File name: Pandora107s1_LynnMA_20240524_L2Fit_fout2c7d20230718p1-8.txt File generation date: 20240916T084036.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 107 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora107_OF_v1d20230601.txt Instrument calibration file used: Pandora107s1_CF_v7d20230718.txt Level 1 file used: Pandora107s1_LynnMA_20240524_L1_smca1c7d20230718p1-8.txt Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20240524 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 6 First and last pixel inside fitting window: 220 362 Nominal wavelengths inside fitting window [nm]: 305.0382 305.1791 305.3200 305.4608 305.6017 305.7426 305.8834 306.0242 306.1650 306.3059 306.4467 306.5874 306.7282 306.8690 307.0097 307.1505 307.2912 307.4319 307.5727 307.7134 307.8540 307.9947 308.1354 308.2761 308.4167 308.5573 308.6980 308.8386 308.9792 309.1198 309.2604 309.4009 309.5415 309.6820 309.8226 309.9631 310.1036 310.2441 310.3846 310.5251 310.6656 310.8060 310.9465 311.0869 311.2273 311.3678 311.5082 311.6485 311.7889 311.9293 312.0697 312.2100 312.3504 312.4907 312.6310 312.7713 312.9116 313.0519 313.1922 313.3324 313.4727 313.6129 313.7531 313.8934 314.0336 314.1738 314.3139 314.4541 314.5943 314.7344 314.8746 315.0147 315.1548 315.2949 315.4350 315.5751 315.7152 315.8552 315.9953 316.1353 316.2754 316.4154 316.5554 316.6954 316.8354 316.9753 317.1153 317.2552 317.3952 317.5351 317.6750 317.8149 317.9548 318.0947 318.2346 318.3744 318.5143 318.6541 318.7939 318.9338 319.0736 319.2134 319.3531 319.4929 319.6327 319.7724 319.9121 320.0519 320.1916 320.3313 320.4710 320.6107 320.7503 320.8900 321.0296 321.1693 321.3089 321.4485 321.5881 321.7277 321.8673 322.0068 322.1464 322.2859 322.4255 322.5650 322.7045 322.8440 322.9835 323.1230 323.2624 323.4019 323.5413 323.6808 323.8202 323.9596 324.0990 324.2384 324.3777 324.5171 324.6564 324.7958 324.9351 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240524T095637.6Z 8910.414325 211 1 29.89 2 83.75 67.28 94.85 236.59 0.00 1 0.00 1 0 25 7.087e-01 8.057e-02 5.485e-01 7.688e-02 1.141767e+00 4.757566e-02 1.315270e-02 -6.000000e+00 4.456246e-01 231.64 -2.00 3.54 -2.00 321.76 0.00e+00 -1.809614e-02 1.331363e-02 1.540859e-03 -6.000000e+00 1.993527e-02 283.39 -2.00 20.00 -2.00 321.05 0.00e+00 8.263 0.011 302.00 328.00 3 1.7854e+00 1.4727e-01 1.0468e-01 -6.0000e+00 1.1164e+00 2.6352e+00 1.7227e-01 6.9877e-02 -6.0000e+00 1.2095e+00 -2.4175e+00 9.9264e-02 2.9203e-02 -6.0000e+00 7.1952e-01 7.2224e-01 5.5008e-02 1.5878e-02 -6.0000e+00 2.9890e-01 4.4154e-06 -5.9756e-04 1.9974e-03 2.3392e-04 -6.0000e+00 2.1231e-02 -3.3622e-02 0.0000e+00 12 9 8 11 8 0 84.90 21.63 1.14 -0.03362 -0.03811 8 8 1 5 0 3734.920 25.79 20.00 21.63 21.64 0.0 930.56 34024 8512 77579 61365 -18367 900000 131544 -26019 -7774 290053 112953 -56375 19758 29786 83414 900000 28200 900000 79802 -35974 900000 48749 -35706 97739 900000 -7277 62478 158639 284495 58378 -34712 -40987 -27029 -66261 900000 10095 -38805 -48633 18398 138634 -9452 -40384 900000 -7049 27436 34887 900000 80350 64291 900000 -42821 86975 95898 241086 161239 -3835 153489 150357 20121 -61033 900000 259837 19453 29800 14993 117853 -1208 76797 175671 56097 31637 40139 67816 22253 118167 -21910 -1491 -47394 2496 -7508 12181 78989 11490 8866 -19880 21248 12702 46191 29646 18291 -23640 14886 12940 -12564 12828 18090 -9886 8147 -10667 2109 944 -2272 6411 -4827 10046 -8643 5940 6705 4385 -8490 926 2672 -911 2945 -10118 -3666 -3095 1213 1101 5114 3166 11670 337 -5171 1554 -10281 -2465 -2443 8050 1349 -2554 2625 -2326 2616 -2379 -2957 4304 -1071 3449 -460 3508 -2772 -2849 3637 1183 5805 4592 -2160 900000 9843 -3145 -850 21703 8452 -11032 1933 2915 6242 900000 3409 900000 5971 -7454 900000 3648 -5960 7313 900000 -1089 4675 11870 21287 4368 -4795 -6841 -4356 -16018 900000 988 -6031 -9237 2118 10373 -1850 -11157 900000 -1258 3422 3698 900000 6012 4811 900000 -9859 6508 7176 18039 12065 -909 11485 11251 3387 -18970 900000 19442 2911 4460 2805 8818 -271 8141 13145 9095 7102 8510 10572 4995 8842 -5738 -288 -14481 514 -2013 3190 12313 3940 3372 -10536 7685 5148 13537 9982 6501 -11940 4827 4196 -5562 5039 8009 -6842 5436 -9578 1749 759 -1671 3798 -3010 5512 -6036 3778 4515 3391 -8735 1010 3216 -1216 3856 -14890 -4938 -4130 1596 1518 6920 4265 13534 409 -6416 1774 -12822 -2782 -2894 9939 2137 -4905 5336 -5438 6377 -6630 -8813 12318 -3258 9936 -1331 9055 -6896 -6662 SS 20240524T100745.8Z 8910.422058 214 1 30.17 2 81.85 69.06 96.52 238.30 0.00 1 0.00 1 0 25 5.735e-01 1.811e-02 3.548e-01 9.395e-03 9.455341e-01 5.621780e-03 1.123163e-02 -6.000000e+00 3.485068e-01 231.64 -2.00 3.54 -2.00 322.11 0.00e+00 1.916892e-02 3.381479e-03 3.568068e-03 -6.000000e+00 1.536882e-02 283.39 -2.00 20.00 -2.00 321.66 0.00e+00 6.605 0.005 302.00 328.00 3 1.3507e+00 2.2626e-02 8.5305e-02 -6.0000e+00 8.7422e-01 8.7921e-01 3.2273e-02 5.7180e-02 -6.0000e+00 9.4417e-01 -1.1105e+00 3.1233e-02 3.3244e-02 -6.0000e+00 5.6119e-01 4.3549e-01 1.4066e-02 2.1470e-02 -6.0000e+00 2.3462e-01 6.4367e-05 -1.5896e-03 2.5364e-04 3.6205e-04 -6.0000e+00 1.6965e-02 -3.4689e-02 0.0000e+00 12 9 8 11 8 0 98.64 21.63 0.75 -0.03469 -0.04663 31 31 1 5 0 972.970 25.79 20.00 21.63 22.01 0.0 931.83 -126100 -137846 -43501 -170229 -138104 -216693 -179949 -216145 -92460 -94209 -239370 -144786 -168418 900000 -104181 -64701 900000 34376 -91099 25625 