File name: Pandora107s1_LynnMA_20240815_L2Fit_fout2c7d20230718p1-8.txt File generation date: 20240916T091850.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 107 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora107_OF_v1d20230601.txt Instrument calibration file used: Pandora107s1_CF_v7d20230718.txt Level 1 file used: Pandora107s1_LynnMA_20240815_L1_smca1c7d20230718p1-8.txt Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20240815 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 6 First and last pixel inside fitting window: 220 362 Nominal wavelengths inside fitting window [nm]: 305.0382 305.1791 305.3200 305.4608 305.6017 305.7426 305.8834 306.0242 306.1650 306.3059 306.4467 306.5874 306.7282 306.8690 307.0097 307.1505 307.2912 307.4319 307.5727 307.7134 307.8540 307.9947 308.1354 308.2761 308.4167 308.5573 308.6980 308.8386 308.9792 309.1198 309.2604 309.4009 309.5415 309.6820 309.8226 309.9631 310.1036 310.2441 310.3846 310.5251 310.6656 310.8060 310.9465 311.0869 311.2273 311.3678 311.5082 311.6485 311.7889 311.9293 312.0697 312.2100 312.3504 312.4907 312.6310 312.7713 312.9116 313.0519 313.1922 313.3324 313.4727 313.6129 313.7531 313.8934 314.0336 314.1738 314.3139 314.4541 314.5943 314.7344 314.8746 315.0147 315.1548 315.2949 315.4350 315.5751 315.7152 315.8552 315.9953 316.1353 316.2754 316.4154 316.5554 316.6954 316.8354 316.9753 317.1153 317.2552 317.3952 317.5351 317.6750 317.8149 317.9548 318.0947 318.2346 318.3744 318.5143 318.6541 318.7939 318.9338 319.0736 319.2134 319.3531 319.4929 319.6327 319.7724 319.9121 320.0519 320.1916 320.3313 320.4710 320.6107 320.7503 320.8900 321.0296 321.1693 321.3089 321.4485 321.5881 321.7277 321.8673 322.0068 322.1464 322.2859 322.4255 322.5650 322.7045 322.8440 322.9835 323.1230 323.2624 323.4019 323.5413 323.6808 323.8202 323.9596 324.0990 324.2384 324.3777 324.5171 324.6564 324.7958 324.9351 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240815T112027.9Z 8993.472545 91 1 29.71 2 74.86 84.99 157.48 300.53 0.00 1 0.00 1 0 25 2.683e-01 1.232e-02 2.151e-01 7.617e-03 5.871167e-01 4.221145e-03 7.113320e-03 -6.000000e+00 1.628489e-01 231.84 -2.00 3.54 -2.00 320.49 0.00e+00 3.632498e-03 1.641295e-03 2.564153e-03 -6.000000e+00 7.594113e-03 288.97 -2.00 20.00 -2.00 319.79 0.00e+00 3.753 0.001 302.00 328.00 3 4.4146e+00 1.3170e-02 5.0171e-02 -6.0000e+00 4.0805e-01 1.3775e-01 1.6720e-02 3.4464e-02 -6.0000e+00 4.4021e-01 -1.1296e-01 1.4651e-02 1.7974e-02 -6.0000e+00 2.6146e-01 3.6790e-02 7.3000e-03 5.3982e-03 -6.0000e+00 1.1004e-01 7.2107e-05 -2.0805e-04 2.2645e-04 8.0002e-05 -6.0000e+00 7.9359e-03 -2.7584e-02 0.0000e+00 12 8 8 10 0 0 37.78 22.15 0.99 -0.02758 -0.02915 