File name: Pandora107s1_LynnMA_20241001_L2Fit_fout2c7d20230718p1-8.txt File generation date: 20241002T043543.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Gonzalo Gonzalez Abad Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 107 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora107_OF_v3d20230601.txt Instrument calibration file used: Pandora107s1_CF_v7d20230718.txt Level 1 file used: Pandora107s1_LynnMA_20241001_L1_smca1c7d20230718p1-8.txt Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20241001 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 6 First and last pixel inside fitting window: 220 362 Nominal wavelengths inside fitting window [nm]: 305.0382 305.1791 305.3200 305.4608 305.6017 305.7426 305.8834 306.0242 306.1650 306.3059 306.4467 306.5874 306.7282 306.8690 307.0097 307.1505 307.2912 307.4319 307.5727 307.7134 307.8540 307.9947 308.1354 308.2761 308.4167 308.5573 308.6980 308.8386 308.9792 309.1198 309.2604 309.4009 309.5415 309.6820 309.8226 309.9631 310.1036 310.2441 310.3846 310.5251 310.6656 310.8060 310.9465 311.0869 311.2273 311.3678 311.5082 311.6485 311.7889 311.9293 312.0697 312.2100 312.3504 312.4907 312.6310 312.7713 312.9116 313.0519 313.1922 313.3324 313.4727 313.6129 313.7531 313.8934 314.0336 314.1738 314.3139 314.4541 314.5943 314.7344 314.8746 315.0147 315.1548 315.2949 315.4350 315.5751 315.7152 315.8552 315.9953 316.1353 316.2754 316.4154 316.5554 316.6954 316.8354 316.9753 317.1153 317.2552 317.3952 317.5351 317.6750 317.8149 317.9548 318.0947 318.2346 318.3744 318.5143 318.6541 318.7939 318.9338 319.0736 319.2134 319.3531 319.4929 319.6327 319.7724 319.9121 320.0519 320.1916 320.3313 320.4710 320.6107 320.7503 320.8900 321.0296 321.1693 321.3089 321.4485 321.5881 321.7277 321.8673 322.0068 322.1464 322.2859 322.4255 322.5650 322.7045 322.8440 322.9835 323.1230 323.2624 323.4019 323.5413 323.6808 323.8202 323.9596 324.0990 324.2384 324.3777 324.5171 324.6564 324.7958 324.9351 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241001T113140.4Z 9040.480329 88 1 50.99 2 81.72 102.51 69.02 106.70 0.00 1 0.00 1 0 25 8.539e-01 7.089e-02 1.832e-01 1.045e-02 7.818096e-01 5.740419e-03 9.971605e-03 -6.000000e+00 5.074457e-01 227.22 -2.00 3.54 -2.00 321.46 0.00e+00 1.552582e-02 2.273814e-03 4.636137e-03 -6.000000e+00 2.286230e-02 284.47 -2.00 20.00 -2.00 320.91 0.00e+00 6.513 0.005 302.00 328.00 3 2.7409e+00 1.8593e-02 7.7131e-02 -6.0000e+00 1.2578e+00 3.4596e-01 2.1987e-02 4.0746e-02 -6.0000e+00 1.3619e+00 -4.9814e-01 1.3205e-02 2.2495e-02 -6.0000e+00 8.1297e-01 2.2366e-01 6.9762e-03 1.0886e-02 -6.0000e+00 3.4388e-01 2.4036e-05 -1.2894e-03 2.8546e-04 2.3383e-04 -6.0000e+00 2.5145e-02 -2.2710e-02 