File name: Pandora107s1_LynnMA_20240928_L2Fit_fout2c7d20230718p1-8.txt File generation date: 20240929T043859.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Gonzalo Gonzalez Abad Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 107 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora107_OF_v3d20230601.txt Instrument calibration file used: Pandora107s1_CF_v7d20230718.txt Level 1 file used: Pandora107s1_LynnMA_20240928_L1_smca1c7d20230718p1-8.txt Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20240928 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 6 First and last pixel inside fitting window: 220 362 Nominal wavelengths inside fitting window [nm]: 305.0382 305.1791 305.3200 305.4608 305.6017 305.7426 305.8834 306.0242 306.1650 306.3059 306.4467 306.5874 306.7282 306.8690 307.0097 307.1505 307.2912 307.4319 307.5727 307.7134 307.8540 307.9947 308.1354 308.2761 308.4167 308.5573 308.6980 308.8386 308.9792 309.1198 309.2604 309.4009 309.5415 309.6820 309.8226 309.9631 310.1036 310.2441 310.3846 310.5251 310.6656 310.8060 310.9465 311.0869 311.2273 311.3678 311.5082 311.6485 311.7889 311.9293 312.0697 312.2100 312.3504 312.4907 312.6310 312.7713 312.9116 313.0519 313.1922 313.3324 313.4727 313.6129 313.7531 313.8934 314.0336 314.1738 314.3139 314.4541 314.5943 314.7344 314.8746 315.0147 315.1548 315.2949 315.4350 315.5751 315.7152 315.8552 315.9953 316.1353 316.2754 316.4154 316.5554 316.6954 316.8354 316.9753 317.1153 317.2552 317.3952 317.5351 317.6750 317.8149 317.9548 318.0947 318.2346 318.3744 318.5143 318.6541 318.7939 318.9338 319.0736 319.2134 319.3531 319.4929 319.6327 319.7724 319.9121 320.0519 320.1916 320.3313 320.4710 320.6107 320.7503 320.8900 321.0296 321.1693 321.3089 321.4485 321.5881 321.7277 321.8673 322.0068 322.1464 322.2859 322.4255 322.5650 322.7045 322.8440 322.9835 323.1230 323.2624 323.4019 323.5413 323.6808 323.8202 323.9596 324.0990 324.2384 324.3777 324.5171 324.6564 324.7958 324.9351 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240928T123208.9Z 9037.522325 248 1 9.19 2 70.45 112.57 28.80 141.35 0.00 1 0.00 1 0 25 4.468e-02 1.183e-02 2.861e-02 5.163e-03 3.672426e-01 2.688356e-03 4.484563e-03 -6.000000e+00 2.654084e-02 227.56 -2.00 3.54 -2.00 318.14 0.00e+00 2.039119e-03 5.013342e-04 4.485387e-04 -6.000000e+00 1.196911e-03 284.84 -2.00 20.00 -2.00 317.37 0.00e+00 2.954 0.000 302.00 328.00 3 3.9963e+00 7.2170e-03 3.5071e-02 -6.0000e+00 6.5832e-02 6.3253e-02 8.1820e-03 1.9273e-02 -6.0000e+00 7.1300e-02 -2.8241e-02 5.2645e-03 9.5529e-03 -6.0000e+00 4.2557e-02 4.2666e-03 2.7045e-03 2.8851e-03 -6.0000e+00 1.7961e-02 3.2518e-04 -1.8177e-03 1.5583e-04 3.3240e-05 -6.0000e+00 1.3163e-03 -1.1396e-02 0.0000e+00 