9 9 1 5 0 3299.300 26.32 19.99 22.15 27.65 0.0 952.23 -74714 -63693 -90407 -142911 -103251 900000 -80677 19637 -50488 900000 -43064 10334 -54678 -65060 -73907 -35386 -42879 36640 32587 13052 29013 60799 17501 44248 -19933 -40006 -37890 -14003 -10436 -21509 12458 -32147 32286 -9445 31342 -5302 48834 151 8603 15221 -6146 -9196 6792 1257 10340 4631 3284 -4906 8004 1949 5405 -1067 2562 4915 -2155 1945 -665 -6106 1830 1526 3695 3029 7037 2609 181 3523 4922 -1648 5148 400 -1198 2686 731 -130 -1141 -4313 1143 387 533 600 -515 -1720 -1551 528 -15 -1209 -766 186 426 -589 -1404 724 2559 1378 415 -595 818 -428 -1469 -2469 -1024 -258 261 715 -2130 -2409 -506 -53 1229 512 -467 -357 93 918 1094 1202 1440 362 775 -1190 59 -111 -147 907 470 -991 1380 1390 572 -317 -297 -539 103 602 219 -439 -275 897 -708 -428 -630 -198 732 -721 -662 -1343 -3280 -1687 900000 -1018 146 -600 900000 -544 84 -1015 -1691 -2634 -1025 -1528 653 653 339 668 1038 468 953 -888 -2317 -2166 -624 -449 -1070 490 -2339 1438 -687 1536 -370 2067 12 773 1514 -858 -1448 963 194 1489 719 527 -874 1296 353 1023 -238 611 1233 -613 556 -201 -1959 534 440 1059 940 2341 1007 69 1315 1926 -685 2167 181 -612 1396 390 -67 -554 -1962 498 165 244 286 -290 -1116 -1105 396 -12 -1039 -695 173 397 -538 -1229 578 1885 1023 336 -553 858 -513 -1787 -3139 -1228 -303 279 754 -2420 -2925 -637 -64 1584 734 -741 -600 157 1493 1680 1753 2067 541 1219 -1998 98 -183 -231 1362 687 -1406 1835 1863 840 -526 -541 -1043 206 1174 455 -971 -627 2049 -1643 -970 -1364 -400 1408 SS 20240815T113113.8Z 8993.480020 94 1 29.11 2 72.88 86.77 159.07 304.80 0.00 1 0.00 1 0 25 2.117e-01 1.180e-02 1.313e-01 5.513e-03 5.217870e-01 2.987913e-03 6.190333e-03 -6.000000e+00 1.280821e-01 231.84 -2.00 3.54 -2.00 320.07 0.00e+00 5.099983e-03 1.025421e-03 1.255005e-03 -6.000000e+00 5.777495e-03 288.97 -2.00 20.00 -2.00 319.33 0.00e+00 3.345 0.001 302.00 328.00 3 4.3834e+00 8.8903e-03 4.3737e-02 -6.0000e+00 3.2056e-01 1.1163e-01 1.0828e-02 2.8028e-02 -6.0000e+00 3.4556e-01 -7.4998e-02 8.8460e-03 1.5319e-02 -6.0000e+00 2.0607e-01 1.8820e-02 4.5152e-03 6.4591e-03 -6.0000e+00 8.6817e-02 1.1839e-04 -2.1383e-04 1.6444e-04 7.5895e-05 -6.0000e+00 6.2405e-03 -2.7640e-02 0.0000e+00 12 8 8 10 0 0 97.87 22.12 0.61 -0.02764 -0.02925 11 11 1 5 0 2645.490 26.21 19.99 22.12 28.34 0.0 955.03 -77698 -127674 61554 -72207 -61042 8057 -88275 -1621 -72691 -61704 -52715 -39467 -5251 -14446 30849 -18866 30831 -25974 10356 11219 -2705 2235 -4425 -7394 -991 -7282 -7643 4643 832 -14218 -6350 -8143 -1692 3234 -9539 14103 -2251 -1029 -4344 -1492 -163 2415 -926 -160 5104 -1928 2859 8535 -1121 1118 -711 2233 2147 2429 3927 1832 -1295 10 2866 1666 1368 4881 