File name: Pandora186s1_MadisonCT_20240626_L2Fit_fout2c2d20210922p1-8.txt File generation date: 20240627T050115.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 186 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora186_OF_v4d20210803.txt Instrument calibration file used: Pandora186s1_CF_v2d20210922.txt Level 1 file used: Pandora186s1_MadisonCT_20240626_L1_smca1c2d20210922p1-8.txt Full location name: Madison - Hammonasset State Park CTDEEP (USEPA AQS ID 09-009-9002) Short location name: MadisonCT Country of location: USA Location latitude [deg]: 41.2568 Location longitude [deg]: -72.5533 Location altitude [m]: 3 Local noon date: 20240626 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0092 305.1504 305.2917 305.4329 305.5741 305.7153 305.8565 305.9977 306.1389 306.2800 306.4212 306.5623 306.7034 306.8445 306.9856 307.1267 307.2678 307.4089 307.5499 307.6909 307.8320 307.9730 308.1140 308.2550 308.3960 308.5369 308.6779 308.8189 308.9598 309.1007 309.2416 309.3825 309.5234 309.6643 309.8052 309.9460 310.0869 310.2277 310.3685 310.5093 310.6501 310.7909 310.9317 311.0724 311.2132 311.3539 311.4946 311.6354 311.7761 311.9167 312.0574 312.1981 312.3387 312.4794 312.6200 312.7606 312.9012 313.0418 313.1824 313.3230 313.4636 313.6041 313.7447 313.8852 314.0257 314.1662 314.3067 314.4472 314.5876 314.7281 314.8685 315.0090 315.1494 315.2898 315.4302 315.5706 315.7109 315.8513 315.9917 316.1320 316.2723 316.4126 316.5529 316.6932 316.8335 316.9738 317.1140 317.2543 317.3945 317.5347 317.6749 317.8151 317.9553 318.0955 318.2356 318.3758 318.5159 318.6560 318.7961 318.9362 319.0763 319.2164 319.3565 319.4965 319.6366 319.7766 319.9166 320.0566 320.1966 320.3366 320.4765 320.6165 320.7565 320.8964 321.0363 321.1762 321.3161 321.4560 321.5959 321.7357 321.8756 322.0154 322.1552 322.2950 322.4348 322.5746 322.7144 322.8542 322.9939 323.1337 323.2734 323.4131 323.5528 323.6925 323.8322 323.9719 324.1115 324.2512 324.3908 324.5304 324.6700 324.8096 324.9492 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240626T102141.0Z 8943.431725 177 1 49.10 2 80.42 67.28 59.38 205.60 0.00 1 0.00 1 0 25 6.847e-01 2.720e-02 3.672e-01 1.926e-02 7.972237e-01 1.138644e-02 9.724442e-03 -6.000000e+00 4.168269e-01 232.94 -2.00 3.52 -2.00 321.78 0.00e+00 1.658358e-02 6.200122e-03 3.946756e-03 -6.000000e+00 2.182644e-02 287.63 -2.00 20.00 -2.00 321.21 0.00e+00 5.723 0.003 302.00 328.00 3 3.4958e+00 4.3170e-02 7.2281e-02 -6.0000e+00 1.0440e+00 8.9639e-01 5.5901e-02 4.3796e-02 -6.0000e+00 1.1297e+00 -1.0505e+00 4.4345e-02 2.6924e-02 -6.0000e+00 6.7072e-01 4.1410e-01 2.0752e-02 1.6067e-02 -6.0000e+00 2.8030e-01 1.8364e-05 -9.4816e-04 5.7049e-04 2.8327e-04 -6.0000e+00 2.1150e-02 6.0902e-04 1.9117e-04 12 8 8 10 0 0 99.60 20.92 0.60 0.00061 -0.00652 14 3 1 5 0 3506.400 23.53 15.00 20.92 25.44 26.9 1069.45 -114166 -113949 -124868 900000 900000 900000 -147309 -62097 171722 -137252 900000 -34556 354328 -85359 -46699 139016 146026 41490 15966 900000 900000 6946 -22184 900000 900000 -63491 900000 -66768 233998 -80748 900000 -32570 328924 -19456 234400 42614 -9819 104579 84998 450 73199 58259 5754 12723 27799 64790 11945 56072 -6683 70445 -3291 82197 38667 20838 33039 -3474 19220 -2151 50042 30270 -12539 -7950 29568 -2223 44636 23274 18787 9987 12295 -5463 25161 4089 7305 5663 14276 -5401 -3222 -5585 -10012 -3109 -6068 -2411 -56 1219 -543 2828 -7221 -815 -1004 2703 3261 3107 -1725 -2015 -1116 -3976 2914 -4054 1868 -601 -1331 -4023 -4645 -2191 200 -1999 -1157 -3938 3 -1338 -1124 246 -146 837 -745 722 -1089 172 -343 998 287 2610 2020 1308 93 -344 2113 