File name: Pandora183s1_LondonderryNH_20241204_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20241205T044904.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20241204_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20241204 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241204T123733.2Z 9104.526078 56 1 50.53 2 85.15 126.81 117.02 102.81 0.00 1 0.00 1 0 17 7.197e-01 8.659e-02 5.539e-01 7.459e-02 1.111124e+00 4.288026e-02 1.244648e-02 -6.000000e+00 4.092638e-01 222.52 -2.00 3.55 -2.00 321.85 0.00e+00 -1.206647e-02 1.186435e-02 7.072536e-03 -6.000000e+00 1.876638e-02 276.11 -2.00 20.00 -2.00 321.21 0.00e+00 10.061 0.019 302.00 328.00 3 -1.1448e+00 1.3266e-01 1.2409e-01 -6.0000e+00 1.0110e+00 2.8175e+00 1.5429e-01 8.7649e-02 -6.0000e+00 1.1058e+00 -2.5406e+00 8.9492e-02 3.0925e-02 -6.0000e+00 6.5216e-01 7.6884e-01 5.1929e-02 1.3253e-02 -6.0000e+00 2.7529e-01 1.7521e-05 -2.1890e-04 1.8454e-03 1.3722e-04 -6.0000e+00 1.9369e-02 -6.4985e-04 7.6930e-06 12 8 8 10 0 0 -29.36 22.82 0.91 -0.00065 -0.00229 29 6 1 5 0 1742.220 26.51 20.01 22.82 1.72 29.4 867.96 129355 35705 162676 900000 -11258 900000 900000 167912 11272 900000 238702 113809 180342 -61492 94888 -11715 77380 900000 78793 231215 -36544 45528 -22110 109347 -13282 -17446 -41141 49532 73041 -32733 17640 -77360 174544 26243 -9538 83333 -19277 105209 -33534 31689 18023 58010 33002 900000 70278 6263 236241 -17130 77149 92837 -22060 5094 -8904 66460 59006 110539 101958 114685 19879 -1372 93356 -55208 188523 -45309 97926 15595 19162 900000 3808 82549 -8261 108998 40942 201387 13381 26013 252731 -14525 83048 -26558 -26828 19223 7798 -18741 22883 16182 9031 23687 2103 49528 15933 10238 -13256 -13006 -6118 -11609 33216 614 15584 491 -166 10776 -13107 -13254 -40156 8932 1593 2051 9671 4650 4727 4027 14517 -136 -5047 -5062 2218 -1520 -1070 3923 2073 17020 4199 1021 -6960 -7778 -11940 -632 10771 834 -1595 -4050 495 -1872 316 2935 -2991 4646 -2235 -805 -1597 -428 5855 9397 5743 11817 900000 -1694 900000 900000 12197 1260 900000 17340 8267 13100 -17524 6893 -2488 6918 900000 6604 16796 -7964 3816 -3459 7943 -2332 -3168 -8717 3598 5306 -4359 1602 -21073 12679 2860 -1328 6053 -2567 7643 -6699 3837 2728 5970 4195 900000 5105 796 17161 -2592 5604 6744 -4140 802 -1725 7022 7014 8030 8080 8331 3019 -226 6781 -14948 13695 -14063 7760 2781 3290 900000 880 9812 -2619 10797 7570 14629 2474 3608 18359 -2878 7130 -8243 -9921 5205 2626 -8663 7253 5664 3459 7821 833 11448 4735 3042 -4990 -5325 -2747 -6593 14258 426 10292 379 -119 6049 -8136 -7965 -33413 4778 968 1355 6770 4053 4807 4574 15530 -168 -6399 -6877 2836 -2109 -1546 5442 2786 18299 4881 1194 -8594 -9436 -14918 -776 14240 1454 -3268 -9414 1199 -5057 905 8592 -9428 13670 -6933 -2308 -4211 -1021 12631 SS 20241204T124911.1Z 9104.534156 59 1 49.58 2 83.47 128.92 115.03 104.47 0.00 1 0.00 1 0 17 5.044e-01 2.206e-02 3.871e-01 1.397e-02 9.458974e-01 7.909633e-03 1.034886e-02 -6.000000e+00 2.805960e-01 222.52 -2.00 3.55 -2.00 322.46 0.00e+00 6.215676e-04 4.639143e-03 6.500095e-03 -6.000000e+00 1.245010e-02 276.11 -2.00 20.00 -2.00 322.04 0.00e+00 7.985 0.010 302.00 328.00 3 -4.7862e-01 3.1192e-02 9.9606e-02 -6.0000e+00 6.9013e-01 