File name: Pandora107s1_LynnMA_20241005_L2Fit_fout2c8d20240424p1-8.txt File generation date: 20241009T193719.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Gonzalo Gonzalez Abad Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 107 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora107_OF_v3d20230601.txt Instrument calibration file used: Pandora107s1_CF_v8d20240424.txt Level 1 file used: Pandora107s1_LynnMA_20241005_L1_smca1c8d20240424p1-8.txt Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20241005 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld based on session 7 "OOB session based on clearance session 6, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used" First and last pixel inside fitting window: 221 362 Nominal wavelengths inside fitting window [nm]: 305.1394 305.2803 305.4212 305.5621 305.7030 305.8438 305.9847 306.1255 306.2663 306.4071 306.5479 306.6887 306.8295 306.9702 307.1110 307.2517 307.3925 307.5332 307.6739 307.8146 307.9553 308.0959 308.2366 308.3773 308.5179 308.6585 308.7991 308.9397 309.0803 309.2209 309.3615 309.5021 309.6426 309.7832 309.9237 310.0642 310.2047 310.3452 310.4857 310.6262 310.7666 310.9071 311.0475 311.1880 311.3284 311.4688 311.6092 311.7496 311.8899 312.0303 312.1706 312.3110 312.4513 312.5916 312.7319 312.8722 313.0125 313.1528 313.2930 313.4333 313.5735 313.7137 313.8540 313.9942 314.1344 314.2745 314.4147 314.5549 314.6950 314.8352 314.9753 315.1154 315.2555 315.3956 315.5357 315.6757 315.8158 315.9558 316.0959 316.2359 316.3759 316.5159 316.6559 316.7959 316.9358 317.0758 317.2157 317.3557 317.4956 317.6355 317.7754 317.9153 318.0552 318.1950 318.3349 318.4747 318.6145 318.7544 318.8942 319.0340 319.1738 319.3135 319.4533 319.5930 319.7328 319.8725 320.0122 320.1519 320.2916 320.4313 320.5710 320.7106 320.8503 320.9899 321.1295 321.2691 321.4087 321.5483 321.6879 321.8275 321.9670 322.1066 322.2461 322.3856 322.5251 322.6646 322.8041 322.9436 323.0831 323.2225 323.3619 323.5014 323.6408 323.7802 323.9196 324.0590 324.1983 324.3377 324.4771 324.6164 324.7557 324.8950 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241005T114714.3Z 9044.491138 70 1 51.27 2 79.80 106.60 109.05 98.57 0.00 1 0.00 1 0 25 3.561e-01 3.325e-02 1.373e-01 1.161e-02 7.569591e-01 6.327646e-03 9.434641e-03 -6.000000e+00 2.067815e-01 226.75 -2.00 3.54 -2.00 321.19 0.00e+00 -2.935783e-03 2.417297e-03 7.075853e-03 -6.000000e+00 9.223142e-03 283.98 -2.00 20.00 -2.00 320.56 0.00e+00 5.410 0.003 302.00 328.00 3 3.5379e+00 2.0083e-02 7.8155e-02 -6.0000e+00 5.1212e-01 8.9625e-01 2.4310e-02 6.8961e-02 -6.0000e+00 5.5561e-01 -1.1768e+00 1.7005e-02 2.3268e-02 -6.0000e+00 3.3137e-01 4.7136e-01 8.5593e-03 8.9190e-03 -6.0000e+00 1.4183e-01 2.9084e-05 -2.4133e-03 3.1953e-04 7.7036e-05 -6.0000e+00 1.0029e-02 2.1612e-02 0.0000e+00 12 8 8 10 0 0 99.91 21.67 0.39 0.02161 0.00348 29 5 1 5 0 1767.720 25.79 20.00 21.67 21.46 0.0 926.19 22744 -14895 -20514 -63677 -40757 -82189 -9841 -79466 -66347 287954 -61179 -73068 -40383 -34146 55509 56822 -226 67955 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3245 -120 4974 2254 -1551 2979 6823 2792 1749 -678 3005 -1198 -6957 -205 3092 -1227 -3296 -5936 218 -900 -703 1346 -789 1085 3044 -2539 -536 -834 -1790 669 -3785 3735 -3823 -2243 -4811 -3866 3425 -3860 -5093 -5073 1040 -944 -4900 -6262 -5988 -2512 -2439 -957 8404 -5152 1588 660 1882 3284 1150 3549 2567 1183 2837 1439 1924 2149 5397 2738 1761 7082 985 -495 831 -410 1986 -2217 -1919 68 207 -94 -1863 -3678 -154 -2067 382 SS 20241005T115017.1Z 9044.493253 76 1 7.18 2 79.26 107.14 108.52 99.05 0.00 1 0.00 1 0 25 5.588e-01 2.130e-02 3.079e-01 1.195e-02 7.177734e-01 6.601327e-03 8.581212e-03 -6.000000e+00 3.273419e-01 226.75 -2.00 3.54 -2.00 321.12 0.00e+00 7.159856e-03 3.135839e-03 2.844550e-03 -6.000000e+00 1.558787e-02 283.98 -2.00 20.00 -2.00 320.56 0.00e+00 5.163 0.003 302.00 328.00 3 2.5777e+00 2.2080e-02 6.4671e-02 -6.0000e+00 8.1261e-01 2.2989e-01 2.9447e-02 4.0313e-02 -6.0000e+00 8.8346e-01 -3.8834e-01 2.8012e-02 2.2329e-02 -6.0000e+00 5.2333e-01 1.5761e-01 1.3451e-02 8.0228e-03 -6.0000e+00 2.2638e-01 1.1289e-04 -1.1963e-03 3.3287e-04 1.2338e-04 -6.0000e+00 1.6276e-02 1.8647e-02 0.0000e+00 12 9 9 12 1 1 76.05 21.68 0.38 0.01865 0.00966 4 7 1 5 0 1433.500 25.90 20.00 21.68 21.57 0.0 926.55 900000 -197921 900000 -118382 -197468 -226756 900000 71365 -62708 900000 -169057 -138535 -66002 38009 267763 -101899 -82797 -65894 42669 -53933 -32388 263134 -40575 24800 -71366 -36947 15024 -55837 19135 6777 900000 -30880 -36257 52168 -43782 35192 -48761 23308 18816 13764 30566 17679 -10396 5189 33444 26182 5213 8534 -2265 33237 14581 17853 16993 9708 18195 9217 13598 -6365 13806 16430 423 8299 12534 10960 7542 11567 6938 8485 9667 727 1817 -1870 -5652 -2768 -2023 3158 3152 -3289 -3087 476 -4406 -1222 -2086 -1180 2020 -1810 -521 -437 592 1144 296 -1471 -523 -1403 -1343 -2335 -2650 936 -1272 -2442 427 667 -2002 -1460 -4200 -1071 -1484 -480 769 1682 -1110 235 1625 382 2343 2257 330 448 -780 -676 -2068 2472 327 -1281 848 1936 4041 -386 984 578 397 690 346 210 -785 -655 -610 -1404 -149 -582 1177 -112 900000 -4835 900000 -1378 -4187 -6413 900000 831 -730 900000 -4062 -3061 -953 442 3116 -3825 -2882 -2120 506 -1676 -814 3063 -1162 405 -3080 -1162 282 -2084 369 171 900000 -1627 -2200 1354 -2778 1087 -3865 1125 1120 970 2008 1387 -1103 486 2452 2119 536 894 -281 3236 1894 2485 2580 1670 3017 1710 2426 -1335 