File name: Pandora107s1_LynnMA_20240707_L2Fit_fout2c7d20230718p1-8.txt File generation date: 20240916T090059.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 107 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora107_OF_v1d20230601.txt Instrument calibration file used: Pandora107s1_CF_v7d20230718.txt Level 1 file used: Pandora107s1_LynnMA_20240707_L1_smca1c7d20230718p1-8.txt Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20240707 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 6 First and last pixel inside fitting window: 220 362 Nominal wavelengths inside fitting window [nm]: 305.0382 305.1791 305.3200 305.4608 305.6017 305.7426 305.8834 306.0242 306.1650 306.3059 306.4467 306.5874 306.7282 306.8690 307.0097 307.1505 307.2912 307.4319 307.5727 307.7134 307.8540 307.9947 308.1354 308.2761 308.4167 308.5573 308.6980 308.8386 308.9792 309.1198 309.2604 309.4009 309.5415 309.6820 309.8226 309.9631 310.1036 310.2441 310.3846 310.5251 310.6656 310.8060 310.9465 311.0869 311.2273 311.3678 311.5082 311.6485 311.7889 311.9293 312.0697 312.2100 312.3504 312.4907 312.6310 312.7713 312.9116 313.0519 313.1922 313.3324 313.4727 313.6129 313.7531 313.8934 314.0336 314.1738 314.3139 314.4541 314.5943 314.7344 314.8746 315.0147 315.1548 315.2949 315.4350 315.5751 315.7152 315.8552 315.9953 316.1353 316.2754 316.4154 316.5554 316.6954 316.8354 316.9753 317.1153 317.2552 317.3952 317.5351 317.6750 317.8149 317.9548 318.0947 318.2346 318.3744 318.5143 318.6541 318.7939 318.9338 319.0736 319.2134 319.3531 319.4929 319.6327 319.7724 319.9121 320.0519 320.1916 320.3313 320.4710 320.6107 320.7503 320.8900 321.0296 321.1693 321.3089 321.4485 321.5881 321.7277 321.8673 322.0068 322.1464 322.2859 322.4255 322.5650 322.7045 322.8440 322.9835 323.1230 323.2624 323.4019 323.5413 323.6808 323.8202 323.9596 324.0990 324.2384 324.3777 324.5171 324.6564 324.7958 324.9351 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240707T131847.2Z 8954.554713 193 1 29.85 2 47.72 97.56 63.63 82.21 0.00 1 0.00 1 0 25 1.385e-02 9.476e-03 6.118e-03 2.821e-03 2.156770e-01 1.501963e-03 2.618822e-03 -6.000000e+00 8.417298e-03 233.00 -2.00 3.54 -2.00 316.36 0.00e+00 1.384179e-05 1.740692e-04 9.169975e-05 -6.000000e+00 3.758879e-04 287.66 -2.00 20.00 -2.00 315.57 0.00e+00 1.484 0.000 302.00 328.00 3 5.6006e+00 3.9464e-03 1.8825e-02 -6.0000e+00 2.1138e-02 5.0524e-02 4.3892e-03 1.1449e-02 -6.0000e+00 2.2768e-02 -1.0226e-02 2.5253e-03 5.5374e-03 -6.0000e+00 1.3553e-02 -1.0917e-03 1.1593e-03 1.5103e-03 -6.0000e+00 5.6921e-03 3.4183e-04 2.1469e-04 8.6134e-05 1.9404e-05 -6.0000e+00 4.0815e-04 -3.1229e-02 0.0000e+00 12 8 8 10 0 0 99.88 22.74 0.61 -0.03123 -0.02962 