0.0000e+00 12 9 8 11 40 0 89.02 21.62 -0.06 -0.02271 -0.03240 16 3 1 5 0 3186.130 25.79 20.00 21.62 21.20 0.0 924.54 -63070 -31293 -78560 -361652 -91356 -49430 -91373 -27504 -61679 -62246 -355907 -55863 -315549 -144629 87963 62368 85416 83729 -213615 110234 -171904 107310 114100 -191009 35296 -79128 106143 101064 112773 104386 140023 192272 -55865 180709 182207 180077 178022 -119565 66062 45496 -63741 234368 99652 38884 130820 34155 -4910 84196 44792 66443 86554 16422 43439 -7660 107204 27709 8855 16699 -29756 37167 38240 17704 17101 4810 7740 1835 6219 18783 55062 -397 4165 -11466 -539 -9221 16544 2628 12062 10507 -105 -7620 -21759 293 -14935 1120 -57 -1085 -444 -1869 -10955 -8021 -2050 -10149 511 -9874 -2525 -1021 -1728 169 -6119 -4125 -929 -333 1860 1145 212 295 -591 -2537 1130 2191 -3524 -1815 1140 1161 425 4834 2360 3567 1095 1229 617 636 2941 1753 -2925 2100 2625 5055 3239 763 -1645 1545 -2 0 -1296 -1013 294 -807 -250 -1814 -251 -512 771 -3975 -1798 -8082 -24086 -10245 -3344 -9061 -1504 -5031 -5250 -22659 -5229 -19630 -2579 5112 5913 7663 8707 -16673 10227 -9883 10393 10120 -12933 360 -2039 10821 10922 11382 12664 14275 14701 -2349 20634 20805 20562 21235 -11470 1372 1297 -5522 2389 2250 1587 2445 1572 -340 2719 2206 2889 3439 1395 3183 -978 4935 2774 1077 1882 -5101 3352 3509 2159 2391 859 1479 385 1248 3416 7785 -107 1189 -3997 -169 -3013 3915 647 2544 2265 -28 -2571 -9926 125 -8135 566 -31 -626 -268 -1189 -7610 -5301 -1231 -6238 275 -5971 -1587 -734 -1456 160 -6716 -4647 -989 -321 1613 974 189 279 -594 -2750 1298 2786 -5222 -2837 1798 1810 647 6904 3434 5304 1744 2021 1021 1018 4454 2606 -4431 2963 3598 6958 4965 1347 -3269 3181 -3 0 -3191 -2592 764 -2130 -657 -4723 -620 -1188 1709 SS 20241001T113514.2Z 9040.482804 92 1 51.10 2 81.08 103.13 68.41 107.37 0.00 1 0.00 1 0 25 4.235e-01 3.530e-02 2.436e-01 9.107e-03 7.478324e-01 5.093023e-03 9.384008e-03 -6.000000e+00 2.516635e-01 227.22 -2.00 3.54 -2.00 321.39 0.00e+00 1.367049e-02 2.495423e-03 4.763579e-03 -6.000000e+00 1.194405e-02 284.47 -2.00 20.00 -2.00 320.83 0.00e+00 6.100 0.004 302.00 328.00 3 2.8417e+00 1.7577e-02 7.4042e-02 -6.0000e+00 6.2418e-01 7.4911e-01 2.2360e-02 4.2871e-02 -6.0000e+00 6.7617e-01 -8.8902e-01 1.9250e-02 2.5814e-02 -6.0000e+00 4.0332e-01 3.4217e-01 9.3543e-03 1.1778e-02 -6.0000e+00 1.7177e-01 2.9451e-05 -1.9010e-03 2.5593e-04 2.2174e-04 -6.0000e+00 1.2534e-02 -2.2509e-02 0.0000e+00 12 9 8 11 32 0 98.81 21.63 0.09 -0.02251 -0.03679 17 3 1 5 0 3005.290 25.79 20.00 21.63 21.24 0.0 924.67 -72285 900000 -23810 39033 -87275 -34629 -86157 -63419 -6010 -72403 900000 -94666 -94522 35347 -1706 -7263 172027 77126 21780 -17302 -16671 -71489 188291 82538 1151 22105 -48571 100854 