File name: Pandora107s1_LynnMA_20241006_L2Fit_fout2c7d20230718p1-8.txt File generation date: 20241007T044112.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Gonzalo Gonzalez Abad Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 107 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora107_OF_v3d20230601.txt Instrument calibration file used: Pandora107s1_CF_v7d20230718.txt Level 1 file used: Pandora107s1_LynnMA_20241006_L1_smca1c7d20230718p1-8.txt Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20241006 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 6 First and last pixel inside fitting window: 220 362 Nominal wavelengths inside fitting window [nm]: 305.0382 305.1791 305.3200 305.4608 305.6017 305.7426 305.8834 306.0242 306.1650 306.3059 306.4467 306.5874 306.7282 306.8690 307.0097 307.1505 307.2912 307.4319 307.5727 307.7134 307.8540 307.9947 308.1354 308.2761 308.4167 308.5573 308.6980 308.8386 308.9792 309.1198 309.2604 309.4009 309.5415 309.6820 309.8226 309.9631 310.1036 310.2441 310.3846 310.5251 310.6656 310.8060 310.9465 311.0869 311.2273 311.3678 311.5082 311.6485 311.7889 311.9293 312.0697 312.2100 312.3504 312.4907 312.6310 312.7713 312.9116 313.0519 313.1922 313.3324 313.4727 313.6129 313.7531 313.8934 314.0336 314.1738 314.3139 314.4541 314.5943 314.7344 314.8746 315.0147 315.1548 315.2949 315.4350 315.5751 315.7152 315.8552 315.9953 316.1353 316.2754 316.4154 316.5554 316.6954 316.8354 316.9753 317.1153 317.2552 317.3952 317.5351 317.6750 317.8149 317.9548 318.0947 318.2346 318.3744 318.5143 318.6541 318.7939 318.9338 319.0736 319.2134 319.3531 319.4929 319.6327 319.7724 319.9121 320.0519 320.1916 320.3313 320.4710 320.6107 320.7503 320.8900 321.0296 321.1693 321.3089 321.4485 321.5881 321.7277 321.8673 322.0068 322.1464 322.2859 322.4255 322.5650 322.7045 322.8440 322.9835 323.1230 323.2624 323.4019 323.5413 323.6808 323.8202 323.9596 324.0990 324.2384 324.3777 324.5171 324.6564 324.7958 324.9351 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241006T113114.7Z 9045.480032 54 1 50.28 2 82.86 104.10 122.46 92.57 0.00 1 0.00 1 0 33 3.309e-01 2.912e-02 1.630e-01 8.475e-03 9.936561e-01 4.845963e-03 1.102941e-02 -6.000000e+00 1.961769e-01 226.64 -2.00 3.54 -2.00 322.14 0.00e+00 1.783218e-06 2.640974e-03 1.141669e-03 -6.000000e+00 9.244459e-03 283.86 -2.00 20.00 -2.00 321.66 0.00e+00 7.396 0.008 302.00 328.00 3 1.0939e+00 1.8354e-02 9.0916e-02 -6.0000e+00 4.8603e-01 1.3580e+00 2.3634e-02 5.4232e-02 -6.0000e+00 5.2676e-01 -1.8168e+00 1.8386e-02 2.8173e-02 -6.0000e+00 3.1414e-01 7.1764e-01 8.8169e-03 8.5089e-03 -6.0000e+00 1.3321e-01 3.9209e-05 -1.6256e-03 2.1774e-04 1.2167e-04 -6.0000e+00 9.7787e-03 -2.1281e-02 