File name: Pandora107s1_LynnMA_20240514_L2Fit_fout2c7d20230718p1-8.txt File generation date: 20240916T084028.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 107 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora107_OF_v1d20230601.txt Instrument calibration file used: Pandora107s1_CF_v7d20230718.txt Level 1 file used: Pandora107s1_LynnMA_20240514_L1_smca1c7d20230718p1-8.txt Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20240514 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 6 First and last pixel inside fitting window: 220 362 Nominal wavelengths inside fitting window [nm]: 305.0382 305.1791 305.3200 305.4608 305.6017 305.7426 305.8834 306.0242 306.1650 306.3059 306.4467 306.5874 306.7282 306.8690 307.0097 307.1505 307.2912 307.4319 307.5727 307.7134 307.8540 307.9947 308.1354 308.2761 308.4167 308.5573 308.6980 308.8386 308.9792 309.1198 309.2604 309.4009 309.5415 309.6820 309.8226 309.9631 310.1036 310.2441 310.3846 310.5251 310.6656 310.8060 310.9465 311.0869 311.2273 311.3678 311.5082 311.6485 311.7889 311.9293 312.0697 312.2100 312.3504 312.4907 312.6310 312.7713 312.9116 313.0519 313.1922 313.3324 313.4727 313.6129 313.7531 313.8934 314.0336 314.1738 314.3139 314.4541 314.5943 314.7344 314.8746 315.0147 315.1548 315.2949 315.4350 315.5751 315.7152 315.8552 315.9953 316.1353 316.2754 316.4154 316.5554 316.6954 316.8354 316.9753 317.1153 317.2552 317.3952 317.5351 317.6750 317.8149 317.9548 318.0947 318.2346 318.3744 318.5143 318.6541 318.7939 318.9338 319.0736 319.2134 319.3531 319.4929 319.6327 319.7724 319.9121 320.0519 320.1916 320.3313 320.4710 320.6107 320.7503 320.8900 321.0296 321.1693 321.3089 321.4485 321.5881 321.7277 321.8673 322.0068 322.1464 322.2859 322.4255 322.5650 322.7045 322.8440 322.9835 323.1230 323.2624 323.4019 323.5413 323.6808 323.8202 323.9596 324.0990 324.2384 324.3777 324.5171 324.6564 324.7958 324.9351 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240514T113242.5Z 8900.481047 148 1 29.98 2 67.91 84.25 114.87 18.54 0.00 1 0.00 1 0 25 5.234e-02 9.824e-03 2.870e-02 2.152e-03 4.543220e-01 1.142919e-03 5.396585e-03 -6.000000e+00 3.159666e-02 231.01 -2.00 3.54 -2.00 319.32 0.00e+00 2.699371e-03 3.015833e-04 7.951406e-04 -6.000000e+00 1.389161e-03 282.38 -2.00 20.00 -2.00 318.65 0.00e+00 2.636 0.000 302.00 328.00 3 3.5482e+00 3.2063e-03 3.5981e-02 -6.0000e+00 7.9097e-02 5.3240e-02 3.7389e-03 2.4193e-02 -6.0000e+00 8.5380e-02 -3.7590e-02 2.8598e-03 1.2443e-02 -6.0000e+00 5.0751e-02 3.9548e-03 1.4923e-03 4.3033e-03 -6.0000e+00 2.1310e-02 5.9574e-04 -9.7735e-05 6.4502e-05 4.7925e-05 -6.0000e+00 1.5403e-03 -3.7782e-02 0.0000e+00 12 8 8 10 0 0 99.99 21.57 0.32 -0.03778 -0.03852 