File name: Pandora107s1_LynnMA_20240523_L2Fit_fout2c8d20240424p1-8.txt File generation date: 20241009T160618.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 107 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora107_OF_v1d20230601.txt Instrument calibration file used: Pandora107s1_CF_v8d20240424.txt Level 1 file used: Pandora107s1_LynnMA_20240523_L1_smca1c8d20240424p1-8.txt Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20240523 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld based on session 7 "OOB session based on clearance session 6, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used" First and last pixel inside fitting window: 221 362 Nominal wavelengths inside fitting window [nm]: 305.1394 305.2803 305.4212 305.5621 305.7030 305.8438 305.9847 306.1255 306.2663 306.4071 306.5479 306.6887 306.8295 306.9702 307.1110 307.2517 307.3925 307.5332 307.6739 307.8146 307.9553 308.0959 308.2366 308.3773 308.5179 308.6585 308.7991 308.9397 309.0803 309.2209 309.3615 309.5021 309.6426 309.7832 309.9237 310.0642 310.2047 310.3452 310.4857 310.6262 310.7666 310.9071 311.0475 311.1880 311.3284 311.4688 311.6092 311.7496 311.8899 312.0303 312.1706 312.3110 312.4513 312.5916 312.7319 312.8722 313.0125 313.1528 313.2930 313.4333 313.5735 313.7137 313.8540 313.9942 314.1344 314.2745 314.4147 314.5549 314.6950 314.8352 314.9753 315.1154 315.2555 315.3956 315.5357 315.6757 315.8158 315.9558 316.0959 316.2359 316.3759 316.5159 316.6559 316.7959 316.9358 317.0758 317.2157 317.3557 317.4956 317.6355 317.7754 317.9153 318.0552 318.1950 318.3349 318.4747 318.6145 318.7544 318.8942 319.0340 319.1738 319.3135 319.4533 319.5930 319.7328 319.8725 320.0122 320.1519 320.2916 320.4313 320.5710 320.7106 320.8503 320.9899 321.1295 321.2691 321.4087 321.5483 321.6879 321.8275 321.9670 322.1066 322.2461 322.3856 322.5251 322.6646 322.8041 322.9436 323.0831 323.2225 323.3619 323.5014 323.6408 323.7802 323.9196 324.0590 324.1983 324.3377 324.4771 324.6164 324.7557 324.8950 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240523T100816.0Z 8909.422408 223 1 28.69 2 81.87 69.30 103.14 248.58 0.00 1 0.00 1 0 17 4.827e-01 4.889e-02 4.225e-01 4.220e-02 8.617153e-01 2.438584e-02 1.013664e-02 -6.000000e+00 2.864561e-01 231.58 -2.00 3.54 -2.00 321.74 0.00e+00 -1.648443e-02 8.661269e-03 1.189081e-03 -6.000000e+00 1.270459e-02 283.29 -2.00 20.00 -2.00 321.10 0.00e+00 6.620 0.005 302.00 328.00 3 3.2985e+00 7.8946e-02 8.3197e-02 -6.0000e+00 7.1880e-01 1.3693e+00 9.4720e-02 5.8609e-02 -6.0000e+00 7.7738e-01 -1.8387e+00 6.1314e-02 2.2812e-02 -6.0000e+00 4.6162e-01 7.0279e-01 3.1624e-02 1.5886e-02 -6.0000e+00 1.9636e-01 1.0668e-05 -1.6400e-03 1.1737e-03 2.1417e-04 -6.0000e+00 1.3605e-02 5.1226e-03 0.0000e+00 12 8 8 10 0 0 96.74 22.18 1.74 0.00512 -0.00720 8 8 1 5 0 3584.960 26.32 19.98 22.18 25.70 0.0 946.46 25428 900000 66839 73174 47148 -20334 99292 -69237 101437 9913 130080 24175 43842 58971 -3801 5650 8792 157197 900000 8603 55286 -33565 -33581 18757 -26074 15774 -77772 145352 135960 42373 10146 -6138 45888 -34622 403 59681 70890 118321 106970 6192 32339 94303 57222 102462 191076 37746 205570 -31386 11667 18680 -8973 -17602 43903 39831 27515 28208 2641 51211 45868 -1018 -10989 1864 59611 10651 15535 39520 9754 3129 -4613 24698 48835 54949 28941 4951 606 7172 30105 -20551 -21791 17411 -24564 2378 6430 7489 -1152 10606 2947 14202 3719 1316 3146 -1585 -9480 -2940 -10379 2226 -6494 -2326 -790 -5703 -8549 4114 -1388 -11871 3790 -5869 10254 -2741 -4421 2811 -4654 2064 -2255 -460 -507 2249 3177 5226 -2704 -417 -2045 5603 -2048 4337 -1534 8452 3493 3993 918 -1188 1101 -2170 4 -2276 2443 -79 1768 2607 -2237 1362 -2351 -2567 2282 900000 3249 3010 1939 -1597 4084 -10874 4173 741 5351 1627 2623 3308 -426 592 888 6466 900000 772 2894 -4142 -4395 1613 -3705 1416 -15705 5979 5593 2060 759 -597 3020 -4402 33 2946 3499 4867 5280 857 3991 6207 5178 5479 7860 3416 8456 -5551 1392 2228 -1550 -3620 5237 5243 4301 4525 543 6109 5283 -176 -2124 345 6866 2147 3003 5852 1966 734 -1328 5892 9642 10171 6548 1283 145 1446 4706 -5749 -7171 4584 -11418 949 2671 3265 -578 4974 1540 6602 1851 633 1398 -710 -4719 -1524 -6745 1493 -5476 -2105 -741 -5443 -7596 2893 -993 -9864 2884 -5214 8267 -2773 -5201 3515 -6929 3022 -3460 -674 -717 3072 4443 7568 -4427 -669 -3213 7768 -2973 5780 -2101 10152 4512 5748 1585 -2384 2360 -5150 9 -5710 6221 -213 4752 6932 -6074 3685 -6073 -6272 SS 20240523T110938.7Z 8909.465031 253 1 10.36 2 70.99 78.94 113.62 257.49 0.00 1 0.00 1 0 25 6.623e-02 8.906e-03 3.277e-02 3.306e-03 4.596069e-01 1.735842e-03 5.477087e-03 -6.000000e+00 3.923194e-02 231.58 -2.00 3.54 -2.00 318.96 0.00e+00 2.035087e-03 4.076783e-04 7.834516e-04 -6.000000e+00 1.709903e-03 283.29 -2.00 20.00 -2.00 318.25 0.00e+00 3.033 0.000 302.00 328.00 3 3.0288e+00 4.7909e-03 3.9099e-02 -6.0000e+00 9.8326e-02 6.1431e-02 5.5205e-03 2.4532e-02 -6.0000e+00 1.0623e-01 -4.8012e-02 4.0353e-03 1.2249e-02 -6.0000e+00 6.3076e-02 1.1499e-02 2.1194e-03 3.7222e-03 -6.0000e+00 2.6771e-02 6.9309e-04 -5.8491e-04 9.5516e-05 4.0058e-05 -6.0000e+00 1.8659e-03 4.8379e-03 0.0000e+00 12 9 1 12 9 1 81.15 22.17 0.39 0.00484 0.00044 10 32 1 5 0 941.140 26.32 20.00 22.17 25.35 0.0 945.28 -13736 -848 -26515 5967 -26500 -22734 -22611 -28907 -24755 -25762 -14547 -21581 -11406 -2987 -1064 1626 -4125 1227 -197 -2208 -1471 -685 