File name: Pandora186s1_MadisonCT_20240123_L2Fit_fout2c2d20210922p1-8.txt File generation date: 20240124T050614.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 186 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora186_OF_v4d20210803.txt Instrument calibration file used: Pandora186s1_CF_v2d20210922.txt Level 1 file used: Pandora186s1_MadisonCT_20240123_L1_smca1c2d20210922p1-8.txt Full location name: Madison - Hammonasset State Park CTDEEP (USEPA AQS ID 09-009-9002) Short location name: MadisonCT Country of location: USA Location latitude [deg]: 41.2568 Location longitude [deg]: -72.5533 Location altitude [m]: 3 Local noon date: 20240123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0092 305.1504 305.2917 305.4329 305.5741 305.7153 305.8565 305.9977 306.1389 306.2800 306.4212 306.5623 306.7034 306.8445 306.9856 307.1267 307.2678 307.4089 307.5499 307.6909 307.8320 307.9730 308.1140 308.2550 308.3960 308.5369 308.6779 308.8189 308.9598 309.1007 309.2416 309.3825 309.5234 309.6643 309.8052 309.9460 310.0869 310.2277 310.3685 310.5093 310.6501 310.7909 310.9317 311.0724 311.2132 311.3539 311.4946 311.6354 311.7761 311.9167 312.0574 312.1981 312.3387 312.4794 312.6200 312.7606 312.9012 313.0418 313.1824 313.3230 313.4636 313.6041 313.7447 313.8852 314.0257 314.1662 314.3067 314.4472 314.5876 314.7281 314.8685 315.0090 315.1494 315.2898 315.4302 315.5706 315.7109 315.8513 315.9917 316.1320 316.2723 316.4126 316.5529 316.6932 316.8335 316.9738 317.1140 317.2543 317.3945 317.5347 317.6749 317.8151 317.9553 318.0955 318.2356 318.3758 318.5159 318.6560 318.7961 318.9362 319.0763 319.2164 319.3565 319.4965 319.6366 319.7766 319.9166 320.0566 320.1966 320.3366 320.4765 320.6165 320.7565 320.8964 321.0363 321.1762 321.3161 321.4560 321.5959 321.7357 321.8756 322.0154 322.1552 322.2950 322.4348 322.5746 322.7144 322.8542 322.9939 323.1337 323.2734 323.4131 323.5528 323.6925 323.8322 323.9719 324.1115 324.2512 324.3908 324.5304 324.6700 324.8096 324.9492 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240123T133427.6Z 8788.565597 275 1 50.71 2 77.43 130.55 107.51 336.32 0.00 1 0.00 1 0 25 3.947e-01 8.354e-03 3.178e-01 6.473e-03 6.422824e-01 3.539349e-03 7.176458e-03 -6.000000e+00 2.316493e-01 224.02 -2.00 3.52 -2.00 321.18 0.00e+00 2.943320e-03 1.612218e-03 8.778159e-04 -6.000000e+00 1.078904e-02 275.00 -2.00 20.00 -2.00 320.69 0.00e+00 4.468 0.002 302.00 328.00 3 3.4926e+00 1.1458e-02 5.5767e-02 -6.0000e+00 5.7389e-01 1.0234e-01 1.5813e-02 3.4438e-02 -6.0000e+00 6.2588e-01 -6.0229e-02 1.6893e-02 1.9087e-02 -6.0000e+00 3.6961e-01 8.0140e-03 8.1546e-03 7.1373e-03 -6.0000e+00 1.5440e-01 8.9859e-05 -6.0334e-04 2.0023e-04 9.1761e-05 -6.0000e+00 1.1874e-02 