0.0000e+00 12 8 8 10 0 0 88.79 21.17 0.69 -0.02128 -0.03350 49 9 1 5 0 1025.910 25.39 19.99 21.17 16.84 0.0 907.46 -44463 75875 -32127 47547 -56765 -26317 -55970 -2362 -18045 -87673 900000 -77523 6099 -37884 48284 32972 14733 54456 54953 26284 7549 -23025 1445 29352 -11556 -99317 5191 -2698 -14154 -64696 -5450 101916 -22532 26669 19561 -4343 11507 -66992 19317 21597 78272 83785 35393 52766 59935 58973 21590 -4148 24433 5236 62045 17102 85339 43264 92648 52755 33608 28141 -5759 33353 42105 13893 27652 10704 17057 10814 24312 28606 36672 14240 14802 4016 11636 3500 77332 8599 1661 -4747 -4736 -7298 5874 2529 -1643 1665 2478 2138 4671 -3302 1689 65 -4975 65747 -2235 744 -1319 -4438 -3412 -4980 -1189 -5409 -2606 -2437 -625 -949 -5369 -4868 -4504 -3630 -1501 -1426 2083 -3665 -756 13 1440 1994 493 1359 333 -788 -409 1969 2889 2303 -1826 2377 2041 4011 988 -828 556 100 942 470 -86 -354 211 700 -91 -907 -1042 -620 -551 -1837 1026 -1255 750 -2175 -633 -1682 -43 -393 -3820 900000 -3261 128 -1508 979 892 520 1350 1362 849 278 -1072 50 849 -477 -9923 189 -98 -550 -3840 -221 1684 -1490 1124 857 -226 504 -6492 1022 1285 2911 3116 2164 2660 2724 2632 1392 -353 1635 454 3333 1597 4443 3682 5053 4447 3472 3000 -814 2977 3340 1538 2993 1557 2551 1787 3516 4090 5364 2954 3352 1055 2789 847 7988 1563 299 -926 -1041 -1972 1675 872 -604 643 1003 909 2028 -1598 772 29 -2216 15104 -993 339 -638 -2647 -2402 -4149 -1072 -5372 -2428 -2027 -456 -664 -4065 -3913 -3837 -3297 -1501 -1661 2710 -5154 -1095 19 2023 2719 684 1937 505 -1248 -636 2841 4258 3310 -2688 3255 2743 5529 1475 -1491 1135 226 2105 1145 -226 -990 603 2002 -260 -2520 -2698 -1452 -1315 SS 20241006T113329.8Z 9045.481595 56 1 51.08 2 82.45 104.50 122.06 92.94 0.00 1 0.00 1 0 25 5.983e-01 3.466e-02 2.532e-01 1.311e-02 9.352774e-01 7.381682e-03 1.058911e-02 -6.000000e+00 3.547153e-01 226.64 -2.00 3.54 -2.00 321.94 0.00e+00 -7.283799e-03 3.538405e-03 5.370435e-03 -6.000000e+00 1.671453e-02 283.86 -2.00 20.00 -2.00 321.41 0.00e+00 7.060 0.007 302.00 328.00 3 2.0713e+00 2.6337e-02 9.3918e-02 -6.0000e+00 8.7881e-01 1.3723e+00 3.2327e-02 7.4022e-02 -6.0000e+00 9.5244e-01 -1.8806e+00 2.1781e-02 2.6968e-02 -6.0000e+00 5.6800e-01 7.5421e-01 1.0941e-02 1.1936e-02 -6.0000e+00 2.4086e-01 2.1867e-05 -1.7244e-03 3.4454e-04 1.1877e-04 -6.0000e+00 1.7680e-02 -2.1576e-02 0.0000e+00 12 8 8 10 0 0 99.24 21.17 0.52 -0.02158 -0.03453 36 7 1 5 0 1418.610 25.39 19.99 21.17 16.93 0.0 907.89 38988 155770 14030 291649 -37394 -12440 -66824 41263 233840 -23594 900000 -19925 -86471 -4041 50242 159542 70205 63898 22764 69805 34041 -5417 187641 -18177 -18610 8301 12548 40309 -16510 -9026 20595 139864 8139 4789 57488 -22637 83313 -82617 82001 50683 