File name: Pandora183s1_LondonderryNH_20241125_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20241126T044458.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20241125_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20241125 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241125T122711.5Z 9095.518883 230 1 49.73 2 85.10 124.61 43.36 179.53 0.00 1 0.00 1 0 25 7.015e-01 7.108e-02 5.237e-01 5.808e-02 1.042528e+00 3.304402e-02 1.273256e-02 -6.000000e+00 3.917082e-01 222.64 -2.00 3.55 -2.00 322.18 0.00e+00 -1.687114e-02 1.311135e-02 4.699616e-03 -6.000000e+00 1.831029e-02 277.12 -2.00 20.00 -2.00 321.67 0.00e+00 9.980 0.019 302.00 328.00 3 -1.1093e+00 1.1400e-01 1.1321e-01 -6.0000e+00 9.6365e-01 2.3734e+00 1.3039e-01 5.3169e-02 -6.0000e+00 1.0527e+00 -2.3392e+00 7.7025e-02 2.8136e-02 -6.0000e+00 6.2671e-01 7.5999e-01 4.4440e-02 1.3085e-02 -6.0000e+00 2.6867e-01 2.4000e-05 -9.2829e-04 1.4911e-03 2.6674e-04 -6.0000e+00 1.9215e-02 -4.3285e-05 4.8031e-05 12 8 8 10 0 0 -2.81 22.92 0.86 -0.00004 -0.00702 36 7 1 5 0 1381.220 26.62 19.99 22.92 7.03 30.1 899.52 55065 147694 237577 220304 -13331 66377 -61811 -36540 231815 65031 8643 8170 900000 -20058 30004 117418 13455 118279 57273 217240 -12090 65979 -11484 6359 159364 143189 900000 243 900000 54069 900000 -92864 98106 52656 -37434 -81365 -17372 900000 -62131 223452 10388 51678 53772 -8567 145239 -47640 33340 -44 6798 2689 36106 900000 -21063 900000 18301 64308 56066 116792 82424 114272 77959 3191 40019 -37337 289382 108966 86035 43747 24673 79835 23846 58231 5749 -45836 36528 46262 52827 -56448 35088 -38911 14295 8972 36054 8873 16799 31120 -9091 36231 2641 9696 14660 10740 -10132 -11903 23461 -12005 25204 -1236 28310 8111 11322 -9369 9643 -6762 -14100 10548 -3921 -750 -1846 -10149 5514 219 6860 -4352 5920 -2618 -266 -4054 -2219 1520 -3242 3136 1139 -8365 2315 -5031 -457 3028 5500 -120 4496 4 -1378 -1828 -836 -1058 301 4264 -4117 26 2860 -247 1237 4450 8355 13439 12462 -1392 3755 -8607 -4293 13113 3679 715 675 900000 -2618 2611 6642 1522 6691 3987 12289 -1420 3732 -1245 630 9015 8100 900000 23 900000 3059 900000 -21450 5550 3227 -5117 -15342 -1720 900000 -12887 12640 1371 4629 4563 -1252 8216 -8534 2515 -5 673 292 3342 900000 -4116 900000 2729 6283 6055 6607 5934 6464 4811 427 4116 -9408 16370 6724 6637 5399 4060 8622 4905 8684 1389 -16735 5072 4996 4890 -15966 4511 -12606 3235 2492 8529 2920 5356 8962 -4020 10248 1018 3291 4373 3148 -3647 -4713 7601 -6606 11276 -839 15869 5631 7103 -6360 4761 -3825 -9136 6205 -2817 -568 -1608 -10282 6114 258 8692 -6179 7368 -3451 -346 -5733 -3238 2175 -4677 3974 1405 -11072 2685 -6118 -522 3632 7685 -210 8597 9 -3345 -4849 -2377 -3178 907 12470 -12924 73 7233 -592 2806 SS 