4.4669e-03 4.7197e-05 11 8 0 10 0 0 99.90 19.71 0.22 0.00447 -0.00007 45 8 1 5 0 1126.720 22.50 15.00 19.71 8.80 23.5 938.16 -109302 -51567 -102988 -46709 -42357 230349 -78859 900000 -158886 900000 -127157 900000 -122040 75119 -73308 8663 -8715 109852 119086 72626 -39358 -49155 -13722 6451 73588 -23718 47752 -31680 -524 -19903 30596 -30089 19873 27547 17218 7700 -11970 27161 -20380 -3131 -12225 993 -14651 939 -6902 14850 -5077 4117 -3578 8144 184 5304 477 6858 659 -3011 5038 -1518 273 1868 7403 -1710 6187 -1037 9729 -1067 2736 1718 2593 1811 1774 -243 344 1873 -388 22 -4033 2283 -5784 -818 -525 1032 -1989 -217 296 -1311 -60 1002 467 -57 751 -281 397 -603 793 -822 153 -263 449 -1140 -659 -983 -156 -998 -372 -493 -1042 268 -734 1372 -61 140 586 -162 32 291 325 685 -376 6 -64 -65 59 -701 681 218 725 446 486 19 92 -420 -80 -192 -198 -448 303 377 2 346 25 97 -785 -690 -325 -721 -295 -267 1453 -498 900000 -2332 900000 -1646 900000 -2036 474 -1239 83 -113 693 751 577 -912 -1269 -265 111 739 -622 669 -921 -11 -544 604 -1237 594 836 579 281 -563 1025 -1451 -226 -1099 86 -1554 89 -720 1288 -547 420 -412 895 24 736 76 1121 122 -605 967 -312 54 360 1387 -380 1434 -289 2604 -317 775 505 820 654 710 -104 146 750 -147 8 -1338 715 -2149 -338 -252 554 -1210 -139 200 -956 -45 772 362 -43 530 -188 254 -399 570 -685 145 -283 519 -1347 -736 -1009 -147 -941 -367 -516 -1156 313 -941 1905 -94 226 950 -257 49 422 471 1026 -597 9 -104 -103 90 -1044 966 301 972 623 748 33 172 -831 -166 -418 -457 -1081 741 932 4 826 57 210 -1676 SS 20240123T134525.9Z 8788.573216 278 1 50.59 2 75.88 132.68 108.27 338.62 0.00 1 0.00 1 0 25 2.741e-01 5.731e-03 2.227e-01 4.815e-03 5.803783e-01 2.560667e-03 6.493889e-03 -6.000000e+00 1.596143e-01 224.02 -2.00 3.52 -2.00 320.86 0.00e+00 4.049244e-03 1.070841e-03 5.253335e-04 -6.000000e+00 6.944261e-03 275.00 -2.00 20.00 -2.00 320.37 0.00e+00 4.011 0.001 302.00 328.00 3 3.2481e+00 7.9817e-03 5.0223e-02 -6.0000e+00 3.9382e-01 6.2143e-02 1.0520e-02 3.1424e-02 -6.0000e+00 4.2886e-01 -3.4013e-02 1.0770e-02 1.6738e-02 -6.0000e+00 2.5529e-01 3.4266e-03 5.3079e-03 7.7402e-03 -6.0000e+00 1.0699e-01 1.9069e-04 -5.4713e-05 1.4816e-04 8.0274e-05 -6.0000e+00 8.1215e-03 3.4612e-03 1.2070e-04 10 0 0 10 0 0 99.97 19.71 0.42 0.00346 0.00305 141 26 1 5 0 358.750 22.50 15.00 19.71 9.24 23.5 941.91 69918 48624 -83704 -59744 -115527 -69494 -29975 175065 -69607 -64280 -99764 -82326 -35710 20983 -31928 28055 3792 14416 -7767 -1616 -25300 12208 15140 -24134 -24577 1114 -20089 -24014 -30912 -8609 -332 -7629 11912 -16681 832 6246 8605 7423 845 3590 -336 1011 -2611 4623 -122 -1815 -5704 -1710 1305 517 5136 4770 4617 4191 2645 2677 -693 -463 45 -824 -1764 3900 572 990 1686 197 917 417 2947 