 -3755 -3533 -806 -652 979 -1293 -4348 -4008 -4804 -3400 -2079 -1302 -1425 -926 -473 -670 404 18 -132 -273 -807 -440 671 918 1056 1586 860 1216 711 179 -1 90 1089 1799 2452 2916 1440 429 -233 -512 987 1051 840 1154 584 682 375 -563 -1078 -2072 -1104 -1182 -1199 -1217 -2116 -1385 -728 -349 54 483 1069 922 652 55 -860 -490 -543 -500 339 915 125 -274 -699 -1300 -964 -353 -1385 -1254 -851 -786 83 563 918 412 452 83 -292 54 175 142 395 133 78 492 786 413 560 -256 -135 834 167 -53 -338 -509 -345 -39 -149 -142 252 609 98 -72 -46 -551 -418 -328 -214 -355 -335 -472 -407 -417 -338 -281 -399 -404 -460 -309 -313 -150 -147 -152 -44 -70 31 -104 -70 -51 -46 -138 -148 -165 -372 -355 -332 -80 -74 122 -178 -596 -522 -672 -545 -400 -298 -368 -254 -135 -196 118 5 -39 -81 -241 -134 215 322 399 637 366 530 320 81 -1 39 482 852 1281 1665 865 248 -127 -276 556 677 602 868 443 496 254 -347 -605 -1128 -630 -775 -902 -934 -1779 -1217 -678 -347 56 522 1152 963 635 49 -796 -444 -480 -497 378 1138 169 -371 -892 -1517 -1041 -385 -1656 -1589 -1126 -1096 122 823 1440 671 720 125 -445 77 250 213 629 207 122 821 1269 645 833 -367 -184 1148 253 -88 -552 -865 -603 -72 -290 -290 526 1293 210 -150 -90 -1049 -777 SS 20241118T140206.0Z 9088.584792 336 1 8.61 2 71.07 142.95 81.11 299.98 0.00 1 0.00 1 0 17 4.021e-02 7.450e-03 1.921e-02 2.112e-03 3.869525e-01 1.040061e-03 4.676849e-03 -6.000000e+00 2.236082e-02 222.73 -2.00 3.55 -2.00 318.89 0.00e+00 1.502176e-03 2.379440e-04 7.494987e-04 -6.000000e+00 9.859469e-04 277.89 -2.00 20.00 -2.00 318.27 0.00e+00 3.045 0.000 302.00 328.00 3 1.5982e+00 2.8309e-03 3.5869e-02 -6.0000e+00 5.5027e-02 3.6009e-02 3.2652e-03 1.9912e-02 -6.0000e+00 6.0056e-02 -8.7458e-03 2.4017e-03 1.0149e-02 -6.0000e+00 3.5819e-02 -4.1689e-03 1.2778e-03 3.1442e-03 -6.0000e+00 1.5258e-02 3.3280e-03 -3.6952e-04 5.9643e-05 3.2985e-05 -6.0000e+00 1.0592e-03 -3.0869e-03 4.2534e-05 12 9 1 12 1 1 99.96 22.84 0.27 -0.00309 -0.00586 33 41 1 5 0 253.160 26.51 20.00 22.84 15.26 31.0 955.28 -14805 67 -12971 -11567 -10675 -19987 -8664 -14176 -5448 -11347 -12076 -13333 -11577 -5500 -4264 648 -1987 1692 -1651 2587 1425 -963 158 -1798 1147 -299 -2505 -1135 -2797 -4408 -175 -1123 -1620 589 -4840 -3399 -5101 -2406 -1708 -1509 -148 -368 140 -709 918 147 656 -260 -1043 435 -87 1374 1057 1492 1241 1376 1479 -346 1241 123 1069 1855 2707 2928 868 968 -560 -556 764 772 560 735 584 808 208 -1048 -1692 -2769 -1009 -1308 -988 -1393 -2196 -990 -902 -273 186 467 1219 811 906 -238 -984 -747 -623 -393 99 1198 48 -79 -787 -1315 -932 -588 -1435 -1418 -770 -780 359 667 1141 554 330 150 -66 181 183 262 300 125 104 506 718 442 644 -281 57 989 170 10 -476 -465 -331 -5 -28 -320 156 516 106 43 77 -680 -451 -432 2 -466 -405 -334 -700 -280 -543 -218 -523 -572 -656 -641 -345 -317 53 -183 160 -172 270 156 -108 18 -218 145 -40 -353 -152 -360 -571 -24 -172 -280 107 -896 -591 -959 -511 -437 -461 -50 -121 48 -250 320 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