File name: Pandora107s1_LynnMA_20240927_L2Fit_fout2c8d20240424p1-8.txt File generation date: 20241009T193559.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Gonzalo Gonzalez Abad Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 107 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora107_OF_v3d20230601.txt Instrument calibration file used: Pandora107s1_CF_v8d20240424.txt Level 1 file used: Pandora107s1_LynnMA_20240927_L1_smca1c8d20240424p1-8.txt Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20240927 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld based on session 7 "OOB session based on clearance session 6, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used" First and last pixel inside fitting window: 221 362 Nominal wavelengths inside fitting window [nm]: 305.1394 305.2803 305.4212 305.5621 305.7030 305.8438 305.9847 306.1255 306.2663 306.4071 306.5479 306.6887 306.8295 306.9702 307.1110 307.2517 307.3925 307.5332 307.6739 307.8146 307.9553 308.0959 308.2366 308.3773 308.5179 308.6585 308.7991 308.9397 309.0803 309.2209 309.3615 309.5021 309.6426 309.7832 309.9237 310.0642 310.2047 310.3452 310.4857 310.6262 310.7666 310.9071 311.0475 311.1880 311.3284 311.4688 311.6092 311.7496 311.8899 312.0303 312.1706 312.3110 312.4513 312.5916 312.7319 312.8722 313.0125 313.1528 313.2930 313.4333 313.5735 313.7137 313.8540 313.9942 314.1344 314.2745 314.4147 314.5549 314.6950 314.8352 314.9753 315.1154 315.2555 315.3956 315.5357 315.6757 315.8158 315.9558 316.0959 316.2359 316.3759 316.5159 316.6559 316.7959 316.9358 317.0758 317.2157 317.3557 317.4956 317.6355 317.7754 317.9153 318.0552 318.1950 318.3349 318.4747 318.6145 318.7544 318.8942 319.0340 319.1738 319.3135 319.4533 319.5930 319.7328 319.8725 320.0122 320.1519 320.2916 320.4313 320.5710 320.7106 320.8503 320.9899 321.1295 321.2691 321.4087 321.5483 321.6879 321.8275 321.9670 322.1066 322.2461 322.3856 322.5251 322.6646 322.8041 322.9436 323.0831 323.2225 323.3619 323.5014 323.6408 323.7802 323.9196 324.0590 324.1983 324.3377 324.4771 324.6164 324.7557 324.8950 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240927T122547.3Z 9036.517908 275 1 35.13 2 71.31 111.00 21.12 157.49 0.00 1 0.00 1 0 17 3.846e-02 8.967e-03 1.694e-02 2.522e-03 3.895233e-01 1.301108e-03 4.712907e-03 -6.000000e+00 2.242768e-02 227.67 -2.00 3.54 -2.00 318.44 0.00e+00 1.264619e-03 2.637152e-04 5.680556e-04 -6.000000e+00 1.000272e-03 284.96 -2.00 20.00 -2.00 317.69 0.00e+00 3.081 0.001 302.00 328.00 3 3.8367e+00 3.5237e-03 3.6788e-02 -6.0000e+00 5.5647e-02 4.5583e-02 4.0205e-03 2.0471e-02 -6.0000e+00 6.0304e-02 -1.6208e-02 2.7212e-03 1.0122e-02 -6.0000e+00 3.5959e-02 -2.8262e-04 1.4260e-03 