772 706 736 418 81 -712 1190 -1442 -357 -2980 -435 -1560 -304 -2255 -1790 -1634 -450 281 289 64 236 1016 765 984 164 696 78 1116 234 -379 -461 -174 -193 -111 -716 -583 -729 -535 84 339 677 -183 51 -32 13 -114 558 142 261 -216 -217 -76 -92 175 94 129 65 104 513 78 -298 328 -229 -149 36 -60 -216 68 238 87 187 -126 -107 -290 328 228 -819 -468 -1492 -544 -164 822 -708 -679 -1600 -1224 -405 172 -562 329 65 248 -182 -38 -722 263 326 -758 -834 34 -711 -876 -1195 -280 -11 -333 495 -1006 42 296 426 432 63 314 -35 112 -319 544 -15 -238 -795 -235 181 77 794 822 874 863 588 619 -170 -114 11 -197 -438 993 169 325 581 68 309 144 1069 324 328 359 205 38 -310 460 -530 -129 -1205 -199 -840 -184 -1525 -1285 -1248 -361 236 249 55 198 791 556 681 116 536 69 1123 269 -440 -580 -207 -209 -111 -716 -618 -819 -634 106 461 1013 -280 81 -52 20 -179 833 213 406 -355 -371 -130 -153 280 145 190 92 144 731 123 -524 624 -432 -294 75 -134 -502 162 574 210 431 -278 -223 -590 SS 20240123T143757.3Z 8788.609691 303 1 50.42 2 69.29 143.67 110.85 350.08 0.00 1 0.00 1 0 25 3.333e-02 4.383e-03 1.352e-02 1.177e-03 4.110911e-01 6.012703e-04 4.803355e-03 -6.000000e+00 1.940427e-02 224.02 -2.00 3.52 -2.00 319.35 0.00e+00 8.982906e-04 1.550288e-04 2.193232e-04 -6.000000e+00 8.443057e-04 275.00 -2.00 20.00 -2.00 318.78 0.00e+00 2.800 0.000 302.00 328.00 3 2.9306e+00 1.6665e-03 3.4829e-02 -6.0000e+00 4.7877e-02 2.9914e-02 1.9363e-03 2.0897e-02 -6.0000e+00 5.2141e-02 -1.8351e-02 1.4938e-03 1.0523e-02 -6.0000e+00 3.1038e-02 -9.3385e-04 7.8597e-04 3.2198e-03 -6.0000e+00 1.3005e-02 1.0375e-03 -1.8044e-04 3.6756e-05 3.8172e-05 -6.0000e+00 9.8752e-04 3.7159e-03 6.6568e-05 10 0 0 10 0 0 99.89 19.71 0.26 0.00372 0.00236 119 22 1 5 0 423.610 22.50 15.00 19.71 10.84 23.8 957.62 -7809 -10075 -11395 -13158 -10907 -8590 -3879 -13573 -6347 -14170 -8902 -11280 -4125 -7229 -2943 -2232 -63 -2905 -167 -1181 1339 974 587 -171 -3030 1372 -3545 -1550 -3892 -597 -2168 1999 435 -719 -2319 -870 -2038 -1379 -1524 -1249 -371 -959 -1097 -658 43 -57 118 -722 -357 -142 1222 637 1649 1579 1118 1495 1137 576 342 1015 1051 1492 1636 1618 578 96 -7 93 684 830 412 172 375 -77 58 -508 -510 -540 -368 -760 -902 -1339 -1408 -1497 -933 -701 -160 46 178 487 190 327 231 412 445 556 427 602 16 -193 -424 -449 -305 84 -504 -781 -628 -586 -58 234 298 -47 174 -154 69 341 414 403 198 -39 -261 -71 172 178 105 439 88 669 502 175 104 -215 -292 -75 -200 -168 -47 154 98 -70 42 -145 -226 -176 -268 -330 -384 -288 -210 -93 -400 -196 -514 -319 -436 -169 -366 -170 -148 -4 -229 -14 -102 116 85 53 -16 -321 147 -405 -169 -415 -62 -246 244 60 -107 -344 -125 -315 -244 -325 -315 -104 -291 -348 -213 14 -18 38 -236 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