44961 -48577 -15881 -37329 -91871 -33072 -67016 14948 -100226 -34606 140815 -53732 20629 8312 16692 -45795 -7389 5919 -11520 18693 25523 30398 28060 24249 43030 43292 34727 22943 18665 8852 10118 38120 23122 63516 13997 49129 30501 8610 25021 12050 23041 14277 23340 11799 17990 13574 6021 19315 15754 14342 18442 11052 6388 4348 1000 -7139 470 1747 -4776 3512 3324 6576 -1121 1552 -524 200 2824 1498 3771 -1409 -478 2546 -2890 -3308 -2802 -1341 -2366 -178 -3785 -2814 -2483 1333 45 -2153 -3766 -4075 -3597 -540 -1192 -147 -1330 -371 -1558 -767 -754 1269 1544 854 603 301 537 1261 2047 646 1315 985 743 2700 757 -914 200 -197 944 635 76 -44 226 162 -670 -562 -781 -456 206 -1155 -1607 -398 -2976 -1610 -4871 -2547 -4319 -847 -863 -5979 -1567 -2945 900000 -1822 -1067 900000 315 -2579 258 412 -979 -218 -615 -2608 -515 -1412 137 -3029 -602 1290 -1772 397 198 367 -1804 -196 152 -411 565 795 974 977 911 1379 1427 1304 1030 940 535 667 2130 1673 3316 1256 3195 2402 828 1971 1048 1815 1334 2287 1502 2406 2002 965 2777 2583 2706 3699 2510 1509 988 212 -1471 83 309 -1019 833 959 2156 -447 654 -238 95 1373 766 1889 -721 -231 1131 -1310 -1560 -1488 -839 -1631 -141 -3517 -2756 -2356 1094 33 -1541 -2816 -3250 -3036 -474 -1173 -165 -1744 -535 -2398 -1179 -1131 1812 2199 1270 950 493 873 1939 2945 910 1800 1309 962 3540 1146 -1657 378 -409 2093 1523 197 -122 639 463 -1918 -1563 -2042 -1085 457 SS 20240524T102456.4Z 8910.433986 219 1 29.95 2 78.86 71.78 99.16 240.89 0.00 1 0.00 1 0 25 5.100e-01 1.089e-02 1.800e-01 3.251e-03 7.549779e-01 1.834713e-03 8.927084e-03 -6.000000e+00 3.084152e-01 231.64 -2.00 3.54 -2.00 321.23 0.00e+00 1.152507e-02 9.006138e-04 2.985219e-03 -6.000000e+00 1.359242e-02 283.39 -2.00 20.00 -2.00 320.69 0.00e+00 4.994 0.002 302.00 328.00 3 1.5689e+00 6.2636e-03 6.5065e-02 -6.0000e+00 7.7299e-01 2.3256e-01 8.8029e-03 4.2486e-02 -6.0000e+00 8.3399e-01 -2.3443e-01 8.9951e-03 3.0065e-02 -6.0000e+00 4.9575e-01 7.7020e-02 4.2334e-03 1.6651e-02 -6.0000e+00 2.0799e-01 3.1538e-04 -2.0476e-04 8.9509e-05 2.0069e-04 -6.0000e+00 1.5011e-02 -3.4556e-02 0.0000e+00 12 8 8 10 0 0 98.20 21.65 0.49 -0.03456 -0.03609 62 62 1 5 0 482.870 25.79 20.00 21.65 22.69 0.0 934.95 12901 -196912 -149807 -213755 -149423 -129342 -145911 -137652 -223432 -139906 -79698 -191439 -100230 -113661 -47181 -74702 -25657 -11774 -54500 -33436 -49616 35388 -46226 -39493 -44648 -41470 777 -65057 -14546 -31936 -21940 -18760 -7643 7463 -12114 -3140 -19562 2041 -6935 -8178 -672 2425 7308 -2733 4444 5838 3065 6986 7693 14195 9319 8443 4782 7505 6366 1491 2853 -2433 -157 -2204 641 5953 4088 5583 1912 5149 2721 2754 4526 1128 3278 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