File name: Pandora107s1_LynnMA_20240717_L2Fit_fout2c7d20230718p1-8.txt File generation date: 20240916T091032.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 107 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora107_OF_v1d20230601.txt Instrument calibration file used: Pandora107s1_CF_v7d20230718.txt Level 1 file used: Pandora107s1_LynnMA_20240717_L1_smca1c7d20230718p1-8.txt Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20240717 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 6 First and last pixel inside fitting window: 220 362 Nominal wavelengths inside fitting window [nm]: 305.0382 305.1791 305.3200 305.4608 305.6017 305.7426 305.8834 306.0242 306.1650 306.3059 306.4467 306.5874 306.7282 306.8690 307.0097 307.1505 307.2912 307.4319 307.5727 307.7134 307.8540 307.9947 308.1354 308.2761 308.4167 308.5573 308.6980 308.8386 308.9792 309.1198 309.2604 309.4009 309.5415 309.6820 309.8226 309.9631 310.1036 310.2441 310.3846 310.5251 310.6656 310.8060 310.9465 311.0869 311.2273 311.3678 311.5082 311.6485 311.7889 311.9293 312.0697 312.2100 312.3504 312.4907 312.6310 312.7713 312.9116 313.0519 313.1922 313.3324 313.4727 313.6129 313.7531 313.8934 314.0336 314.1738 314.3139 314.4541 314.5943 314.7344 314.8746 315.0147 315.1548 315.2949 315.4350 315.5751 315.7152 315.8552 315.9953 316.1353 316.2754 316.4154 316.5554 316.6954 316.8354 316.9753 317.1153 317.2552 317.3952 317.5351 317.6750 317.8149 317.9548 318.0947 318.2346 318.3744 318.5143 318.6541 318.7939 318.9338 319.0736 319.2134 319.3531 319.4929 319.6327 319.7724 319.9121 320.0519 320.1916 320.3313 320.4710 320.6107 320.7503 320.8900 321.0296 321.1693 321.3089 321.4485 321.5881 321.7277 321.8673 322.0068 322.1464 322.2859 322.4255 322.5650 322.7045 322.8440 322.9835 323.1230 323.2624 323.4019 323.5413 323.6808 323.8202 323.9596 324.0990 324.2384 324.3777 324.5171 324.6564 324.7958 324.9351 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240717T102520.5Z 8964.434265 99 1 30.32 2 80.31 70.25 142.90 284.08 0.00 1 0.00 1 0 17 5.067e-01 2.209e-02 3.448e-01 1.064e-02 7.499384e-01 6.227844e-03 9.936719e-03 -6.000000e+00 3.128599e-01 232.93 -2.00 3.54 -2.00 321.62 0.00e+00 1.343891e-02 3.425786e-03 7.932889e-03 -6.000000e+00 1.435718e-02 288.40 -2.00 20.00 -2.00 321.04 0.00e+00 5.663 0.003 302.00 328.00 3 2.7061e+00 2.3453e-02 7.7177e-02 -6.0000e+00 7.9024e-01 5.2100e-01 3.1645e-02 5.7001e-02 -6.0000e+00 8.5581e-01 -7.0191e-01 2.7758e-02 3.2245e-02 -6.0000e+00 5.0255e-01 2.8155e-01 1.2844e-02 1.1421e-02 -6.0000e+00 2.0967e-01 5.3203e-05 -8.0843e-04 3.0831e-04 2.5355e-04 -6.0000e+00 1.5401e-02 -2.7946e-02 0.0000e+00 12 8 8 10 0 0 97.84 22.32 0.60 -0.02795 -0.03402 