2.9212e-03 -6.0000e+00 1.5389e-02 3.3197e-04 -5.4059e-04 7.3970e-05 3.2376e-05 -6.0000e+00 1.0830e-03 1.5375e-02 0.0000e+00 12 9 1 12 1 1 99.87 22.10 0.13 0.01537 0.01131 15 4 1 5 0 2194.790 26.21 20.00 22.10 24.43 0.0 938.25 -137 -14109 -7997 -14661 -5682 -9336 -13183 5544 -17368 16727 -15510 -6202 -4959 1147 699 -609 3270 1764 589 -4282 -1341 3786 2067 -4217 -70 -1603 -655 -1749 -2623 212 3764 -2151 -3113 -2770 -2655 -834 -8054 398 -604 -1225 502 -1315 -151 843 1000 -311 -472 823 -87 3665 1325 2578 1364 2475 1692 539 -332 -942 1248 1803 1624 2039 998 -95 -1112 549 1287 2761 304 269 -1012 -283 -658 -1327 -981 136 284 513 -358 -940 -1962 -1785 -1231 -850 124 -378 -512 -101 -58 -394 229 1719 1251 1004 121 -74 668 -377 -1355 -1556 -67 823 702 -1304 -1847 -1218 -458 335 457 739 27 -164 505 473 1722 1423 983 789 -120 -563 -335 567 -52 -363 -113 445 2108 739 -296 -1012 -599 125 -231 -131 -382 -118 -25 -205 -525 -250 134 697 -6 -720 -380 -690 -230 -401 -661 263 -1101 790 -1037 -426 -399 103 72 -69 382 221 78 -613 -189 515 300 -696 -12 -276 -109 -283 -424 35 680 -455 -700 -613 -569 -183 -2142 117 -206 -463 199 -549 -64 355 425 -133 -203 349 -38 1624 639 1315 736 1373 971 318 -199 -559 722 1051 998 1342 705 -69 -805 375 856 1893 232 221 -872 -245 -559 -1081 -748 96 193 357 -273 -792 -1802 -1737 -1243 -892 135 -430 -599 -118 -67 -439 241 1698 1211 1010 131 -87 836 -500 -1835 -2051 -83 964 823 -1607 -2388 -1619 -624 473 674 1139 42 -258 772 694 2412 1975 1396 1165 -185 -881 -521 861 -77 -531 -161 613 2861 1051 -449 -1612 -974 207 -392 -230 -692 -217 -46 -384 -979 -455 236 1206 SS 20240927T123023.1Z 9036.521101 277 1 8.09 2 70.52 111.89 20.83 160.28 0.00 1 0.00 1 0 25 2.697e-02 8.504e-03 1.093e-02 2.273e-03 3.759447e-01 1.173578e-03 4.537857e-03 -6.000000e+00 1.573132e-02 227.67 -2.00 3.54 -2.00 317.99 0.00e+00 1.254825e-03 2.066293e-04 3.709205e-04 -6.000000e+00 7.016308e-04 284.96 -2.00 20.00 -2.00 317.22 0.00e+00 2.964 0.000 302.00 328.00 3 2.4129e+00 3.1374e-03 3.5358e-02 -6.0000e+00 3.9032e-02 3.5245e-02 3.5510e-03 1.9588e-02 -6.0000e+00 4.2299e-02 -2.1224e-02 2.2741e-03 9.6591e-03 -6.0000e+00 2.5223e-02 3.0843e-03 1.1702e-03 2.8125e-03 -6.0000e+00 1.0794e-02 1.5821e-03 -5.2129e-04 6.6410e-05 3.0949e-05 -6.0000e+00 7.5967e-04 1.5517e-02 0.0000e+00 12 9 1 12 1 1 97.37 22.10 0.28 0.01552 0.01160 14 18 1 5 0 538.710 26.21 20.00 22.10 24.51 0.0 938.31 -4502 -11274 -5329 -12540 -7274 -9329 -7440 -3642 -8693 -7584 -6148 -6830 -7378 -2168 161 -2091 3979 2461 -525 -1877 924 2003 -201 -28 -2362 -1634 -2205 -348 851 2004 946 -1478 -2103 -3074 -668 -10 -585 281 -423 -602 -1475 -502 -920 312 -80 1087 647 -35 1097 1750 2148 1709 995 2109 1287 614 486 -128 834 2284 2319 