57 57 1 5 0 525.850 25.79 20.03 21.57 20.53 0.0 926.05 -8165 -26460 -14672 -7636 -33973 -2897 -16870 -13583 -10113 -15548 -5662 -10965 -4891 -8262 -3280 -5154 -709 -1621 -113 6652 -3238 1420 960 -1679 -2660 -7519 -4653 -6437 -2417 -4526 -924 -1270 -595 -1906 -4328 -2257 -2796 292 -93 -1924 -1493 -2880 -1456 -2516 176 955 972 1484 721 2215 2149 2014 1880 2058 2268 842 625 -501 -220 1162 2064 3270 1796 1123 -1017 -580 1697 2516 3927 1114 -2 -1191 -1502 -584 -1389 -667 7 591 1400 -106 -427 -1474 -1818 -1156 -186 -560 -752 -412 -524 -449 -107 386 989 1658 2045 876 1012 111 -1199 -1984 -1297 -99 1472 1481 -1049 -2173 -1260 -499 652 589 277 -686 -261 227 873 1821 2099 1437 696 -766 -909 -574 345 -337 198 -458 905 2238 850 -335 -872 -605 106 -47 -41 -729 36 101 -217 -493 -259 83 826 -146 -672 -358 -173 -959 -56 -380 -329 -268 -469 -161 -352 -168 -356 -164 -306 -45 -113 -8 480 -268 114 78 -146 -252 -795 -481 -665 -236 -453 -95 -150 -80 -275 -643 -323 -414 48 -19 -464 -404 -787 -413 -739 51 279 286 437 216 675 694 709 724 846 973 381 292 -238 -103 528 943 1572 964 664 -646 -365 989 1413 2308 697 -2 -894 -1145 -428 -962 -453 5 344 841 -73 -312 -1225 -1657 -1119 -176 -564 -807 -459 -586 -489 -110 368 933 1511 1955 876 1142 141 -1572 -2711 -1690 -125 1681 1675 -1278 -2856 -1616 -666 915 899 430 -1125 -427 355 1356 2640 2971 2101 1085 -1198 -1460 -908 557 -528 297 -661 1231 2985 1223 -538 -1434 -1038 187 -87 -75 -1428 73 207 -448 -1006 -507 154 1550 SS 20240514T113951.8Z 8900.486016 152 1 30.04 2 66.59 85.41 114.47 20.25 0.00 1 0.00 1 0 25 3.830e-02 1.036e-02 4.556e-03 5.374e-04 4.322879e-01 2.841555e-04 5.126661e-03 -6.000000e+00 2.311772e-02 231.01 -2.00 3.54 -2.00 318.71 0.00e+00 2.055676e-03 6.251847e-05 3.226556e-04 -6.000000e+00 1.016421e-03 282.38 -2.00 20.00 -2.00 318.01 0.00e+00 2.498 0.000 302.00 328.00 3 1.2177e+00 7.7832e-04 3.4074e-02 -6.0000e+00 5.7871e-02 3.5464e-02 8.8862e-04 2.2866e-02 -6.0000e+00 6.2470e-02 -4.2480e-02 6.1916e-04 1.1348e-02 -6.0000e+00 3.7132e-02 8.0403e-03 3.2242e-04 3.6806e-03 -6.0000e+00 1.5590e-02 7.2992e-03 -1.0769e-04 1.5984e-05 3.9923e-05 -6.0000e+00 1.1271e-03 -3.7445e-02 0.0000e+00 12 8 8 10 0 0 94.34 21.58 0.35 -0.03744 -0.03825 379 379 1 5 0 79.220 25.79 20.01 21.58 20.85 0.0 928.50 -12901 -11937 -12783 -11584 -11816 -8404 -11867 -11793 -12598 -13284 -11721 -10759 -5398 -4944 -3041 -1456 -987 122 157 1935 1117 996 2164 272 -1490 -3135 -4134 -4091 -1788 1158 722 662 -13 -3215 -3361 -518 521 110 511 -2082 -2666 -1955 -1451 -1340 -328 377 99 654 868 1842 2583 1859 1958 1508 1021 1350 586 -151 196 1317 2161 2758 1650 372 -1217 -581 1349 2106 3243 1029 -639 -1086 -1328 -880 -1038 -259 387 1158 1577 