2187 -4652 -3094 -2481 -5687 -4439 -3254 2226 -4249 -4 -4530 -3627 148 -2618 2120 -1979 -2020 -2106 -2124 96 252 1516 115 1799 474 489 1418 2177 2996 2483 2170 1979 1823 1499 -206 421 796 2072 1740 2213 2460 367 -217 719 1301 558 246 -233 -1087 -571 -1356 -903 -931 -94 446 732 -597 -1393 -1086 -2208 -1182 -553 -173 -199 -141 587 331 28 102 911 1111 287 535 50 -87 -264 -2142 -1163 -775 498 594 -1073 -2042 -1332 -292 408 839 662 -332 569 449 922 1268 1727 978 888 -134 -888 -171 7 -27 -52 -333 550 1586 1149 -520 -695 -900 311 449 -234 -343 -93 122 -331 -531 -214 -112 593 -385 -23 -915 138 -794 -667 -743 -1155 -1029 -1121 -595 -1085 -632 -186 -76 126 -367 111 -19 -226 -151 -71 230 -568 -360 -292 -741 -552 -400 278 -593 -1 -779 -614 23 -440 392 -465 -565 -669 -671 31 84 504 39 607 163 170 501 812 1214 1104 1038 997 883 750 -105 211 423 1101 913 1279 1562 251 -147 457 799 366 169 -180 -900 -477 -1105 -685 -642 -63 282 480 -417 -1132 -929 -2093 -1183 -547 -182 -223 -154 643 377 30 102 890 1053 290 564 56 -111 -347 -2962 -1526 -975 569 670 -1302 -2675 -1723 -393 579 1225 997 -531 904 685 1377 1875 2491 1385 1334 -216 -1399 -264 11 -42 -75 -490 766 2171 1687 -814 -1125 -1529 541 778 -432 -641 -180 239 -655 -1036 -399 -206 1047 SS 20240523T111517.5Z 8909.468952 256 1 29.99 2 69.97 79.82 114.60 258.31 0.00 1 0.00 1 0 25 4.182e-02 8.072e-03 5.929e-03 6.381e-04 4.361155e-01 3.342439e-04 5.173494e-03 -6.000000e+00 2.477466e-02 231.58 -2.00 3.54 -2.00 318.90 0.00e+00 2.097154e-03 7.614578e-05 5.230072e-04 -6.000000e+00 1.079718e-03 283.29 -2.00 20.00 -2.00 318.18 0.00e+00 2.888 0.000 302.00 328.00 3 1.0384e+00 9.2178e-04 3.7120e-02 -6.0000e+00 6.2092e-02 3.1386e-02 1.0609e-03 2.3166e-02 -6.0000e+00 6.7082e-02 -3.4424e-02 7.6720e-04 1.1585e-02 -6.0000e+00 3.9832e-02 6.3251e-03 4.0238e-04 3.6760e-03 -6.0000e+00 1.6907e-02 6.0921e-03 -4.5622e-04 1.8596e-05 3.7748e-05 -6.0000e+00 1.1783e-03 4.5250e-03 0.0000e+00 11 8 0 10 0 0 2.00 22.20 0.31 0.00452 0.00110 309 309 1 5 0 97.030 26.32 20.00 22.20 25.51 0.0 946.35 -12059 -9484 -13721 -12286 -16184 -15952 -15991 -14625 -12698 -13054 -11858 -10300 -6649 -3343 -1122 158 -254 -301 750 288 -298 1532 389 -814 -2711 -3423 -3109 -3296 -786 101 237 534 -2262 -3102 -2246 -965 -690 -1119 -1403 -1902 -1439 -1243 -747 -194 152 52 83 383 1134 2362 1783 1764 1624 1286 1442 538 -116 -76 798 1691 2134 2089 1197 -188 -264 810 1732 2211 724 -149 -414 -560 -573 -808 -467 -48 19 524 -393 -1086 -1397 -1841 -1295 -432 -403 -358 -338 82 80 166 448 1055 1486 1354 231 376 412 -776 -1639 -1343 -319 912 785 -1117 -1836 -1279 -557 451 542 188 -227 -134 191 689 1464 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