File name: Pandora107s1_LynnMA_20250520_L2Fit_fwvt1c8d20240424p1-8.txt File generation date: 20250530T143148.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Gonzalo Gonzalez Abad Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 107 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora107_OF_v3d20230601.txt Instrument calibration file used: Pandora107s1_CF_v8d20240424.txt Level 1 file used: Pandora107s1_LynnMA_20250520_L1_smca1c8d20240424p1-8.txt Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20250520 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld based on session 7 "OOB session based on clearance session 6, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used" First and last pixel inside fitting window: 1640 1789 Nominal wavelengths inside fitting window [nm]: 492.0496 492.1707 492.2918 492.4128 492.5339 492.6549 492.7759 492.8969 493.0179 493.1388 493.2598 493.3807 493.5016 493.6225 493.7434 493.8642 493.9851 494.1059 494.2267 494.3475 494.4683 494.5890 494.7098 494.8305 494.9512 495.0719 495.1925 495.3132 495.4338 495.5544 495.6750 495.7956 495.9162 496.0367 496.1573 496.2778 496.3983 496.5188 496.6392 496.7597 496.8801 497.0005 497.1209 497.2413 497.3617 497.4820 497.6023 497.7226 497.8429 497.9632 498.0835 498.2037 498.3239 498.4441 498.5643 498.6845 498.8046 498.9248 499.0449 499.1650 499.2851 499.4052 499.5252 499.6452 499.7653 499.8852 500.0052 500.1252 500.2451 500.3651 500.4850 500.6049 500.7248 500.8446 500.9645 501.0843 501.2041 501.3239 501.4437 501.5634 501.6831 501.8029 501.9226 502.0423 502.1619 502.2816 502.4012 502.5208 502.6404 502.7600 502.8796 502.9991 503.1187 503.2382 503.3577 503.4771 503.5966 503.7160 503.8355 503.9549 504.0743 504.1936 504.3130 504.4323 504.5517 504.6710 504.7902 504.9095 505.0288 505.1480 505.2672 505.3864 505.5056 505.6248 505.7439 505.8630 505.9821 506.1012 506.2203 506.3394 506.4584 506.5774 506.6964 506.8154 506.9344 507.0533 507.1723 507.2912 507.4101 507.5290 507.6479 507.7667 507.8855 508.0043 508.1231 508.2419 508.3607 508.4794 508.5981 508.7168 508.8355 508.9542 509.0729 509.1915 509.3101 509.4287 509.5473 509.6659 509.7844 509.9029 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250520T120824.0Z 9271.505834 197 1 14.87 2 60.58 88.95 58.98 199.38 0.00 1 0.00 1 0 15 2.941e-03 2.912e-03 1.178e-03 1.175e-03 2.341666e+03 6.758288e+01 1.789896e+02 -6.000000e+00 1.567933e+02 282.89 -2.00 20.00 -2.00 505.24 0.00e+00 4.708886e-04 3.177096e-05 2.829141e-05 -6.000000e+00 8.118526e-05 282.89 -2.00 20.00 -2.00 500.39 0.00e+00 9.803846e-02 2.291646e-02 1.513216e-02 -6.000000e+00 5.750155e-02 231.33 -2.00 3.54 -2.00 501.99 0.00e+00 2.027 0.000 489.00 513.00 1 6.5632e+00 1.7518e-03 3.2430e-03 -6.0000e+00 4.3959e-03 1.5398e-02 4.6039e-04 4.1062e-04 -6.0000e+00 1.1597e-03 2.0404e-03 7.0994e-04 9.9838e-05 2.4405e-05 -6.0000e+00 2.5572e-04 2.8604e-02 -1.1935e-04 12 1 1 12 33 1 98.62 21.33 1.73 0.02860 0.03353 7 5 1 4 0 1857.730 25.58 20.00 21.33 16.93 0.0 907.08 -555 -432 -595 6 180 527 411 28 215 434 400 210 -158 -132 7 116 19 2 42 -91 114 343 150 -36 280 202 137 -9 -364 -159 -34 -230 -148 -195 -253 -227 127 129 -162 115 -31 102 200 244 256 270 331 237 57 -79 -600 -476 -209 6 -173 -267 -347 -205 288 249 65 166 87 -1 55 -36 78 -311 -267 -444 -131 117 166 -15 -489 -184 92 -340 -71 -320 -401 -186 23 -53 -46 -107 -72 -119 207 296 118 199 178 277 468 47 -56 32 -516 -433 -270 -191 -333 -613 -330 -209 -142 -87 37 -247 -71 -66 183 237 313 470 281 169 195 183 280 191 401 59 -13 170 152 288 271 166 -79 -190 -73 -296 75 -65 -193 -80 