2352 2769 90 1854 3027 2916 2102 3066 1947 2552 3246 293 762 -815 -2439 -1079 -714 988 983 -1190 -1301 227 -2481 -736 -1348 -799 1401 -1360 -401 -337 444 814 201 -976 -350 -1032 -1122 -2235 -2842 1061 -1512 -2833 448 646 -1943 -1469 -4555 -1183 -1728 -597 1039 2456 -1753 374 2534 581 3425 3281 500 709 -1283 -1114 -3361 3767 494 -1920 1218 2696 5642 -602 1677 1070 773 1392 731 466 -1813 -1546 -1454 -3360 -347 -1312 2504 -232 SS 20241005T132432.5Z 9044.558710 130 1 24.02 2 63.74 125.80 92.64 114.00 0.00 1 0.00 1 0 25 2.232e-02 8.681e-03 9.673e-03 2.133e-03 3.464111e-01 1.098316e-03 4.214504e-03 -6.000000e+00 1.296844e-02 226.74 -2.00 3.54 -2.00 317.86 0.00e+00 7.963728e-04 1.866997e-04 2.629715e-04 -6.000000e+00 5.780558e-04 283.97 -2.00 20.00 -2.00 317.11 0.00e+00 2.247 0.000 302.00 328.00 3 4.0167e+00 2.9242e-03 2.8750e-02 -6.0000e+00 3.2118e-02 2.6282e-02 3.3060e-03 1.7971e-02 -6.0000e+00 3.4836e-02 -1.5171e-02 2.0921e-03 8.9014e-03 -6.0000e+00 2.0776e-02 1.1784e-03 1.0729e-03 2.5542e-03 -6.0000e+00 8.9000e-03 6.5345e-04 -2.4851e-04 6.2709e-05 2.9115e-05 -6.0000e+00 6.2833e-04 1.5949e-02 0.0000e+00 12 9 1 12 1 1 99.96 21.86 0.34 0.01595 0.01408 29 12 1 5 0 800.210 26.00 20.00 21.86 22.38 0.0 930.43 -1333 -2652 -2628 -12891 -8882 -8170 444 -6675 -7694 -1670 -5509 4983 -4184 239 842 -265 1362 618 437 246 264 1532 1763 -1660 -2888 -915 -1098 556 704 1297 3653 355 -2827 -3429 -2284 -169 -2423 -599 -1151 -758 -582 -996 -757 409 160 -355 -274 276 1228 1985 1583 1122 707 1996 1482 532 36 -384 1058 2358 1632 1661 394 -743 -657 523 1278 3027 613 -583 -951 -1170 -576 -436 -869 -198 48 997 -826 -963 -1693 -1737 -1359 -425 -376 -253 -605 228 143 69 420 848 2094 1172 354 455 97 -450 -1549 -1225 -509 756 756 -1323 -1712 -1104 -510 696 453 278 -212 -44 447 767 1569 1748 1121 518 -381 -703 -727 259 51 -48 8 599 1834 1070 -259 -756 -671 194 123 -183 -484 -75 210 -243 -666 -331 5 614 -91 -194 -187 -933 -574 -534 30 -549 -685 -143 -504 457 -496 32 127 -44 233 112 83 48 52 300 361 -379 -645 -220 -255 121 149 287 879 90 -778 -928 -589 -44 -754 -222 -466 -342 -281 -502 -387 208 82 -181 -138 137 612 1031 892 636 426 1237 953 354 24 -254 680 1519 1129 1174 305 -601 -512 374 936 2295 499 -499 -864 -1075 -510 -385 -701 -154 35 742 -653 -869 -1612 -1793 -1393 -458 -432 -292 -728 273 167 81 448 878 2061 1218 385 523 125 -594 -2107 -1578 -626 907 911 -1635 -2269 -1448 -695 991 661 433 -328 -66 671 1121 2131 2323 1546 765 -572 -1089 -1118 383 73 -69 11 820 2458 1451 -388 -1157 -1062 313 196 -311 -828 -133 376 -440 -1194 -568 9 1013 SS 20241005T143040.5Z 9044.604635 179 1 32.78 2 54.96 142.05 82.51 125.35 0.00 1 0.00 1 0 25 1.181e-02 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