20241125T123856.1Z 9095.527039 233 1 49.67 2 83.35 126.74 43.47 183.73 0.00 1 0.00 1 0 17 4.441e-01 1.940e-02 4.024e-01 1.102e-02 9.170942e-01 6.218226e-03 9.973573e-03 -6.000000e+00 2.468418e-01 222.64 -2.00 3.55 -2.00 322.43 0.00e+00 8.057400e-03 3.787147e-03 1.592205e-03 -6.000000e+00 1.089473e-02 277.12 -2.00 20.00 -2.00 322.01 0.00e+00 7.867 0.009 302.00 328.00 3 -6.5018e-01 2.4915e-02 9.3064e-02 -6.0000e+00 6.0742e-01 9.9751e-01 3.5224e-02 5.5240e-02 -6.0000e+00 6.6320e-01 -1.2753e+00 3.4427e-02 2.8075e-02 -6.0000e+00 3.9550e-01 4.9179e-01 1.5766e-02 1.1750e-02 -6.0000e+00 1.6834e-01 1.7602e-04 -1.2364e-03 2.9757e-04 1.7212e-04 -6.0000e+00 1.1738e-02 -2.4639e-04 1.2612e-05 12 8 8 10 0 0 18.38 22.92 0.40 -0.00025 -0.00954 117 24 1 5 0 424.500 26.62 20.00 22.92 7.38 30.2 902.37 -204436 -171512 -100164 16807 22887 -129926 -161548 6188 -46334 -98835 -45891 -24010 -174232 900000 -80755 -46475 71383 -8945 -38063 -41666 -5994 131513 -11050 107857 31549 -41923 21224 -88303 29984 -42534 -7630 -8687 3760 -29491 34628 -22419 34104 17150 -33167 21453 26469 32448 24908 2747 8344 43079 20367 15301 55407 18118 64467 22471 17770 41395 45168 44512 52424 29827 32848 3173 24655 1424 25075 43804 29101 25082 9034 10446 11462 16349 15487 22716 19163 9397 1931 -61 -2292 -1964 -113 3880 5693 3252 2308 4798 910 583 4722 -1716 6448 4702 575 1577 -2813 -6320 -2633 -4531 345 216 -817 -139 -2385 -3720 -5956 -6387 -6295 -1208 -3338 -3090 529 -652 712 -551 -62 -644 -1647 -1040 -1608 -726 657 544 2601 1633 1944 2124 1635 1354 1237 868 659 288 829 417 -247 -527 -253 -338 877 1185 21 148 -435 -1002 -1963 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1.672329e-02 277.12 -2.00 20.00 -2.00 321.61 0.00e+00 6.553 0.005 302.00 328.00 3 -5.7521e-01 8.2863e-03 7.8551e-02 -6.0000e+00 9.3590e-01 3.5728e-01 1.2917e-02 4.7017e-02 -6.0000e+00 1.0218e+00 -4.5670e-01 1.4455e-02 2.9298e-02 -6.0000e+00 6.0918e-01 1.7243e-01 6.5516e-03 1.2468e-02 -6.0000e+00 2.5922e-01 6.8592e-04 -6.1696e-04 1.1062e-04 1.9364e-04 -6.0000e+00 1.8031e-02 -5.0472e-04 9.4903e-06 12 8 8 10 0 0 26.21 22.93 0.34 -0.00050 -0.00514 242 50 1 5 0 205.250 26.62 19.99 22.93 7.86 30.0 905.17 -267712 -158661 -213775 -176038 -244688 -133637 -162472 -204931 -206331 -205979 -198533 -236300 -142981 -155115 -115137 96905 -87134 -60603 -85156 -75386 -49735 -79859 -85529 -52883 -40713 -51992 -28110 -77164 -76190 -44127 -30214 -39800 -29400 -16952 -7997 -9021 -31024 -21181 -5177 -1345 9869 3593 2604 2140 7090 -3232 14502 6366 11516 7885 9024 14651 13308 9832 7930 13493 14345 5579 6977 5151 8023 1849 10317 9822 9375 7989 7221 2378 1798 6549 6653 6963 3915 3263 1039 -2428 -1002 -7149 -2004 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