22 22 1 5 0 1377.820 26.41 20.00 22.32 29.61 0.0 960.63 900000 -131830 -101257 35950 57523 -120197 -221770 900000 -157595 900000 -176443 -109908 -94973 -48765 53960 -114037 6342 -84148 -3232 900000 -67200 900000 -24184 106805 64450 49070 32753 -86900 64846 -14076 147706 168436 75906 46636 29240 900000 -7667 126507 -9295 -5943 13967 1323 74892 -2184 73393 5426 17504 40340 9702 48766 22668 34247 19227 17458 21327 5653 42851 6064 12986 -4582 13654 33169 7834 23566 5991 23602 17604 3768 9296 -527 10247 136 8058 2234 -1202 9133 -3961 10753 -9661 -1283 -2412 -3411 2116 -1203 3616 -587 799 -4261 -2289 702 -3028 2297 -194 886 -2368 -3012 -755 -934 -1423 -2757 -1755 -1561 1842 219 -3317 -3495 -3014 44 -885 -20 322 -2088 -498 -491 1027 1018 1412 2414 107 1010 -506 231 2663 400 1651 -1564 5058 2400 1049 -62 -366 -732 331 1349 16 -207 -365 145 -265 -1027 213 -1228 368 900000 -2485 -1527 373 596 -1812 -8778 900000 -3565 900000 -4989 -1761 -1611 -689 559 -4944 96 -3489 -64 900000 -2660 900000 -593 1107 668 601 463 -4013 672 -345 1531 1746 1288 1143 854 900000 -318 1705 -526 -375 803 94 2682 -175 2836 424 1254 2395 823 2987 1965 2937 2120 2106 2593 831 4402 892 1738 -717 1814 3939 1359 3953 1304 4426 3451 856 2182 -154 2984 46 2521 705 -360 2229 -1019 2381 -2895 -417 -943 -1556 1015 -644 1956 -350 498 -2900 -1532 443 -1892 1279 -106 486 -1486 -2220 -638 -835 -1424 -2932 -1780 -1554 1607 189 -3092 -3485 -3176 48 -980 -25 447 -3216 -780 -758 1501 1433 1972 3459 166 1622 -829 364 3902 580 2301 -2167 6349 3166 1558 -106 -710 -1536 730 2901 38 -509 -932 372 -682 -2607 505 -2964 835 SS 20240717T103300.7Z 8964.439591 104 1 30.95 2 78.97 71.46 144.21 285.77 0.00 1 0.00 1 0 46 6.410e-01 2.954e-02 3.787e-01 1.709e-02 6.603934e-01 9.882912e-03 8.812712e-03 -6.000000e+00 3.941067e-01 232.93 -2.00 3.54 -2.00 321.36 0.00e+00 9.686606e-03 4.919651e-03 7.456483e-03 -6.000000e+00 1.947736e-02 288.40 -2.00 20.00 -2.00 320.75 0.00e+00 5.037 0.002 302.00 328.00 3 4.1718e+00 3.5215e-02 7.0352e-02 -6.0000e+00 9.9323e-01 4.5456e-01 4.4674e-02 5.4138e-02 -6.0000e+00 1.0726e+00 -6.6290e-01 3.5359e-02 2.4477e-02 -6.0000e+00 6.3474e-01 2.7499e-01 1.6918e-02 5.9485e-03 -6.0000e+00 2.6742e-01 2.4983e-05 -8.5454e-04 5.2084e-04 1.8651e-04 -6.0000e+00 1.9623e-02 -2.7467e-02 0.0000e+00 12 8 8 10 0 0 99.61 22.33 1.21 -0.02747 -0.03389 9 9 1 5 0 3437.840 26.41 20.00 22.33 29.90 0.0 961.57 -175301 900000 59227 -69832 900000 -157884 22100 -180561 900000 177578 900000 -68742 -128678 88503 -81463 223937 -67074 900000 -35460 219878 81895 -40875 325904 94688 44976 -1098 109835 900000 127403 900000 900000 139292 27517 -27066 142870 6704 156943 -8755 44220 66419 46124 -5143 -1923 