File name: Pandora107s1_LynnMA_20240719_L2Fit_fout2c7d20230718p1-8.txt File generation date: 20240916T091101.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 107 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora107_OF_v1d20230601.txt Instrument calibration file used: Pandora107s1_CF_v7d20230718.txt Level 1 file used: Pandora107s1_LynnMA_20240719_L1_smca1c7d20230718p1-8.txt Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20240719 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 6 First and last pixel inside fitting window: 220 362 Nominal wavelengths inside fitting window [nm]: 305.0382 305.1791 305.3200 305.4608 305.6017 305.7426 305.8834 306.0242 306.1650 306.3059 306.4467 306.5874 306.7282 306.8690 307.0097 307.1505 307.2912 307.4319 307.5727 307.7134 307.8540 307.9947 308.1354 308.2761 308.4167 308.5573 308.6980 308.8386 308.9792 309.1198 309.2604 309.4009 309.5415 309.6820 309.8226 309.9631 310.1036 310.2441 310.3846 310.5251 310.6656 310.8060 310.9465 311.0869 311.2273 311.3678 311.5082 311.6485 311.7889 311.9293 312.0697 312.2100 312.3504 312.4907 312.6310 312.7713 312.9116 313.0519 313.1922 313.3324 313.4727 313.6129 313.7531 313.8934 314.0336 314.1738 314.3139 314.4541 314.5943 314.7344 314.8746 315.0147 315.1548 315.2949 315.4350 315.5751 315.7152 315.8552 315.9953 316.1353 316.2754 316.4154 316.5554 316.6954 316.8354 316.9753 317.1153 317.2552 317.3952 317.5351 317.6750 317.8149 317.9548 318.0947 318.2346 318.3744 318.5143 318.6541 318.7939 318.9338 319.0736 319.2134 319.3531 319.4929 319.6327 319.7724 319.9121 320.0519 320.1916 320.3313 320.4710 320.6107 320.7503 320.8900 321.0296 321.1693 321.3089 321.4485 321.5881 321.7277 321.8673 322.0068 322.1464 322.2859 322.4255 322.5650 322.7045 322.8440 322.9835 323.1230 323.2624 323.4019 323.5413 323.6808 323.8202 323.9596 324.0990 324.2384 324.3777 324.5171 324.6564 324.7958 324.9351 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240719T101719.5Z 8966.428698 150 1 30.00 2 81.96 69.22 123.54 259.71 0.00 1 0.00 1 0 25 3.906e-01 2.672e-02 3.343e-01 1.712e-02 9.217605e-01 1.018436e-02 1.029819e-02 -6.000000e+00 2.382892e-01 232.86 -2.00 3.54 -2.00 322.11 0.00e+00 -6.476628e-03 5.551182e-03 3.732060e-03 -6.000000e+00 1.067257e-02 288.44 -2.00 20.00 -2.00 321.58 0.00e+00 6.679 0.006 302.00 328.00 3 2.2251e+00 3.9673e-02 8.7664e-02 -6.0000e+00 5.9857e-01 1.1321e+00 5.1193e-02 6.3328e-02 -6.0000e+00 6.4585e-01 -1.6471e+00 3.6424e-02 2.6952e-02 -6.0000e+00 3.8424e-01 6.8224e-01 1.7146e-02 9.3935e-03 -6.0000e+00 1.6163e-01 2.7714e-05 -1.8021e-03 4.7605e-04 1.0821e-04 -6.0000e+00 1.1593e-02 -2.6565e-02 0.0000e+00 12 9 8 11 8 0 99.92 21.90 0.83 -0.02657 -0.04011 16 16 1 5 0 1874.610 26.11 20.00 21.90 24.00 0.0 937.61 900000 -25976 -43489 -30004 125904 -38912 -25358 21434 -99514 4947 -115695 -9573 -93160 29867 79007 -16214 900000 -35427 152239 8106 164809 6918 -51794 80137 -28466 25951 -29817 -16038 70337 -35317 21213 -40790 17902 14703 27494 45196 21321 17442 -20819 3341 39384 57575 131412 53221 86907 18624 50420 17420 38920 67098 39794 63366 35697 25327 29228 33908 64135 29164 56156 8983 22003 -6022 22434 35379 8576 29394 10896 33415 6223 27089 29085 6435 16986 3401 2375 2509 12239 8036 -8881 2653 -2012 751 3570 3113 2031 1983 1186 -3702 182 1017 -1190 6277 -2887 8007 -6607 -4015 930 -144 -2900 -7021 -4929 -4638 -752 -1784 -4082 -593 -7486 -2940 -3829 -3227 -2023 -619 -741 1962 1190 -362 605 -33 875 2436 -82 3147 990 3800 2046 1541 2644 3330 1732 -59 28 -1480 603 851 1179 298 -821 575 -1128 -612 -485 -433 -816 900000 -946 -1847 -1001 2101 -1063 -577 358 -5435 98 -7723 -232 -5794 634 1318 -713 900000 -2096 2540 307 2750 266 -3143 1471 -1663 909 -1742 -749 1291 -1827 673 -2791 777 687 1101 1433 854 815 -1702 251 2300 2978 3289 2842 3191 1305 2524 1221 2273 3135 2656 3701 3038 2578 3024 3508 5030 3212 4498 1079 2240 -844 2621 4074 1402 4022 1782 4461 1205 4837 5630 1643 3883 840 535 502 2042 1395 -2015 633 -601 254 1323 1262 885 910 578 -1958 92 494 -562 2608 -1277 3300 -3550 -2479 646 -117 -2468 -6583 -4389 -4086 -573 -1325 -3222 -483 -6946 -2786 -4070 -3568 -2535 -846 -1070 2778 1657 -498 821 -46 1295 3681 -127 4507 1375 4964 2666 2149 3547 4579 2480 -101 55 -3195 1370 2082 3095 834 -2399 1671 -3307 -1731 -1281 -1043 -1858 SS 20240719T103510.1Z 8966.441089 156 1 29.77 2 78.86 72.05 126.63 262.27 0.00 1 0.00 1 0 25 6.154e-01 1.340e-02 2.299e-01 4.319e-03 7.426178e-01 2.444381e-03 8.985002e-03 -6.000000e+00 3.736429e-01 232.86 -2.00 3.54 -2.00 321.30 0.00e+00 1.050772e-02 1.257976e-03 4.508207e-03 -6.000000e+00 1.688936e-02 288.44 -2.00 20.00 -2.00 320.70 0.00e+00 4.990 0.002 302.00 328.00 3 2.0412e+00 8.7114e-03 6.6084e-02 -6.0000e+00 9.3763e-01 2.5758e-01 1.2066e-02 4.5046e-02 -6.0000e+00 1.0102e+00 -2.9533e-01 1.1515e-02 2.8903e-02 -6.0000e+00 6.0179e-01 1.0276e-01 5.3940e-03 1.2590e-02 -6.0000e+00 2.5398e-01 2.0126e-04 -2.8108e-04 1.2129e-04 1.8903e-04 -6.0000e+00 1.8172e-02 -2.7782e-02 0.0000e+00 12 8 8 10 0 0 95.41 21.92 0.61 -0.02778 -0.02989 44 44 1 5 0 676.200 26.11 20.00 21.92 24.16 0.0 938.98 -214854 900000 -181430 157193 -215251 -152062 -174444 -220156 -111690 -204660 -71003 -183264 -147688 23354 -127648 293411 -70385 28755 -60599 109358 -15217 -60142 -26971 -49192 -26328 -19590 -69713 -22936 -49147 -8821 -29267 9339 -13244 -11226 -4701 -28061 45 -13490 13342 -6818 5558 