1710 288 2707 1905 -824 96 -507 -1071 -190 1309 958 -1061 201 -373 -442 -1756 -3570 -4234 -5517 900000 900000 900000 -5755 -1164 3220 -4665 900000 -648 6644 -2994 -1457 2607 2738 852 444 900000 900000 202 -814 900000 900000 -3258 900000 -3368 4388 -5005 900000 -1845 6168 -1213 4395 1360 -527 2062 2316 31 2798 2720 462 986 1897 3170 994 3174 -722 3865 -398 4826 3730 2542 3738 -567 2520 -339 4605 3288 -2102 -1387 4065 -470 6474 4184 3508 2084 2705 -1603 6035 1251 2137 1582 3332 -1371 -746 -1342 -2808 -969 -2301 -1012 -25 582 -279 1486 -4375 -477 -589 1484 1678 1505 -850 -1032 -635 -2719 2189 -3761 1804 -607 -1290 -3640 -3843 -1728 161 -1746 -1063 -4010 4 -1659 -1555 360 -220 1230 -1072 995 -1537 250 -527 1563 448 3838 2870 1808 126 -451 2659 2266 435 4528 3561 -1701 208 -1175 -2651 -489 3387 2508 -2809 506 -886 -988 -3835 SS 20240626T103110.6Z 8943.438317 182 1 50.64 2 78.77 68.73 60.12 208.05 0.00 1 0.00 1 0 17 4.950e-01 1.014e-02 2.126e-01 4.311e-03 7.139694e-01 2.452172e-03 8.282609e-03 -6.000000e+00 3.003681e-01 232.94 -2.00 3.52 -2.00 321.53 0.00e+00 7.152234e-03 1.357730e-03 3.581692e-03 -6.000000e+00 1.378062e-02 287.63 -2.00 20.00 -2.00 320.97 0.00e+00 4.953 0.002 302.00 328.00 3 2.2284e+00 9.2358e-03 6.4447e-02 -6.0000e+00 7.5296e-01 1.6985e-01 1.3100e-02 4.2224e-02 -6.0000e+00 8.1279e-01 -2.3135e-01 1.2862e-02 2.4717e-02 -6.0000e+00 4.8285e-01 8.6716e-02 5.9089e-03 9.7368e-03 -6.0000e+00 2.0169e-01 1.8216e-04 -1.0733e-04 1.2896e-04 1.6824e-04 -6.0000e+00 1.4966e-02 -9.3902e-05 1.8204e-04 12 8 8 10 0 0 98.80 20.46 0.40 -0.00009 -0.00090 95 18 1 5 0 532.950 23.11 15.00 20.46 26.12 26.8 1075.88 -28774 -261865 900000 -230441 900000 -230739 900000 -178874 -119978 -156335 -76490 -121094 -130788 -36922 -69221 -64100 -34440 71405 -57280 18657 -65511 23284 -46005 -12113 -21894 -21690 -21230 -40514 -40136 -13348 13652 -23199 45527 -32551 40395 -38279 15171 -19962 22030 -3164 8124 -4958 8110 8625 5951 3317 1918 9916 8122 11616 -5915 11465 5186 12321 1975 10555 984 3019 -1247 5310 3091 2321 7537 8996 5049 2800 8459 506 4722 856 4806 1916 3347 -1118 2130 -1548 2255 -68 63 -164 -1052 -1010 -2697 -1191 -1656 1108 -1697 1251 -803 572 -393 1775 -1205 -404 -666 -675 -423 -117 175 -721 7 -1164 -226 -1477 -970 -1584 -1037 -1394 5 -131 579 -85 158 -55 -62 207 215 480 160 464 -160 412 62 1144 -438 929 62 1065 502 309 66 75 31 -294 -203 -358 298 65 166 -474 152 -92 -452 -121 -5102 900000 -3785 900000 -3438 900000 -1777 -807 -1493 -386 -1069 -1449 -233 -714 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6.0776e-01 6.7271e-02 1.0194e-02 3.7312e-02 -6.0000e+00 6.5594e-01 -1.0753e-01 9.9035e-03 1.9857e-02 -6.0000e+00 3.9017e-01 3.6298e-02 4.6387e-03 6.4421e-03 -6.0000e+00 1.6250e-01 2.1173e-04 6.8720e-05 1.1223e-04 9.5396e-05 -6.0000e+00 1.1931e-02 2.4180e-04 1.5271e-04 11 8 0 10 0 0 99.57 20.31 0.26 0.00024 0.00076 77 14 1 5 0 659.870 23.01 15.00 20.31 26.58 26.7 1079.75 -116673 -36039 -180481 -116671 -203248 900000 -153126 -88101 -121607 -135026 -13941 -134982 -76795 -92372 2644 -41581 49157 -55854 -11364 -28122 30884 -32928 -20686 -39890 -1953 -26023 -22732 -30133 -37989 -17283 -13821 9646 -903 -368 -15558 4466 -12692 7677 -11112 4143 -2410 8277 -3911 4892 -575 7287 8231 -2468 6199 -2272 7162 1721 10277 1201 9874 -141 5779 553 605 -257 3072 36 4226 2625 1990 3296 11 2250 177 2107 1331 2475 -450 1442 -992 -380 -3420 -1425 -2871 -184 -1306 -1532 -1914 -2269 -585 -397 714 -117 1023 259 1646 8 427 -131 971 -123 412 490 -1 -289 -573 -518 -1346 272 -1460 -1456 -1318 -384 -260 703 -102 300 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