97 -860 -1507 -2152 -1341 -491 -605 -531 -620 -414 -540 -47 588 1499 2353 2024 940 554 73 -1405 -2059 -1421 -333 1452 1662 -1025 -1998 -1106 -596 633 512 -136 -762 -362 132 922 2013 2238 1571 720 -686 -949 -606 114 -288 6 -204 904 2148 985 -378 -815 -640 230 373 141 -501 -46 61 -448 -698 -345 -43 752 -402 -430 -500 -445 -434 -280 -411 -454 -555 -634 -571 -552 -296 -325 -237 -129 -96 13 17 222 134 122 264 35 -212 -437 -585 -566 -261 164 108 102 -2 -621 -653 -96 98 24 134 -661 -878 -694 -538 -508 -125 144 38 251 335 722 1061 835 958 791 519 711 319 -84 107 699 1152 1556 1033 257 -832 -391 907 1361 2195 740 -517 -937 -1162 -745 -826 -187 271 765 1076 70 -717 -1329 -2085 -1377 -497 -652 -609 -697 -467 -631 -52 599 1490 2250 2039 996 664 93 -1852 -2825 -1859 -416 1752 1988 -1247 -2619 -1431 -803 897 746 -215 -1204 -570 208 1352 2901 3151 2285 1059 -1080 -1540 -970 175 -428 9 -294 1233 3037 1414 -572 -1344 -1047 385 652 250 -941 -85 114 -850 -1314 -653 -76 1348 SS 20240514T114542.2Z 8900.490072 155 1 30.02 2 65.52 86.36 114.12 21.63 0.00 1 0.00 1 0 25 3.224e-02 1.026e-02 3.756e-03 5.098e-04 4.136671e-01 2.689118e-04 4.909101e-03 -6.000000e+00 1.946489e-02 231.01 -2.00 3.54 -2.00 318.52 0.00e+00 1.782974e-03 5.572889e-05 2.970921e-04 -6.000000e+00 8.557633e-04 282.38 -2.00 20.00 -2.00 317.82 0.00e+00 2.397 0.000 302.00 328.00 3 1.2468e+00 7.3160e-04 3.2628e-02 -6.0000e+00 4.8727e-02 3.0119e-02 8.3233e-04 2.1834e-02 -6.0000e+00 5.2597e-02 -3.8060e-02 5.6794e-04 1.0810e-02 -6.0000e+00 3.1264e-02 7.0199e-03 2.9528e-04 3.4202e-03 -6.0000e+00 1.3128e-02 8.0339e-03 -6.1548e-05 1.5140e-05 3.6698e-05 -6.0000e+00 9.4888e-04 -3.7982e-02 0.0000e+00 12 8 8 10 0 0 80.13 21.60 0.32 -0.03798 -0.03844 397 397 1 5 0 75.580 25.79 20.01 21.60 21.49 0.0 931.71 -8490 -10068 -8922 -10964 -8870 -8435 -8873 -8965 -10773 -11080 -11543 -8534 -6232 -3398 -1485 -2333 -343 976 800 1508 612 1521 1830 1 -1438 -2713 -4251 -3961 -1723 265 1331 378 -180 -3359 -3027 -437 670 1060 108 -1662 -2400 -1764 -1075 -1225 135 255 147 574 718 1908 2275 1776 1572 1495 927 1176 604 -63 347 1118 2353 2567 1618 483 -1373 -539 1251 2044 3002 953 -657 -1218 -1261 -983 -1278 -307 510 1152 1715 288 -960 -1572 -2241 -1244 -585 -596 -562 -703 -461 -529 15 535 1409 2280 2128 984 524 49 -1456 -2008 -1328 -332 1461 1567 -1012 -1951 -1110 -563 533 483 -46 -750 -368 117 940 1930 2185 1499 769 -668 -983 -638 144 -189 50 -196 899 2204 1002 -404 -713 -631 221 371 118 -466 -81 83 -402 -637 -355 -162 728 -305 -428 -402 -500 -377 -334 -355 -399 -553 -614 -665 -505 -404 -256 -132 -240 -38 116 91 180 76 191 231 0 -210 -427 -682 -618 -257 38 201 65 -35 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