File name: Pandora107s1_LynnMA_20250518_L2Fit_fout2c8d20240424p1-8.txt File generation date: 20250519T044837.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Gonzalo Gonzalez Abad Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 107 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora107_OF_v3d20230601.txt Instrument calibration file used: Pandora107s1_CF_v8d20240424.txt Level 1 file used: Pandora107s1_LynnMA_20250518_L1_smca1c8d20240424p1-8.txt Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20250518 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld based on session 7 "OOB session based on clearance session 6, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used" First and last pixel inside fitting window: 221 362 Nominal wavelengths inside fitting window [nm]: 305.1394 305.2803 305.4212 305.5621 305.7030 305.8438 305.9847 306.1255 306.2663 306.4071 306.5479 306.6887 306.8295 306.9702 307.1110 307.2517 307.3925 307.5332 307.6739 307.8146 307.9553 308.0959 308.2366 308.3773 308.5179 308.6585 308.7991 308.9397 309.0803 309.2209 309.3615 309.5021 309.6426 309.7832 309.9237 310.0642 310.2047 310.3452 310.4857 310.6262 310.7666 310.9071 311.0475 311.1880 311.3284 311.4688 311.6092 311.7496 311.8899 312.0303 312.1706 312.3110 312.4513 312.5916 312.7319 312.8722 313.0125 313.1528 313.2930 313.4333 313.5735 313.7137 313.8540 313.9942 314.1344 314.2745 314.4147 314.5549 314.6950 314.8352 314.9753 315.1154 315.2555 315.3956 315.5357 315.6757 315.8158 315.9558 316.0959 316.2359 316.3759 316.5159 316.6559 316.7959 316.9358 317.0758 317.2157 317.3557 317.4956 317.6355 317.7754 317.9153 318.0552 318.1950 318.3349 318.4747 318.6145 318.7544 318.8942 319.0340 319.1738 319.3135 319.4533 319.5930 319.7328 319.8725 320.0122 320.1519 320.2916 320.4313 320.5710 320.7106 320.8503 320.9899 321.1295 321.2691 321.4087 321.5483 321.6879 321.8275 321.9670 322.1066 322.2461 322.3856 322.5251 322.6646 322.8041 322.9436 323.0831 323.2225 323.3619 323.5014 323.6408 323.7802 323.9196 324.0590 324.1983 324.3377 324.4771 324.6164 324.7557 324.8950 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250518T111001.9Z 9269.465300 188 1 50.66 2 71.53 79.92 71.19 205.88 0.00 1 0.00 1 0 25 6.463e-02 7.916e-03 3.453e-03 3.295e-04 4.946914e-01 1.726823e-04 5.821686e-03 -6.000000e+00 3.813122e-02 231.21 -2.00 3.54 -2.00 318.95 0.00e+00 2.260889e-03 4.041043e-05 6.262309e-04 -6.000000e+00 1.664698e-03 282.69 -2.00 20.00 -2.00 318.25 0.00e+00 3.116 0.001 302.00 328.00 3 9.0569e-02 4.7722e-04 4.0842e-02 -6.0000e+00 9.5493e-02 5.4615e-02 5.5009e-04 2.6159e-02 -6.0000e+00 1.0330e-01 -4.4492e-02 4.0725e-04 1.3106e-02 -6.0000e+00 6.1334e-02 1.0205e-02 2.1466e-04 4.1748e-03 -6.0000e+00 2.5960e-02 1.1575e-02 -4.2293e-04 9.3943e-06 4.3765e-05 -6.0000e+00 1.8220e-03 2.4376e-02 0.0000e+00 11 8 0 10 0 0 8.38 21.60 0.29 0.02438 0.02120 1086 204 1 5 0 46.380 25.79 20.01 21.60 22.79 0.0 930.86 -19226 -20720 -20577 -26598 -22942 -25928 -21852 -19224 -21323 -19912 -19846 -8496 -10064 -5695 -2235 -2854 -430 -267 429 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565 947 1176 889 194 444 339 -1024 -1983 -1641 -390 875 578 -1769 -2347 -1649 -541 678 811 379 -155 150 404 1057 2089 2062 1651 747 -757 -987 -245 680 254 -28 -508 1042 2393 872 -673 -1247 -870 186 184 -176 -725 17 353 -359 -984 -683 -29 876 SS 20250518T111225.0Z 9269.466956 190 1 50.61 2 71.10 80.29 71.38 206.41 0.00 1 0.00 1 0 25 5.637e-02 7.973e-03 3.037e-03 3.129e-04 4.841036e-01 1.637889e-04 5.725100e-03 -6.000000e+00 3.325792e-02 231.21 -2.00 3.54 -2.00 318.83 0.00e+00 2.038016e-03 3.708214e-05 