1.2352e+00 4.2216e-02 6.6959e-02 -6.0000e+00 7.5403e-01 -1.6037e+00 3.8023e-02 3.4363e-02 -6.0000e+00 4.4929e-01 6.1972e-01 1.7898e-02 1.0126e-02 -6.0000e+00 1.9083e-01 1.2768e-04 -8.2974e-04 3.7586e-04 1.8633e-04 -6.0000e+00 1.3290e-02 -4.1988e-04 -6.5879e-06 12 8 8 10 0 0 9.57 22.84 0.36 -0.00042 -0.00665 95 20 1 5 0 521.810 26.51 19.99 22.84 2.81 29.6 876.77 -96191 -9028 -53776 15445 -37721 -53267 27815 -98530 -102731 -116431 -48642 -93964 -128362 -94975 -23413 158450 17264 311495 -41580 17381 17678 -27745 155658 -41494 900000 -14096 51762 -61075 -96 -44040 31655 32790 22541 65485 10098 56095 -18019 22580 20955 60517 51577 112433 65420 18347 52885 -10885 50897 8328 30570 29481 -2467 41612 73264 96394 1345 39013 37117 31089 65464 -8441 133510 13087 37490 53453 18129 43859 27361 7252 11040 12161 6346 15754 25425 9355 18956 6646 1331 -16558 7098 -3137 -57 2745 8550 1790 4056 6160 2373 -1574 4864 -2031 935 2927 468 -9569 -2257 -5842 -3668 -343 -10 -756 -4098 -4665 -3675 -1289 -7883 -5124 -2387 -869 2319 -794 584 77 132 19 -1303 -1186 -2421 372 742 2366 1300 1386 2395 1588 3341 -1803 80 1294 2932 -869 707 -665 -1146 321 -1022 932 451 1120 344 -395 442 -1333 -1895 -3024 -132 -1240 210 -553 -781 379 -2271 -2584 -3416 -773 -2453 -5683 -3774 -558 2158 353 4243 -1652 375 361 -819 2120 -1413 900000 -384 705 -2357 -2 -1350 539 670 589 1298 325 1042 -714 671 753 1724 1788 2228 2106 932 1834 -701 1765 454 1401 1460 -186 2267 3176 3581 137 2802 2758 2387 3324 -836 3141 1102 2832 3972 2088 3911 2880 979 1586 1988 1210 2829 4030 1599 2606 905 178 -2748 1180 -641 -13 741 2435 639 1497 2350 979 -691 1981 -849 354 1029 167 -4054 -1036 -3334 -2439 -259 -9 -650 -3416 -3463 -2398 -806 -5637 -3783 -1821 -713 2088 -863 723 105 188 27 -1800 -1591 -3337 525 1102 3541 1905 1914 3135 2042 4105 -2270 97 1675 4414 -1597 1445 -1507 -2805 836 -2904 2727 1346 3353 1024 -1120 1143 -3226 -4437 SS 20241204T130010.6Z 9104.541790 62 1 49.66 2 81.93 130.95 113.16 106.03 0.00 1 0.00 1 0 17 6.125e-01 1.433e-02 2.820e-01 4.845e-03 8.327046e-01 2.682739e-03 9.753506e-03 -6.000000e+00 3.402116e-01 222.52 -2.00 3.55 -2.00 322.15 0.00e+00 1.265280e-02 1.542639e-03 3.787151e-03 -6.000000e+00 1.490583e-02 276.11 -2.00 20.00 -2.00 321.72 0.00e+00 6.670 0.006 302.00 328.00 3 -4.7902e-01 1.0155e-02 7.9951e-02 -6.0000e+00 8.3733e-01 5.3925e-01 1.5672e-02 4.7582e-02 -6.0000e+00 9.1440e-01 -6.9144e-01 1.7318e-02 2.9818e-02 -6.0000e+00 5.4487e-01 2.6899e-01 7.8514e-03 1.5960e-02 -6.0000e+00 2.3173e-01 5.1315e-04 -9.8911e-04 1.3301e-04 2.5000e-04 -6.0000e+00 1.6136e-02 -1.1334e-03 9.8452e-06 12 8 8 10 0 0 14.26 22.83 0.39 -0.00113 -0.00857 205 43 1 5 0 242.200 26.51 20.01 22.83 4.08 29.7 885.48 -163747 -115301 -148138 -215252 -131206 -255870 -52230 -254503 135891 -155033 -172792 -163364 -159188 -102675 -144063 -5801 -134564 98515 -53563 -60309 50193 -108489 -39560 -74883 -26872 -107835 -31344 -64313 -14848 -47070 -59770 -12867 1022 5168 28033 30505 -3958 -9018 24979 -6769 41122 -15401 27397 17820 37344 44771 -7537 21763 -6744 44904 7206 27541 22861 16379 20454 10420 21089 4509 18644 4826 13107 10862 7641 17689 7964 22049 7196 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