File name: Pandora183s1_LondonderryNH_20241120_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20241121T044344.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20241120_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20241120 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241120T122046.4Z 9090.514426 277 1 49.20 2 85.08 123.04 46.17 263.82 0.00 1 0.00 1 0 61 5.409e-01 5.646e-02 4.855e-01 5.111e-02 8.868474e-01 2.870883e-02 1.000230e-02 -6.000000e+00 3.042416e-01 222.71 -2.00 3.55 -2.00 322.11 0.00e+00 -1.828941e-03 1.033659e-02 3.710027e-03 -6.000000e+00 1.403254e-02 277.68 -2.00 20.00 -2.00 321.59 0.00e+00 9.947 0.019 302.00 328.00 3 -9.4803e-01 9.5509e-02 1.1064e-01 -6.0000e+00 7.4846e-01 1.9984e+00 1.1148e-01 5.2695e-02 -6.0000e+00 8.1829e-01 -2.0617e+00 6.5404e-02 2.3063e-02 -6.0000e+00 4.8651e-01 7.0070e-01 3.6880e-02 7.4866e-03 -6.0000e+00 2.0918e-01 2.7393e-05 -1.4840e-04 1.4198e-03 1.0316e-04 -6.0000e+00 1.4979e-02 -2.5126e-03 8.5972e-05 12 8 8 10 0 0 36.24 22.83 0.78 -0.00251 -0.00363 35 7 1 5 0 1405.380 26.51 20.00 22.83 7.39 30.2 900.96 25739 206602 -39928 900000 104275 900000 2982 20963 105163 8991 9070 -45347 46895 -10161 900000 35368 128957 154644 34033 52839 20010 900000 26142 -29620 124506 138012 131485 -75477 900000 63055 184482 -4517 -41675 23227 49188 900000 121767 900000 48373 75825 84143 86464 900000 8195 900000 39527 100615 -6383 6396 58846 -60496 900000 50322 157120 64282 61087 52432 -21028 20965 35551 89074 -32222 98010 -28660 16349 88985 -170 69712 31786 59961 2486 64348 -11648 8968 6956 -46160 -38045 -13989 2959 14336 45460 11750 490 25751 12368 -2674 -10154 13741 -2136 17485 6044 16228 5622 6110 40244 -11254 12606 -601 2693 -6032 -18059 6645 3034 4042 -7276 -3520 -8717 2023 -1763 -7132 4329 -4514 1009 7149 -2722 3648 3449 5004 -6251 3427 860 3221 -765 7075 -6399 -882 3949 -6597 7055 -763 1274 2286 -507 -1763 -1266 -698 461 1128 -2493 1068 -56 1121 438 2652 10278 -7945 900000 5187 900000 217 1284 5232 619 590 -5032 2333 -1050 900000 2978 6415 7693 2995 3640 1761 900000 1951 -3929 6194 6866 6541 -13142 900000 3137 9178 -431 -6392 1926 2855 900000 6058 900000 3209 4401 4884 5018 900000 985 900000 3113 5005 -767 752 4258 -14295 900000 5007 7816 6105 6078 5691 -4565 2750 3698 5237 -6703 6206 -7258 2810 7244 -33 6936 5031 8135 652 9313 -3477 1987 1384 -13570 -9463 -2784 562 2918 8018 3348 173 7453 4307 -1137 -4822 5220 -937 6010 2159 4917 1856 2128 11466 -6362 6613 -419 2010 -4965 -15681 3997 1688 2194 -4739 -2340 -6465 1611 -1640 -7386 5039 -5696 1365 8997 -3643 4446 4272 6422 -9516 4876 1223 4247 -1009 8411 -8468 -1075 4499 -8992 9862 -1348 2484 4811 -1177 -4482 -3457 -1996 1330 3277 -7454 2927 -145 2638 1005 SS 20241120T123215.9Z 9090.522406 280 1 49.91 2 83.34 125.11 48.23 265.85 0.00 1 0.00 1 0 25 6.336e-01 1.856e-02 3.562e-01 9.843e-03 7.676570e-01 5.453686e-03 8.446093e-03 -6.000000e+00 3.524111e-01 222.71 -2.00 3.55 -2.00 322.18 0.00e+00 1.887975e-03 3.183983e-03 3.429274e-03 -6.000000e+00 1.593566e-02 277.68 -2.00 20.00 -2.00 321.73 0.00e+00 7.849 0.009 302.00 328.00 3 -4.9475e-01 2.1194e-02 8.8799e-02 -6.0000e+00 8.6691e-01 6.0241e-01 3.0948e-02 4.6252e-02 -6.0000e+00 9.4647e-01 -8.2231e-01 3.1043e-02 2.6642e-02 -6.0000e+00 5.6474e-01 3.2403e-01 1.4089e-02 9.4990e-03 -6.0000e+00 2.4234e-01 2.0038e-04 -4.0465e-04 2.8618e-04 1.4851e-04 -6.0000e+00 1.6993e-02 -8.3793e-04 -4.4201e-06 12 8 8 10 0 0 -13.83 22.83 0.43 -0.00084 -0.00388 114 24 1 5 0 437.670 26.51 19.99 22.83 8.34 30.2 907.50 -98607 900000 -163281 48628 900000 -3822 -224937 34827 -140387 -165794 -151701 -207615 -133256 -120127 -63875 -71794 -47844 54093 -29145 143751 -61219 139614 -39714 -24314 -12745 -13531 157118 -52647 285558 -66268 -20096 -41409 63026 15612 -13874 55363 -11835 288913 -17538 66123 -12421 15943 33760 61695 36494 58891 54971 -9987 39985 15253 59001 30313 27958 31557 27702 34885 24282 28303 16997 4736 30041 6425 31887 19906 20036 5202 8154 8319 12036 16897 907 11173 5984 2170 11076 2219 -8363 -2955 -2847 -1149 75 -158 999 -119 624 4068 1533 713 3182 2287 2226 -2999 192 -5536 -3062 -1330 -1832 -1819 -410 -1219 -1519 -3480 -2919 -3050 -2682 -718 -1184 -453 -144 -341 479 -1159 -169 -2061 -525 -1151 -425 -301 1294 984 806 2221 1936 1871 1306 -195 460 382 1253 172 85 -276 -669 -75 -206 629 547 1019 93 299 -404 -981 -1962 -946 900000 -3134 467 900000 -37 -6143 334 -2133 -3447 -2790 -7139 -2664 -2690 -1022 -1493 -880 519 -513 1379 -1518 1340 -762 -428 -214 -238 1508 -1305 2740 -1855 -456 -1409 880 381 -436 821 -361 2772 -796 1557 -726 751 1384 1937 1464 1901 1870 -671 1709 891 2471 1904 1975 2340 2272 2769 2203 2444 1572 475 2358 695 3060 2466 2674 799 1202 1270 1953 3022 211 2456 1368 483 2243 437 -1701 -581 -634 -303 23 -52 395 -51 281 1889 768 371 1612 1128 1027 -1373 83 -2656 -1637 -824 -1341 -1546 -380 -1153 -1352 -2829 -2135 -2230 -2108 -588 -1034 -425 -150 -409 643 -1706 -251 -3052 -731 -1560 -580 -432 1940 1534 1238 3216 2711 2550 1733 -255 582 514 1936 309 170 -597 -1542 -185 -546 1738 1543 2905 267 814 -1035 -2357 -4625 SS 20241120T124313.5Z 9090.530017 283 1 49.79 2 81.71 127.14 50.20 267.72 0.00 1 0.00 1 0 25 5.109e-01 9.995e-03 2.007e-01 3.575e-03 6.802612e-01 1.930064e-03 8.177561e-03 -6.000000e+00 2.840322e-01 222.71 -2.00 3.55 -2.00 321.77 0.00e+00 7.868006e-03 1.039169e-03 4.487519e-03 -6.000000e+00 1.251542e-02 277.68 -2.00 20.00 -2.00 321.29 0.00e+00 6.520 0.005 302.00 328.00 3 -5.5735e-01 6.9563e-03 7.5181e-02 -6.0000e+00 6.9897e-01 2.3645e-01 1.0302e-02 4.1880e-02 -6.0000e+00 7.6301e-01 -2.5733e-01 1.1309e-02 2.7481e-02 -6.0000e+00 4.5502e-01 8.8068e-02 5.2425e-03 1.1989e-02 -6.0000e+00 1.9371e-01 7.9584e-04 -6.4128e-04 1.0370e-04 1.8047e-04 -6.0000e+00 1.3463e-02 -1.1240e-03 4.5287e-06 12 8 8 10 0 0 16.74 22.83 0.33 -0.00112 -0.00594 242 50 1 5 0 205.670 26.51 20.00 22.83 9.29 30.1 914.00 -178459 -165021 -137173 -104033 -144910 -160550 -195762 -108384 -238056 -156526 -162101 -71106 -53249 -133488 -48652 -46386 -11020 -50626 -53533 -30570 -42446 -28514 -57473 -3628 -60883 -40231 -40970 -53202 -26884 -52930 -29990 -42281 -13949 -21591 -22931 -20984 -16744 2713 2879 5087 -7554 9072 5012 -3202 3127 3726 13967 5315 10610 427 8464 8595 10253 8374 8026 7409 3329 4619 1193 4587 334 4069 8386 4954 6303 2404 1384 2766 2573 4866 1288 4413 1565 2763 -1363 -1920 -692 -4261 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