13 13 1 5 0 2295.830 26.83 20.00 22.74 34.38 0.0 979.68 -1710 -3496 -1186 -4675 -246 745 3233 3755 245 -2594 -2931 2287 1142 -233 618 -712 24 335 108 1571 -687 -999 2987 2563 40 239 -2265 -1036 272 2158 4199 1280 226 -3297 -1687 1450 400 1284 -1 -1146 -2321 -855 -698 -1162 -423 -683 -695 -460 -433 1258 861 925 1264 389 27 863 1050 279 398 1267 2271 1901 1141 -64 -1541 -859 431 1756 2787 840 -767 -1245 -1210 -1038 1120 -830 495 772 1809 946 -1482 -1470 -2436 -660 75 -256 -105 -735 175 -869 -346 10 1111 1871 1825 1007 961 33 -851 -1577 -861 -415 1020 794 -613 -1982 -1361 -325 23 676 40 -407 -252 133 716 1312 1839 877 952 -521 -907 -206 -47 -22 209 495 949 1871 1150 -258 -366 -883 109 11 122 -440 36 14 -232 -467 -168 -266 178 -301 -687 -234 -921 -44 121 513 651 49 -558 -639 481 256 -59 173 -218 8 110 36 539 -246 -361 1047 920 16 96 -925 -403 101 753 1431 473 90 -1388 -688 559 160 572 -1 -681 -1516 -582 -484 -817 -297 -478 -482 -311 -286 815 571 639 919 294 21 678 836 224 317 998 1791 1573 1000 -59 -1453 -781 364 1398 2269 748 -741 -1257 -1236 -1045 1065 -752 409 602 1400 788 -1369 -1456 -2561 -713 84 -302 -130 -935 222 -1092 -418 11 1164 1869 1854 1087 1112 40 -1113 -2103 -1107 -502 1176 926 -752 -2574 -1821 -443 33 980 60 -622 -379 191 969 1686 2318 1133 1283 -740 -1332 -302 -68 -31 285 651 1198 2316 1470 -349 -513 -1264 157 16 185 -693 57 23 -383 -768 -270 -417 275 SS 20240707T135628.0Z 8954.580880 212 1 3.64 2 40.92 105.35 56.94 88.12 0.00 1 0.00 1 0 25 1.625e-02 1.196e-02 8.377e-03 5.579e-03 1.889857e-01 3.010894e-03 2.321589e-03 -6.000000e+00 9.875705e-03 233.00 -2.00 3.54 -2.00 315.02 0.00e+00 4.314980e-04 2.642133e-04 3.501903e-05 -6.000000e+00 4.410021e-04 287.66 -2.00 20.00 -2.00 314.35 0.00e+00 1.322 0.000 302.00 328.00 3 4.7617e+00 7.7969e-03 1.6660e-02 -6.0000e+00 2.4800e-02 4.2541e-02 8.6085e-03 1.0037e-02 -6.0000e+00 2.6713e-02 -9.9174e-03 4.9119e-03 4.8579e-03 -6.0000e+00 1.5901e-02 -5.2534e-04 2.1395e-03 1.3478e-03 -6.0000e+00 6.6787e-03 9.7874e-04 2.1472e-04 1.6809e-04 1.8732e-05 -6.0000e+00 4.7882e-04 -3.1595e-02 0.0000e+00 12 9 9 12 1 1 999.00 22.86 0.31 -0.03160 -0.02998 1 17 1 5 0 1816.040 26.94 20.00 22.86 35.25 0.0 983.09 -71 -3160 -4595 -1890 -2127 1439 1834 5243 3102 -5901 -731 1936 3669 1661 1805 -600 -1575 -400 2177 942 178 1644 1052 1903 1363 143 -1853 -1398 1764 2684 3067 873 -1007 -3316 -2644 2001 752 736 2 -2667 -1375 -1447 -1514 -1121 -363 -946 -1501 -333 -1610 1593 1471 1381 199 -567 1109 2135 449 -326 448 928 1243 2704 1167 233 -1925 -1437 1285 2462 3383 447 -4 -1796 -115 -51 -1272 -1771 1162 968 1877 705 -1131 -1691 -1859 -1435 -513 125 -671 -706 30 -522 166 125 1335 2225 2576 536 336 614 -1019 -1798 -1429 -223 747 1320 -545 -2194 -1085 -1653 333 712 63 -198 252 389 902 1753 1951 1255 -494 -146 -472 -563 401 -161 265 76 171 1997 669 -363 185 -1450 375 115 531 -1123 -238 626 -1051 -556 -621 -25 1260 -22 -1059 -1589 -621 -660 407 515 1545 1013 -2138 -255 667 1297 646 762 -274 -747 -192 1047 467 90 827 531 969 725 79 -1028 -751 896 1311 1485 447 -548 -1852 -1451 1040 401 429 1 -1946 -1057 -1158 -1236 -918 -296 -774 -1217 -264 -1258 1209 1133 1100 166 -486 955 1853 398 -291 395 812 1097 2448 1110 229 -1934 -1402 1169 2142 2984 425 -4 -1884 -121 -53 -1288 -1715 1038 826 1593 632 -1094 -1733 -1986 -1578 -579 146 -816 -880 38 -644 198 142 1422 2277 2657 584 386 740 -1284 -2300 -1781 -264 854 1516 -654 -2758 -1395 -2174 443 975 89 -282 354 526 1161 2158 2367 1552 -638 -196 -649 -776 543 -214 344 96 210 2393 823 -465 243 -1948 503 158 743 -1631 -352 931 -1586 -834 -919 -36 1786 SS 20240707T140625.4Z 8954.587794 218 1 18.83 2 39.16 107.65 55.17 89.74 0.00 1 0.00 1 0 29 1.290e-02 1.017e-02 2.477e-03 1.592e-03 1.850950e-01 8.581891e-04 2.251316e-03 -6.000000e+00 7.837845e-03 233.00 -2.00 3.54 -2.00 315.20 0.00e+00 -6.364831e-06 7.772041e-05 4.417499e-05 -6.000000e+00 3.499941e-04 287.66 -2.00 20.00 -2.00 314.51 0.00e+00 1.288 0.000 302.00 328.00 3 4.5094e+00 2.2278e-03 1.6238e-02 -6.0000e+00 1.9682e-02 3.6782e-02 2.4630e-03 9.7656e-03 -6.0000e+00 2.1200e-02 -8.5143e-03 1.4043e-03 4.7325e-03 -6.0000e+00 1.2620e-02 -4.1066e-04 6.1313e-04 1.2943e-03 -6.0000e+00 5.3007e-03 1.3165e-03 1.0969e-04 4.8035e-05 1.7668e-05 -6.0000e+00 3.7999e-04 -3.1795e-02 0.0000e+00 12 9 9 12 1 1 99.82 22.89 0.39 -0.03180 -0.03097 15 25 1 5 0 1176.500 26.94 20.01 22.89 35.59 0.0 984.54 -392 -2476 -3099 -4195 -373 2138 1237 999 -275 -2862 -1212 2581 1439 413 76 -990 -319 1329 341 1094 480 604 2251 1862 1096 171 -1787 -1004 1171 2622 2054 1017 828 -2846 -2390 383 1335 1145 84 -1767 -2133 -1833 -915 -1053 -319 -472 -901 -229 -269 1005 1616 731 797 827 385 1126 611 488 806 1299 2098 1960 803 -633 -2098 -1128 791 1707 3187 745 -869 -1151 -1345 -456 -305 -635 181 958 1762 459 -946 -1523 -2205 -1094 -372 -377 -370 -310 -238 -657 -312 364 1368 2188 2008 932 479 207 -1245 -1782 -1203 -690 1117 1179 -750 -1722 -1017 -600 461 492 169 -559 -202 244 869 1703 1889 1184 832 -137 -835 -484 -229 -46 349 252 648 1887 898 -360 -691 -671 141 321 32 -419 -47 0 -512 -470 -217 -223 308 -118 -764 -984 -1287 -111 570 330 293 -84 -943 -393 881 477 154 32 -454 -140 589 156 512 231 293 1067 905 568 93 -982 -523 564 1277 995 485 423 -1537 -1256 189 667 654 54 -1239 -1654 -1412 -719 -834 -251 -369 -740 -181 -205 745 1212 582 673 682 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