101271 23240 70417 30988 36999 28300 -757 16413 20223 18499 50947 37958 9149 8070 21202 13289 12542 21550 33970 13567 11715 9844 7704 23710 14079 6948 14441 -1639 6658 -5291 1779 1095 -5253 5892 -17055 1161 -8854 1118 -890 5089 -827 -6688 1597 -6943 1764 13 -3669 -1225 -5319 367 -1181 -4595 2439 -4726 2529 -2773 -3223 -2831 2664 -1944 -830 -498 -4892 -2236 288 -433 -220 -460 346 165 951 -1003 1105 3066 -734 1980 -169 618 -27 2054 176 1279 1535 1349 5809 1065 -42 -1656 527 1219 -6 1099 -831 -476 168 -1628 559 -890 -173 -592 -8701 900000 986 -1518 900000 -6827 368 -9793 900000 2955 900000 -1480 -5918 1473 -3734 3727 -3582 900000 -1608 3659 1363 -2028 5424 1576 974 -38 1828 900000 2120 900000 900000 2318 1123 -2012 2378 345 2612 -603 2152 2990 2822 -556 -211 4181 2091 4090 2696 3108 2682 -100 1985 2590 2623 5636 4994 1643 1488 3434 2253 2119 3378 5115 2754 2708 2490 2019 5194 3353 1924 4186 -611 2408 -2159 653 373 -1744 1609 -5709 355 -3442 463 -427 2543 -472 -4254 991 -4978 1204 9 -2583 -810 -3430 214 -702 -3057 1742 -4170 2348 -2976 -3631 -3057 2509 -1753 -733 -455 -4985 -2332 310 -513 -288 -665 527 258 1444 -1497 1561 4216 -1075 2993 -271 1003 -43 3098 261 1844 2121 1801 7603 1575 -70 -3117 1028 2465 -13 2501 -2018 -1181 419 -4140 1375 -2109 -386 -1269 SS 20240717T104808.0Z 8964.450092 113 1 29.95 2 76.31 73.83 146.76 289.35 0.00 1 0.00 1 0 25 1.909e-01 9.067e-03 6.670e-02 2.275e-03 5.684187e-01 1.241044e-03 6.835226e-03 -6.000000e+00 1.159431e-01 232.93 -2.00 3.54 -2.00 320.41 0.00e+00 7.043328e-03 4.786603e-04 2.168649e-03 -6.000000e+00 5.196566e-03 288.40 -2.00 20.00 -2.00 319.71 0.00e+00 4.125 0.001 302.00 328.00 3 2.0584e+00 3.8410e-03 5.1711e-02 -6.0000e+00 2.9103e-01 8.9185e-02 4.8261e-03 3.1406e-02 -6.0000e+00 3.1350e-01 -8.7742e-02 4.2373e-03 1.8733e-02 -6.0000e+00 1.8671e-01 2.0066e-02 2.1204e-03 8.4878e-03 -6.0000e+00 7.8445e-02 5.6418e-04 -2.0195e-04 6.6829e-05 1.0154e-04 -6.0000e+00 5.6276e-03 -2.8184e-02 0.0000e+00 11 8 0 10 0 0 49.00 22.36 0.36 -0.02818 -0.02970 74 74 1 5 0 404.440 26.41 20.00 22.36 30.18 0.0 962.68 -92700 -56761 -55435 -38811 -79691 -35272 -53854 -61944 -79408 -51060 -16012 -60292 -32187 -30049 -14046 -26284 -16222 -3053 -23016 2139 -15105 -9089 -9981 -18851 -14217 -18604 -8595 -18585 -7578 -8507 -10518 3715 -2641 3311 -8225 -3976 -1199 -1791 3958 -5697 -1980 -5229 -415 888 -1722 3228 2776 2940 2813 3878 3562 1867 4986 2982 1186 1322 -209 -1149 -1622 240 1768 4924 2094 1853 -71 183 2612 1727 4117 1128 -349 -749 -1772 -483 2452 129 -678 0 375 -70 -341 -1492 -1691 -833 -518 -548 -276 54 -301 -477 419 445 1134 1054 1190 101 483 152 -1225 -1207 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