2190 849 -606 -511 154 1021 1533 -473 -444 -1043 -656 -225 -954 -541 354 668 423 -421 -1420 -1484 -1705 -1569 -573 -428 -178 -629 -396 243 -160 137 935 1367 1009 285 410 262 -823 -1592 -1136 -552 685 559 -1168 -2022 -1048 -587 665 765 425 77 125 217 831 1382 1452 1263 563 -140 -707 -343 377 266 -41 -23 669 1798 718 -374 -825 -739 217 397 -224 -409 -168 377 31 -888 -201 -267 325 -289 -749 -360 -839 -430 -575 -506 -271 -732 -647 -537 -614 -795 -264 22 -319 607 403 -93 -348 168 363 -39 -6 -491 -371 -488 -72 172 424 209 -374 -568 -824 -169 -3 -178 95 -170 -253 -674 -237 -445 150 -39 523 311 -17 533 890 1181 954 595 1303 829 409 325 -85 540 1482 1505 1566 630 -474 -387 115 732 1155 -385 -379 -949 -601 -199 -797 -433 270 481 316 -335 -1236 -1372 -1719 -1593 -611 -464 -205 -757 -477 284 -177 147 960 1351 1051 315 485 330 -1087 -2168 -1466 -675 806 659 -1424 -2658 -1373 -802 912 1132 651 117 189 326 1198 1942 2001 1800 823 -210 -1096 -526 555 394 -58 -32 900 2377 1021 -564 -1290 -1153 344 659 -382 -709 -300 684 57 -1620 -350 -460 540 SS 20240927T123150.8Z 9036.522116 279 1 2.25 2 70.27 112.17 20.75 161.18 0.00 1 0.00 1 0 17 3.972e-02 1.066e-02 4.270e-02 8.294e-03 3.831175e-01 4.277320e-03 4.633897e-03 -6.000000e+00 2.316668e-02 227.67 -2.00 3.54 -2.00 318.01 0.00e+00 6.021767e-04 7.618767e-04 2.981777e-04 -6.000000e+00 1.033134e-03 284.96 -2.00 20.00 -2.00 317.24 0.00e+00 2.929 0.000 302.00 328.00 3 3.0765e+00 1.1447e-02 3.5327e-02 -6.0000e+00 5.7481e-02 6.8990e-02 1.2967e-02 2.0019e-02 -6.0000e+00 6.2289e-02 -2.7170e-02 8.3476e-03 9.8292e-03 -6.0000e+00 3.7143e-02 1.5479e-03 4.3152e-03 2.7609e-03 -6.0000e+00 1.5897e-02 8.2044e-04 -6.6342e-04 2.4115e-04 3.1130e-05 -6.0000e+00 1.1186e-03 1.4792e-02 0.0000e+00 12 9 9 12 1 1 999.00 22.10 0.50 0.01479 0.00981 1 8 1 5 0 1120.910 26.21 19.99 22.10 24.51 0.0 938.35 -2365 -2964 -22962 -14646 4173 -10630 5165 -9389 4037 1111 -13514 -13702 4292 17435 -1014 7957 -8116 1638 1289 -210 2183 -4879 1692 1763 -4536 -443 734 3304 -146 145 309 -4121 -671 -2877 4306 -144 -3045 -622 537 -2149 -2510 1196 -1294 2218 -894 -647 457 -902 1249 653 4751 1382 1326 -160 2012 2134 -611 845 496 787 1164 2049 126 -1379 -1796 2292 3213 2201 -1480 -450 -10 370 -1116 -1972 -685 -1195 884 1596 259 -2010 -1435 -2387 -1607 -440 321 843 -398 -130 -184 -320 799 1505 1941 1197 -586 -1471 327 97 -617 -106 -1031 87 1461 -1812 -1640 -1942 -397 760 1132 1154 -662 168 -251 603 918 1294 282 477 -226 -433 525 -581 481 217 131 -13 1807 1248 34 -1332 -44 -423 -93 -55 -538 -88 910 -40 -79 -518 -1211 870 -138 -185 -1697 -931 208 -624 293 -693 282 82 -1187 -1343 418 1771 -138 1080 -1344 262 216 -37 377 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