60597 308929 29252 122887 42309 85194 46123 29061 27642 14340 69181 56102 76084 44539 59880 84118 42872 66190 2213 37607 25085 -5321 28441 -9441 47543 15728 34358 32145 48851 5779 7277 -1399 5742 1456 29549 -7684 11357 -1833 -7557 -1813 10569 716 -3630 6467 -3159 4117 2729 -419 -4697 -3107 -4701 1183 2962 7226 -5953 -6167 -1946 -4611 -193 -5382 -1098 -4000 -4564 -2668 -2284 -5008 -1416 -6377 -3127 -2698 4326 -3322 -30 1694 327 3264 77 -86 2318 18 1348 1630 4795 604 -3998 3679 1787 5523 1557 -521 -205 -44 185 322 163 -550 106 525 -13 -1778 -1282 -518 900 1785 2322 822 3727 -2708 -596 -5195 1143 2988 -1332 900000 -1125 -10406 -245 2033 2595 2692 2654 1406 2602 1704 -375 2398 -1394 -1526 530 722 1733 -1055 -519 1029 2437 546 342 2538 -1905 2613 -13902 3430 3356 4013 3948 2555 4426 3244 4058 3162 2363 2344 1466 4421 4497 5480 4709 5705 6548 5130 6152 337 4063 2944 -878 3701 -1840 6186 2887 5189 5079 7208 1360 1852 -405 1529 378 5664 -1893 2124 -392 -1896 -508 2859 248 -1477 2583 -1470 1868 1317 -215 -2491 -1558 -2273 512 1227 3001 -3195 -3921 -1401 -3943 -177 -5462 -1030 -3468 -3572 -1975 -1749 -4208 -1220 -6186 -3280 -3258 5598 -4741 -43 2444 468 4772 107 -124 3441 28 2072 2385 6981 889 -6050 4995 2412 7458 2483 -920 -412 -96 437 821 414 -1491 294 1458 -35 -4843 -3240 -1275 2060 SS 20241006T113752.2Z 9045.484632 66 1 16.74 2 81.67 105.26 121.30 93.63 0.00 1 0.00 1 0 25 4.913e-01 2.837e-02 2.928e-01 1.429e-02 8.907947e-01 8.172366e-03 1.107436e-02 -6.000000e+00 2.927898e-01 226.64 -2.00 3.54 -2.00 321.72 0.00e+00 7.776661e-03 4.233340e-03 8.511669e-03 -6.000000e+00 1.433464e-02 283.85 -2.00 20.00 -2.00 321.20 0.00e+00 6.486 0.005 302.00 328.00 3 2.0530e+00 2.9437e-02 8.9591e-02 -6.0000e+00 7.2706e-01 1.0553e+00 3.7478e-02 6.8333e-02 -6.0000e+00 7.8880e-01 -1.3637e+00 3.0195e-02 3.1820e-02 -6.0000e+00 4.6825e-01 5.4009e-01 1.4513e-02 8.1185e-03 -6.0000e+00 1.9890e-01 3.8463e-05 -1.7166e-03 3.7911e-04 2.1976e-04 -6.0000e+00 1.4774e-02 -2.2731e-02 0.0000e+00 12 9 9 12 1 1 99.88 21.18 0.18 -0.02273 -0.03563 8 5 1 5 0 1858.860 25.47 19.99 21.18 17.08 0.0 907.81 39965 900000 -47102 -65797 -117350 -62280 -88579 -70558 900000 -44190 900000 -88612 -144148 88408 -1926 41975 66775 -10705 -9701 48086 30002 33173 152390 -14749 -40006 317789 -5641 900000 -51356 -40522 56236 214504 -33678 -16950 30692 24135 50665 -58978 -12546 3711 40981 95161 24400 42085 60577 33346 31619 8634 16547 39706 55411 45298 44525 25058 52492 56752 37644 39751 272 15863 20906 -3199 17218 11863 20996 11085 15253 10259 36634 5977 23303 -1663 4302 -7329 -2991 -5888 8561 -4271 -404 -5430 4804 6705 1503 -147 2401 6573 4040 -5487 -677 -2966 -3401 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