41834 17960 20500 -71773 -43710 -12073 75117 11627 100581 -86759 35689 54204 33030 150891 13687 30823 27964 39639 33728 8237 46717 12369 65982 39479 54381 21304 43193 31331 8851 11505 -7911 23029 30230 5435 21493 6378 21183 10858 14657 -17890 28591 4880 11386 -2353 6585 -3937 -12120 -812 13331 4861 -1988 -5835 -173 1822 -3678 952 -1469 187 -1335 -3810 -135 -1689 -11150 75675 -703 5224 -4079 -2766 -3197 -2510 1049 -1949 396 -1897 -83 -699 -2589 -4706 -1699 -2348 -2399 1511 3364 -3396 -434 863 839 1551 1506 1266 1177 -884 815 1343 1884 228 556 -2117 482 3891 1404 39 1006 135 689 -392 -186 -399 -251 -359 -231 -1039 -253 -523 875 -1596 900000 -422 373 -2511 -543 -2051 -1236 -70 -1577 900000 -2766 -3306 471 -41 -220 1527 1317 660 -780 -741 -5173 1672 1328 40 637 -2641 1321 969 550 701 -7075 -3868 -844 2302 621 2333 -13052 1966 2848 2325 3755 1298 2557 2422 3146 2901 932 3830 1486 5154 4346 5689 3251 5570 4635 1631 2046 -1636 3481 4320 1058 4023 1544 4839 2798 3594 -5964 6670 1589 3842 -941 2422 -1519 -4635 -254 3386 1331 -634 -2251 -74 878 -2055 545 -907 119 -906 -2738 -94 -1162 -7995 23085 -416 2964 -2770 -2131 -2851 -2523 1121 -2230 431 -1926 -76 -627 -2443 -4787 -1773 -2608 -2891 1955 4741 -5391 -694 1347 1271 2266 2195 1902 1856 -1468 1341 2137 2872 344 820 -3090 672 5367 2162 67 1911 274 1460 -882 -440 -985 -635 -915 -587 -2621 -607 -1186 1896 SS 20241001T133015.6Z 9040.562681 174 1 2.81 2 61.84 125.77 50.79 133.16 0.00 1 0.00 1 0 25 1.521e-02 1.034e-02 3.276e-03 1.417e-03 2.792547e-01 7.420458e-04 3.423749e-03 -6.000000e+00 9.042115e-03 227.21 -2.00 3.54 -2.00 316.50 0.00e+00 4.369594e-04 9.045139e-05 6.941045e-05 -6.000000e+00 4.071822e-04 284.46 -2.00 20.00 -2.00 315.78 0.00e+00 2.108 0.000 302.00 328.00 3 1.5800e+00 1.9309e-03 2.5476e-02 -6.0000e+00 2.2413e-02 2.5105e-02 2.1577e-03 1.4480e-02 -6.0000e+00 2.4263e-02 -1.4980e-02 1.2532e-03 7.1148e-03 -6.0000e+00 1.4484e-02 1.9670e-03 5.8834e-04 2.0163e-03 -6.0000e+00 6.1307e-03 9.5245e-03 6.7597e-05 4.2779e-05 2.5527e-05 -6.0000e+00 4.4762e-04 -2.7122e-02 0.0000e+00 12 9 9 12 1 1 99.95 21.99 0.34 -0.02712 -0.02661 27 95 1 5 0 100.140 26.11 20.01 21.99 24.84 0.0 940.88 -1295 -4017 -4381 -5971 -3584 -1537 109 118 -2390 -4176 -3562 845 2690 671 -321 -944 1041 925 900 988 599 1435 2814 1668 1113 -226 -1853 -800 801 2109 2054 1277 -198 -3476 -2704 -108 1011 1020 -73 -1335 -2193 -1142 -944 -715 -107 -74 -436 -589 537 1533 2181 1287 1208 430 693 1037 662 204 657 1314 2363 2060 1101 35 -1703 -916 973 1720 2747 336 -987 -1229 -1094 -1061 -1127 -170 166 1281 1831 151 -1238 -1892 -2174 -1158 -436 -618 -617 -775 -675 -512 -215 565 1559 2281 2128 784 664 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