1744 -404 146 346 226 56 24 -278 -383 -402 -394 -381 -546 -426 -597 7 186 555 432 29 228 452 417 216 -161 -135 7 118 19 2 44 -96 119 363 156 -37 294 212 143 -10 -374 -160 -34 -228 -151 -204 -267 -240 132 135 -167 117 -31 105 208 253 268 283 343 242 58 -80 -593 -467 -202 6 -172 -269 -358 -208 295 255 67 168 88 -1 56 -36 78 -311 -264 -434 -127 113 163 -14 -486 -180 89 -326 -68 -311 -384 -179 22 -52 -44 -105 -70 -117 202 290 117 197 179 278 462 46 -54 31 -487 -407 -252 -182 -319 -604 -331 -208 -139 -85 36 -243 -69 -65 184 236 312 471 284 171 195 183 274 185 393 57 -13 166 149 279 263 161 -76 -184 -69 -282 71 -62 -185 -78 1695 -397 143 340 224 56 24 -276 -371 -385 -376 -363 SQ 20250520T120934.8Z 9271.506653 199 1 11.78 2 60.36 89.14 59.05 199.70 0.00 1 0.00 1 0 15 2.176e-03 2.180e-03 4.663e-04 4.655e-04 2.208588e+03 2.661428e+01 1.624323e+02 -6.000000e+00 1.160094e+02 282.89 -2.00 20.00 -2.00 505.24 0.00e+00 4.422660e-04 1.258426e-05 2.666742e-05 -6.000000e+00 6.006313e-05 282.89 -2.00 20.00 -2.00 500.42 0.00e+00 9.707859e-02 9.062573e-03 1.568005e-02 -6.000000e+00 4.253422e-02 231.33 -2.00 3.54 -2.00 502.01 0.00e+00 2.013 0.000 489.00 513.00 1 4.6138e+00 6.9288e-04 3.2293e-03 -6.0000e+00 3.2518e-03 1.4346e-02 1.8202e-04 4.0675e-04 -6.0000e+00 8.5765e-04 1.4370e-02 6.0679e-04 3.9416e-05 2.2396e-05 -6.0000e+00 1.8916e-04 2.6802e-02 -9.4415e-05 12 1 1 12 1 1 98.39 21.34 1.88 0.02680 0.03101 40 33 1 4 0 287.070 25.58 20.00 21.34 16.91 0.0 907.19 -360 -423 -442 -108 139 373 334 274 300 281 244 115 -169 -167 -35 58 127 -77 -51 183 196 247 346 191 183 258 147 -139 -392 -212 -110 -40 -44 -263 -277 -48 -20 -142 -78 -8 -77 45 200 260 197 205 236 249 -56 -250 -329 -315 -179 -107 -292 -342 -223 15 132 343 205 278 145 129 58 54 62 -177 -279 -287 -259 -53 -97 -307 -380 -320 -46 -49 -156 -185 -237 -256 -30 2 60 37 -18 20 -59 194 305 222 95 57 215 150 -29 -328 -339 -251 -179 -104 -277 -444 -418 -207 -112 -173 33 -58 -155 17 66 233 367 488 230 169 134 123 256 265 182 83 35 147 160 286 435 113 -182 2 36 -85 16 -109 -81 59 237 107 55 214 186 193 -46 -132 -353 -350 -208 -217 -350 -421 -449 -111 144 387 353 287 318 294 251 118 -172 -171 -35 59 129 -79 -53 192 206 259 362 201 193 272 155 -145 -404 -214 -110 -40 -45 -271 -289 -50 -21 -147 -81 -8 -80 45 206 271 204 212 246 256 -57 -250 -325 -308 -172 -104 -290 -346 -227 16 134 346 208 283 148 132 59 55 61 -177 -276 -281 -251 -51 -96 -303 -379 -315 -45 -47 -150 -179 -226 -247 -29 2 59 36 -18 19 -58 191 303 221 97 57 214 149 -28 -317 -320 -236 -167 -99 -267 -440 -417 -205 -110 -170 32 -56 -153 17 66 234 369 494 231 170 133 122 253 257 177 81 34 145 157 280 424 111 -177 2 34 -81 15 -104 -78 57 232 106 55 213 183 191 -45 -130 -346 -338 -199 -207 SQ 20250520T121044.1Z 9271.507455 201 1 30.40 2 60.15 89.34 59.12 200.01 0.00 1 0.00 1 0 15 2.110e-03 2.108e-03 3.324e-04 3.318e-04 2.185340e+03 1.898150e+01 1.615827e+02 -6.000000e+00 1.124748e+02 282.89 -2.00 20.00 -2.00 505.24 0.00e+00 4.382228e-04 8.968895e-06 2.624497e-05 -6.000000e+00 5.824216e-05 282.89 -2.00 20.00 -2.00 500.40 0.00e+00 9.249780e-02 6.471755e-03 1.529155e-02 -6.000000e+00 4.125732e-02 231.33 -2.00 3.54 -2.00 501.99 0.00e+00 2.000 0.000 489.00 513.00 1 4.8990e+00 4.9469e-04 3.1984e-03 -6.0000e+00 3.1540e-03 1.5277e-02 1.3017e-04 3.9996e-04 -6.0000e+00 8.3222e-04 1.0829e-02 8.5272e-04 2.8074e-05 2.1938e-05 -6.0000e+00 1.8347e-04 2.8805e-02 -1.3218e-04 12 1 1 12 1 1 99.98 21.34 1.88 0.02880 0.03472 131 41 1 4 0 230.220 25.58 20.00 21.34 16.92 0.0 907.53 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