1536 2604 716 1282 2471 2479 3172 1541 1739 -294 -597 856 -7888 1050 -1618 649 -167 -966 -121 -961 -1177 -976 27 -99 -296 -1568 -233 636 1431 1464 -823 2278 167 -254 -116 -322 -1122 -1689 -392 -966 1549 2010 -1382 -1910 -1220 -1150 121 1556 48 -1098 -172 -328 826 1695 1519 1012 617 -686 -1037 160 180 636 383 -202 1746 1485 1071 -570 -590 -215 85 507 358 -310 -87 56 -59 -1017 -14 -298 273 -1291 -4181 364 -1630 -1181 74 -2136 -18 -1876 -1526 -1247 -891 -99 -373 630 -751 845 -1382 412 470 -135 108 -231 -413 -56 -462 -489 260 48 -986 -447 -683 -154 299 -1010 1160 -226 -118 -626 -223 -27 426 -178 -32 975 -402 579 1660 -246 250 -174 582 615 743 1242 616 -461 4 968 563 473 1751 633 1171 347 617 1126 1112 1519 844 1052 -192 -394 536 -5023 556 -806 306 -84 -559 -81 -730 -982 -797 23 -91 -287 -1599 -234 618 1311 1245 -728 1930 141 -244 -127 -396 -1400 -2190 -520 -1167 1683 2155 -1609 -2384 -1595 -1579 162 2260 77 -1875 -293 -538 1262 2432 2150 1484 961 -1136 -1755 262 283 962 562 -285 2503 2143 1543 -930 -1050 -401 153 956 717 -657 -191 124 -132 -2248 -29 -587 518 SS 20240815T113835.9Z 8993.485137 98 1 30.16 2 71.52 87.99 160.11 308.04 0.00 1 0.00 1 0 25 1.028e-01 9.774e-03 6.493e-02 3.130e-03 4.991902e-01 1.674390e-03 5.907878e-03 -6.000000e+00 6.215909e-02 231.84 -2.00 3.54 -2.00 319.67 0.00e+00 3.801463e-03 5.074115e-04 1.046232e-03 -6.000000e+00 2.803888e-03 288.96 -2.00 20.00 -2.00 318.90 0.00e+00 3.114 0.001 302.00 328.00 3 3.7650e+00 4.8446e-03 4.1183e-02 -6.0000e+00 1.5557e-01 8.7500e-02 5.7871e-03 2.6763e-02 -6.0000e+00 1.6770e-01 -5.0594e-02 4.5771e-03 1.4036e-02 -6.0000e+00 1.0001e-01 8.6203e-03 2.3697e-03 5.2242e-03 -6.0000e+00 4.2132e-02 2.8352e-04 -7.1196e-05 9.2909e-05 5.8867e-05 -6.0000e+00 3.0286e-03 -2.7535e-02 0.0000e+00 12 9 8 11 8 0 8.69 22.11 0.79 -0.02754 -0.02807 21 21 1 5 0 1435.520 26.21 20.00 22.11 28.81 0.0 957.00 -58238 -34737 -16309 5945 -29395 30897 12058 -50048 49377 -20169 -18363 -12897 -20394 -10124 -17904 5662 -9903 917 -3387 2093 3701 -2921 4570 -6095 -1326 -12750 -901 -6680 -6138 -1448 -3849 6835 -1045 1001 -4718 -4337 1595 1463 934 -3501 -4500 -1102 -4667 741 -928 1462 -640 1239 320 850 3699 1311 3377 2618 1164 1042 -1182 24 -216 1808 2453 3486 1942 522 200 -467 2234 2492 2953 1392 -911 -1161 -1166 -1030 -1588 54 -859 802 1341 -310 -682 -1196 -1938 -1401 -399 -114 -470 -428 -271 -101 758 156 1966 2035 1893 704 314 300 -1576 -1773 -1426 -87 1394 1048 -1198 -2401 -927 -874 819 722 136 -614 -160 512 679 2085 1554 1362 364 -735 -670 -859 479 -257 -140 -244 659 1910 685 -281 -737 -804 359 306 44 -616 138 54 -468 -430 -401 265 759 -1156 -647 -274 80 -538 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