12 9 9 12 1 1 -618105.44 21.80 0.19 -0.01140 -0.02505 3 4 1 5 0 2295.080 26.00 20.00 21.80 23.07 0.0 932.83 -6948 -1744 -20869 4132 -7447 -14823 5128 -12417 -4517 -19284 21718 -4652 16436 -4994 -2273 3810 -2897 -399 -283 -2460 -130 1613 1135 5128 4496 -91 -6580 -7523 -4521 -2199 1867 9399 -2126 -3161 -1614 -3362 387 -6517 -966 1211 -2037 -1077 -1684 -789 -591 -1209 377 -654 622 1042 2873 2676 3031 1745 417 2799 850 624 -588 3062 3853 2369 2949 -147 -575 -378 1323 2077 4837 119 -832 -1217 -1253 -2311 -588 -111 244 750 1362 -62 -775 -1612 -2360 -1849 -1345 -663 -136 -1315 174 -305 -40 465 895 2092 2064 257 591 -512 -1378 -2363 -1704 -317 1023 1426 -716 -2218 -729 -1008 538 916 -210 -506 117 391 1182 2081 1868 1176 849 -194 -611 -291 518 -540 293 216 746 1839 774 -497 -513 -627 560 -90 348 -857 35 299 -197 -664 -700 -56 250 -363 -99 -1503 232 -441 -886 257 -815 -308 -1604 1266 -364 1174 -513 -266 477 -417 -60 -44 -412 -22 271 194 873 824 -18 -1390 -1566 -899 -424 363 1894 -522 -813 -408 -849 98 -1974 -327 456 -863 -481 -782 -369 -279 -578 178 -310 292 496 1402 1390 1668 1011 252 1702 535 394 -371 1873 2376 1550 2050 -110 -444 -287 951 1448 3448 95 -713 -1085 -1125 -2052 -494 -88 180 531 986 -49 -673 -1515 -2353 -1915 -1445 -739 -158 -1569 206 -356 -45 499 906 2061 2101 282 696 -648 -1835 -3215 -2246 -392 1207 1683 -887 -2889 -971 -1384 759 1349 -323 -798 183 592 1710 2895 2574 1657 1243 -296 -951 -449 782 -804 425 305 1020 2491 1093 -745 -802 -1005 906 -150 597 -1525 63 546 -361 -1217 -1257 -97 426 SS 20240928T123255.4Z 9037.522864 250 1 3.28 2 70.31 112.72 28.71 141.68 0.00 1 0.00 1 0 25 2.634e-02 1.014e-02 1.251e-02 2.750e-03 3.671297e-01 1.434491e-03 4.411774e-03 -6.000000e+00 1.567591e-02 227.56 -2.00 3.54 -2.00 317.85 0.00e+00 8.844614e-04 2.475132e-04 2.616695e-04 -6.000000e+00 7.062810e-04 284.84 -2.00 20.00 -2.00 317.09 0.00e+00 2.935 0.000 302.00 328.00 3 2.0391e+00 3.8279e-03 3.4829e-02 -6.0000e+00 3.8883e-02 4.1422e-02 4.3248e-03 1.9086e-02 -6.0000e+00 4.2085e-02 -3.1609e-02 2.6971e-03 9.3659e-03 -6.0000e+00 2.5120e-02 6.8128e-03 1.3645e-03 2.6878e-03 -6.0000e+00 1.0625e-02 2.3852e-03 -1.0376e-04 8.2456e-05 3.1290e-05 -6.0000e+00 7.7549e-04 -2.4660e-02 0.0000e+00 12 9 9 12 1 1 -156.95 21.81 0.30 -0.02466 -0.02544 10 32 1 5 0 297.350 26.00 20.00 21.81 23.09 0.0 932.96 -3595 -6880 -11786 -7916 -2399 -7771 2564 -10850 -1181 -10678 -8534 -4870 -8564 -1572 -2023 309 -2173 591 515 -23 1315 153 2963 1749 -136 -1205 -2996 -1958 97 2651 -279 887 -123 -4086 -1065 -466 1082 953 452 -293 -2045 -1252 -2073 261 -478 -118 273 580 1576 1677 2199 2083 1262 1608 852 1447 -429 1220 497 1926 2261 1462 1778 -255 -974 -956 444 1480 2999 1069 -789 -691 -1285 -1255 -929 -591 664 1024 1885 -94 -1491 -1723 -2320 -1559 -777 -602 -464 -921 42 -720 38 766 1275 2003 1361 826 307 251 -1362 -1988 -1868 -299 1336 1283 -866 -1743 -867 -679 284 618 -135 -425 -118 328 760 2157 2046 1255 985 -383 -754 -546 420 -42 112 -73 650 2111 886 -642 -711 -513 140 122 223 -404 15 -46 -417 -574 -575 146 311 -228 -515 -888 -618 -167 -536 162 -876 -98 -945 -762 -485 -894 -181 -276 47 -366 103 94 -4 259 31 587 366 -29 -271 -686 -431 22 581 -66 211 -33 -1193 -300 -128 303 310 165 -126 -927 -607 -1057 132 -247 -61 140 295 792 857 1175 1122 743 1000 556 912 -282 793 322 1214 1445 1003 1329 -198 -787 -755 324 1097 2186 888 -696 -609 -1150 -1153 -798 -489 493 764 1444 -77 -1335 -1637 -2285 -1624 -851 -669 -549 -1085 49 -826 43 834 1271 2024 1379 931 371 321 -1828 -2638 -2465 -370 1597 1543 -1074 -2229 -1158 -908 398 895 -203 -662 -182 497 1112 2930 2849 1739 1452 -582 -1139 -850 628 -60 163 -101 890 2832 1222 -944 -1123 -806 226 197 382 -706 27 -81 -747 -1018 -1018 254 524 SS 20240928T123356.9Z 9037.523575 252 1 50.43 2 70.14 112.92 28.60 142.12 0.00 1 0.00 1 0 25 2.126e-02 9.786e-03 4.575e-03 7.998e-04 3.665137e-01 4.155127e-04 4.391135e-03 -6.000000e+00 1.265237e-02 227.56 -2.00 3.54 -2.00 318.24 0.00e+00 1.137158e-03 7.968799e-05 2.816708e-04 -6.000000e+00 5.700751e-04 284.84 -2.00 20.00 -2.00 317.47 0.00e+00 2.911 0.000 302.00 328.00 3 2.2699e+00 1.1187e-03 3.4634e-02 -6.0000e+00 3.1383e-02 4.5423e-02 1.2716e-03 1.9107e-02 -6.0000e+00 3.3968e-02 -2.3579e-02 8.3067e-04 9.4343e-03 -6.0000e+00 2.0275e-02 1.4855e-03 4.2804e-04 2.8033e-03 -6.0000e+00 8.5756e-03 1.9280e-03 1.8025e-05 2.4222e-05 3.1333e-05 -6.0000e+00 6.2597e-04 -2.4313e-02 0.0000e+00 12 9 8 11 8 0 99.97 21.82 0.32 -0.02431 -0.02418 319 60 1 5 0 158.050 26.00 20.01 21.82 23.15 0.0 933.13 -7633 -2262 -8286 -6676 -7328 -3175 -4125 -3596 -4464 -8977 -4429 -2130 -404 -2566 -1078 -79 -1355 895 2011 1149 688 948 3607 864 -44 -3098 -3136 -2411 -599 1167 1535 1273 -181 -3200 -3182 320 971 -477 356 -1961 -2289 -1347 -1193 -923 -319 42 1 530 503 1513 2209 1156 1545 914 1058 1424 235 86 243 1555 2304 2563 1376 157 -1385 -678 1174 2005 3113 708 -494 -1077 -1271 -917 -1489 -348 506 1126 1697 -112 -912 -1518 -2075 -1045 -508 -472 -400 -483 -337 -507 151 1116 1417 2298 2044 875 578 -13 -1365 -1876 -1370 -384 1291 1257 -1075 -1958 -1022 -583 547 353 110 -569 -227 135 962 1954 1956 1356 745 -648 -837 -650 103 -131 85 -45 858 2072 756 -363 -865 -646 187 307 110 -440 -45 39 -447 -576 -227 -70 628 -392 -126 -470 -401 -419 -163 -217 -211 -298 -670 -325 -161 -33 -233 -114 -9 -178 122 286 173 107 150 559 143 -8 -610 -616 -457 -108 204 280 260 -42 -798 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