6.088734e-04 -6.000000e+00 1.451910e-03 282.69 -2.00 20.00 -2.00 318.13 0.00e+00 3.049 0.000 302.00 328.00 3 7.0693e-02 4.5111e-04 3.9987e-02 -6.0000e+00 8.3289e-02 5.1273e-02 5.1819e-04 2.5624e-02 -6.0000e+00 9.0096e-02 -4.2248e-02 3.7557e-04 1.2763e-02 -6.0000e+00 5.3495e-02 9.9632e-03 1.9765e-04 3.9485e-03 -6.0000e+00 2.2643e-02 1.2771e-02 -4.3214e-04 8.9184e-06 4.1944e-05 -6.0000e+00 1.5891e-03 2.4174e-02 0.0000e+00 11 8 0 10 0 0 10.43 21.62 0.32 0.02417 0.02093 1144 215 1 5 0 44.000 25.90 20.01 21.62 22.90 0.0 931.66 -17632 -15656 -18941 -21001 -21460 -21780 -18508 -18525 -18183 -19008 -16344 -5387 -7932 -5583 -2878 -1254 -690 93 414 -858 -105 274 -480 -1636 -8044 -3429 -3942 -3526 -1611 162 932 213 -1660 -2870 -2029 -1251 -937 -777 -1406 -1373 -1089 -851 -381 324 462 548 615 458 1280 2203 1776 1823 1615 1568 1455 739 176 132 821 1702 2294 1989 1198 -233 -270 718 1298 1858 474 -361 -490 -590 -557 -799 -458 -367 -94 212 -665 -1090 -1431 -1861 -1330 -648 -382 -379 -334 127 241 317 502 997 1251 928 172 343 317 -741 -1577 -1210 -352 773 484 -1423 -1900 -1199 -403 527 564 260 -137 37 279 783 1428 1442 1210 487 -428 -658 -169 472 196 32 -289 703 1684 668 -454 -757 -473 134 91 -94 -387 0 175 -185 -530 -369 -52 489 -511 -479 -592 -623 -604 -637 -595 -678 -715 -783 -701 -242 -451 -380 -223 -97 -58 8 39 -84 -10 27 -51 -191 -1064 -438 -493 -427 -194 21 140 37 -311 -537 -366 -236 -206 -191 -414 -456 -360 -294 -134 115 165 198 224 170 488 893 795 828 787 804 777 409 98 72 440 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-3.9582e-04 7.8008e-06 3.5848e-05 -6.0000e+00 9.3823e-04 2.3714e-02 0.0000e+00 11 8 0 10 0 0 99.93 21.73 0.31 0.02371 0.02074 1379 259 1 5 0 36.490 25.90 20.01 21.73 23.66 0.0 934.59 -9112 -8391 -11168 -12889 -13706 -12449 -9994 -10589 -10226 -10769 -8785 -4610 -4303 -2221 -1528 23 118 1224 1326 460 848 1713 1304 -572 -4563 -2819 -2644 -1932 -765 1006 845 312 -2185 -2640 -1883 -1171 -577 -725 -1202 -1384 -953 -680 -339 335 336 315 334 99 1083 1886 1702 1503 1365 1315 1481 730 238 286 826 1714 2165 1841 951 -447 -426 607 1225 1694 328 -350 -543 -575 -531 -675 -485 -212 66 308 -591 -1110 -1476 -1929 -1416 -697 -388 -346 -293 127 222 237 446 994 1373 960 296 356 278 -798 -1574 -1271 -378 777 530 -1363 -1864 -1230 -422 517 573 243 -121 83 253 798 1456 1496 1141 557 -407 -635 -261 370 188 56 -222 772 1691 684 -425 -736 -524 135 138 -36 -362 36 190 -218 -570 -406 -84 414 -396 -386 -520 -564 -569 -527 -468 -567 -587 -641 -542 -313 -354 -196 -155 3 14 152 174 63 116 236 191 -93 -813 -498 -452 -316 -124 173 167 64 -488 -582 -400 -260 -149 -228 -415 -538 -397 -295 -139 138 139 131 150 42 465 856 846 814 737 744 868 443 145 172 486 1018 1373 1214 692 -323 -319 423 831 1223 256 -287 -471 -502 -447 -563 -365 -153 46 223 -462 -949 -1349 -1927 -1421 -738 -416 -394 -346 150 254 255 464 1001 1349 1007 332 429 358 -1079 -2096 -1669 -467 923 633 -1682 -2360 -1626 -581 721 833 367 -192 129 391 1145 2039 2063 1634 818 -637 -978 -410 558 274 82 -309 1063 2309 972 -646 -1162 -861 220 235 -63 -645 65 353 -408 -1052 -741 -145 714 SS 20250518T112747.6Z 9269.477635 196 1 50.85 2 68.29 82.73 72.64 209.76 0.00 1 0.00 1 0 25 3.103e-02 7.739e-03 2.162e-03 3.128e-04 4.278883e-01 1.634450e-04 5.087567e-03 -6.000000e+00 1.830874e-02 231.21 -2.00 3.54 -2.00 318.44 0.00e+00 1.449817e-03 3.240709e-05 4.080182e-04 -6.000000e+00 7.992127e-04 282.69 -2.00 20.00 -2.00 317.72 0.00e+00 2.679 0.000 302.00 328.00 3 4.5251e-01 4.4416e-04 3.5209e-02 -6.0000e+00 4.5851e-02 4.3602e-02 5.0448e-04 2.2600e-02 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