8475 -6520 4170 -5139 6735 5202 2478 5712 4720 14464 4363 12565 7608 8467 5530 4145 8343 -4896 10278 6035 6058 7708 5677 7826 2775 8228 4758 5312 3203 764 3224 -1426 -738 517 -676 1521 -1726 2665 -2255 1738 -933 -2073 -1398 -2358 556 -1401 -274 -473 -275 -381 389 2051 -556 653 -686 -275 317 -1509 -1172 -1811 143 1158 284 -1364 -3512 -1663 -407 264 34 -465 -628 -561 -239 542 1788 1690 1037 1003 -734 -287 -140 1021 -161 220 179 1439 2670 235 -357 -800 -235 412 644 514 -772 132 -152 -376 -702 -721 395 619 -2386 900000 -2014 662 -3297 -1281 -1837 -3625 -753 -3706 -359 -3242 -2301 98 -2903 1236 -1334 230 -1302 461 -231 -1444 -466 -1098 -499 -363 -2143 -444 -1283 -167 -801 216 -463 -421 -168 -1253 2 -625 573 -422 344 560 -535 321 -450 542 443 228 539 485 1486 557 1651 1141 1334 939 731 1413 -930 1653 1037 1135 1617 1380 1846 709 2162 1195 1458 1021 277 1206 -559 -275 175 -209 470 -551 899 -856 754 -480 -1198 -867 -1567 380 -1034 -208 -359 -203 -268 254 1260 -357 459 -569 -243 320 -1719 -1389 -2074 144 1147 277 -1291 -3621 -1783 -458 324 47 -668 -976 -897 -374 807 2736 2573 1644 1553 -1204 -469 -220 1645 -254 335 263 2015 3780 379 -613 -1540 -482 828 1378 1179 -1892 331 -387 -957 -1753 -1703 857 1281 SS 20240719T104535.5Z 8966.448327 162 1 7.99 2 77.02 73.69 128.44 263.79 0.00 1 0.00 1 0 25 5.162e-01 2.749e-02 3.503e-01 2.070e-02 6.522708e-01 1.162673e-02 8.753834e-03 -6.000000e+00 3.180573e-01 232.86 -2.00 3.54 -2.00 320.73 0.00e+00 1.369375e-02 4.890432e-03 5.386624e-03 -6.000000e+00 1.499584e-02 288.44 -2.00 20.00 -2.00 320.06 0.00e+00 4.335 0.001 302.00 328.00 3 3.9889e+00 3.7202e-02 5.8540e-02 -6.0000e+00 8.0197e-01 3.6645e-01 4.7019e-02 4.0381e-02 -6.0000e+00 8.6697e-01 -4.1172e-01 3.9418e-02 2.6469e-02 -6.0000e+00 5.0925e-01 1.5703e-01 1.9407e-02 1.2304e-02 -6.0000e+00 2.1391e-01 5.5461e-05 -2.7718e-04 5.9701e-04 1.9746e-04 -6.0000e+00 1.5598e-02 -2.6999e-02 0.0000e+00 12 9 9 12 1 1 999.00 21.94 1.36 -0.02700 -0.02908 1 8 1 5 0 3990.700 26.11 20.00 21.94 24.29 0.0 938.78 900000 -79615 -74399 900000 -178514 2066 900000 -159095 900000 900000 -104767 -89114 -115575 -75946 -114104 164559 -31860 17661 -66867 117292 900000 -54520 -10002 -5446 195559 327359 -30808 23593 -37710 -7379 28527 86303 85535 22157 -1533 -5573 -29949 -25494 13096 -28821 41058 28269 -6085 -860 6158 8883 12253 32755 31400 19765 22208 24173 38201 8335 3650 19172 12014 -5973 -1298 5199 5428 1058 3990 14212 3068 8207 -3683 -1204 2821 -2529 9694 12396 -230 -5212 5362 -7263 3080 -9737 -2326 -3609 1221 -3104 2874 -80 -3246 3798 -1354 -1736 -6342 -3057 5052 -606 1531 -2186 -642 -814 812 -1095 -964 -3677 -3612 434 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