File name: Pandora186s1_MadisonCT_20240629_L2Fit_fout2c2d20210922p1-8.txt File generation date: 20240630T050152.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 186 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora186_OF_v4d20210803.txt Instrument calibration file used: Pandora186s1_CF_v2d20210922.txt Level 1 file used: Pandora186s1_MadisonCT_20240629_L1_smca1c2d20210922p1-8.txt Full location name: Madison - Hammonasset State Park CTDEEP (USEPA AQS ID 09-009-9002) Short location name: MadisonCT Country of location: USA Location latitude [deg]: 41.2568 Location longitude [deg]: -72.5533 Location altitude [m]: 3 Local noon date: 20240629 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0092 305.1504 305.2917 305.4329 305.5741 305.7153 305.8565 305.9977 306.1389 306.2800 306.4212 306.5623 306.7034 306.8445 306.9856 307.1267 307.2678 307.4089 307.5499 307.6909 307.8320 307.9730 308.1140 308.2550 308.3960 308.5369 308.6779 308.8189 308.9598 309.1007 309.2416 309.3825 309.5234 309.6643 309.8052 309.9460 310.0869 310.2277 310.3685 310.5093 310.6501 310.7909 310.9317 311.0724 311.2132 311.3539 311.4946 311.6354 311.7761 311.9167 312.0574 312.1981 312.3387 312.4794 312.6200 312.7606 312.9012 313.0418 313.1824 313.3230 313.4636 313.6041 313.7447 313.8852 314.0257 314.1662 314.3067 314.4472 314.5876 314.7281 314.8685 315.0090 315.1494 315.2898 315.4302 315.5706 315.7109 315.8513 315.9917 316.1320 316.2723 316.4126 316.5529 316.6932 316.8335 316.9738 317.1140 317.2543 317.3945 317.5347 317.6749 317.8151 317.9553 318.0955 318.2356 318.3758 318.5159 318.6560 318.7961 318.9362 319.0763 319.2164 319.3565 319.4965 319.6366 319.7766 319.9166 320.0566 320.1966 320.3366 320.4765 320.6165 320.7565 320.8964 321.0363 321.1762 321.3161 321.4560 321.5959 321.7357 321.8756 322.0154 322.1552 322.2950 322.4348 322.5746 322.7144 322.8542 322.9939 323.1337 323.2734 323.4131 323.5528 323.6925 323.8322 323.9719 324.1115 324.2512 324.3908 324.5304 324.6700 324.8096 324.9492 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240629T172831.0Z 8946.728136 446 1 1.97 2 19.49 204.50 85.98 276.40 0.00 1 0.00 1 0 17 7.106e-03 5.939e-03 2.497e-03 1.919e-03 1.510984e-01 1.035262e-03 1.823884e-03 -6.000000e+00 4.280442e-03 232.94 -2.00 3.52 -2.00 314.28 0.00e+00 1.695982e-04 7.902877e-05 1.585362e-05 -6.000000e+00 1.899643e-04 287.94 -2.00 20.00 -2.00 313.68 0.00e+00 1.061 0.000 302.00 328.00 3 3.2362e+00 2.6653e-03 1.3323e-02 -6.0000e+00 1.0741e-02 1.6300e-02 2.9374e-03 7.9016e-03 -6.0000e+00 1.1591e-02 -9.1892e-04 1.6814e-03 3.8229e-03 -6.0000e+00 6.9049e-03 -2.5893e-03 7.1201e-04 1.0424e-03 -6.0000e+00 2.8799e-03 6.3174e-03 3.2160e-04 5.8144e-05 1.5847e-05 -6.0000e+00 2.1113e-04 9.7155e-04 1.7173e-04 12 1 1 12 1 1 20.41 20.06 0.30 0.00097 0.00339 6 35 1 5 0 270.860 22.80 14.98 20.06 28.12 26.9 1090.87 97 -144 -1311 -2445 -1065 378 375 562 21 198 -952 -20 549 -52 -604 412 -287 212 365 495 846 771 1681 588 1035 -10 -252 -332 504 458 1662 1058 1448 -589 -1728 -1969 -1313 -610 -773 -990 -506 -1095 -950 -400 -80 -66 -678 -343 -761 -26 367 772 870 1127 636 871 562 661 530 661 691 1202 1250 907 263 -397 -196 -452 424 506 355 -94 -5 265 -385 -169 -153 -328 -422 -364 -998 -892 -1858 -1491 -1206 -473 -711 -35 297 63 135 151 412 587 803 521 679 460 142 -447 -169 -508 -193 5 -390 -1092 -507 -499 -71 389 282 245 27 -21 -113 819 524 613 325 36 -122 66 4 -71 275 519 391 793 832 -31 371 -305 -336 121 -40 -222 -93 95 -179 -275 -20 -211 -564 40 -61 -578 -1044 -432 139 138 224 9 86 -420 -9 247 -26 -314 229 -157 118 206 286 497 452 978 356 650 -6 -156 -207 289 264 947 632 851 -362 -1032 -1204 -787 -412 -551 -780 -416 -951 -844 -357 -71 -58 -584 -283 -637 -21 304 638 753 1013 564 781 512 601 477 590 631 1152 1225 934 271 -383 -181 -415 397 499 367 -98 -5 272 -392 -163 -139 -292 -377 -337 -982 -918 -1974 -1658 -1367 -549 -874 -42 363 78 162 171 440 592 826 555 762 543 177 -558 -199 -582 -219 6 -470 -1353 -630 -645 -92 524 381 331 36 -27 -140 973 616 748 409 47 -165 89 5 -90 341 633 455 949 995 -38 470 -397 -426 158 -53 -309 -130 134 -256 -388 -29 -291 -768 SS 20240629T173844.8Z 8946.735240 449 1 51.33 2 20.39 210.88 87.79 278.05 0.00 1 0.00 1 0 17 1.158e-02 7.664e-03 7.139e-03 3.717e-03 1.620945e-01 1.960436e-03 1.938387e-03 -6.000000e+00 6.973691e-03 232.94 -2.00 3.52 -2.00 316.10 0.00e+00 7.460030e-04 2.123892e-04 3.539235e-05 -6.000000e+00 3.095172e-04 287.94 -2.00 20.00 -2.00 315.31 0.00e+00 1.067 0.000 302.00 328.00 3 6.6194e+00 5.1409e-03 1.3764e-02 -6.0000e+00 1.7499e-02 5.3427e-02 5.7204e-03 8.5306e-03 -6.0000e+00 1.8885e-02 -2.0873e-03 3.2660e-03 4.1083e-03 -6.0000e+00 1.1250e-02 -2.2340e-03 1.4615e-03 1.2084e-03 -6.0000e+00 4.6917e-03 2.0449e-04 2.8445e-04 1.1540e-04 1.5124e-05 -6.0000e+00 3.4401e-04 -4.9093e-04 8.8876e-05 11 8 0 10 0 0 99.98 20.02 0.40 -0.00049 0.00165 31 6 1 5 0 1655.410 22.80 15.00 20.02 28.63 26.8 1094.47 2177 -1901 1200 -4442 2217 -2477 2430 -1103 -1007 -1285 -1384 -1063 358 -611 -3286 -25 -1706 1431 244 2957 660 2653 237 1586 -827 469 728 -361 -1002 -891 -821 -797 2722 -625 381 -2652 -953 -2204 442 -566 -802 -140 218 679 -134 -344 -1249 -419 -740 70 -1094 1158 784 1523 -194 1967 20 825 269 1028 669 1475 1636 1643 450 -680 -298 -479 782 -426 770 154 599 -200 396 -944 -731 -2423 -1526 -2027 -1465 -1499 -2163 -1192 -1090 163 -28 786 345 1130 -378 648 -630 172 -78 -34 739 888 255 17 130 -1376 -587 -810 -207 -878 -367 -759 226 188 1309 357 461 -376 -45 -41 -342 81 -237 873 -609 377 -49 862 -279 420 145 953 162 582 401 -459 -147 76 131 -318 224 -362 587 -194 -104 -832 -257 463 -459 289 -1085 461 -498 468 -238 -238 -322 -348 -265 93 -176 -1077 -9 -623 517 92 1108 258 1016 93 634 -351 202 314 -151 -392 -332 -308 -313 1090 -264 154 -1064 -395 -1043 238 -354 -550 -100 159 498 -99 -253 -907 -292 -501 46 -747 813 578 1158 -153 1551 16 665 215 814 544 1254 1478 1552 429 -615 -248 -382 634 -382 743 157 612 -201 375 -831 -585 -1845 -1161 -1678 -1327 -1472 -2266 -1295 -1252 197 -35 1022 453 1434 -457 716 -647 168 -78 -36 852 1107 335 22 162 -1635 -665 -941 -254 -1145 -496 -1066 326 283 2014 554 693 -534 -60 -51 -420 102 -319 1234 -898 550 -71 1188 -371 531 176 1141 203 759 542 -636 -206 109 197 -500 360 -594 961 -315 -166 -1297 -393 SS 20240629T174727.3Z 8946.741289 452 1 6.49 2 21.29 215.91 89.33 279.46 0.00 1 0.00 1 0 17 7.024e-03 5.789e-03 1.858e-03 1.384e-03 1.519515e-01 7.443489e-04 1.825759e-03 -6.000000e+00 4.230261e-03 232.94 -2.00 3.52 -2.00 314.47 0.00e+00 1.874728e-04 5.855820e-05 1.750157e-05 -6.000000e+00 1.877623e-04 287.94 -2.00 20.00 -2.00 313.85 0.00e+00 1.073 0.000 302.00 328.00 3 3.8272e+00 1.9189e-03 1.3438e-02 -6.0000e+00 1.0615e-02 1.4646e-02 2.1172e-03 7.9270e-03 -6.0000e+00 1.1456e-02 -1.5986e-04 1.2103e-03 3.8339e-03 -6.0000e+00 6.8242e-03 -2.7520e-03 5.1501e-04 1.0469e-03 -6.0000e+00 2.8458e-03 3.4506e-03 2.1811e-04 4.1993e-05 1.5573e-05 -6.0000e+00 2.0870e-04 8.6185e-05 8.9610e-05 12 1 1 12 1 1 95.41 20.01 0.29 0.00009 0.00173 13 20 1 5 0 462.770 22.80 15.00 20.01 28.87 26.9 1096.37 -86 -797 -435 -1778 -2281 -480 -23 557 631 84 -402 -547 -353 -206 187 -185 -336 260 586 470 722 1335 1386 910 662 547 -90 -494 406 485 1573 1246 1548 -183 -1725 -1334 -1444 -1008 -159 -570 -1087 -1109 -853 -476 -537 -516 -716 -705 -446 276 452 690 911 1172 627 726 1039 544 476 624 1079 1189 1050 505 186 -239 -81 -220 357 438 245 -27 -54 39 282 175 -297 -407 -61 -205 -998 -1442 -1794 -1670 -1163 -546 -223 -260 35 70 93 37 180 444 543 428 606 587 219 -379 -353 -454 -409 151 -390 -786 -542 -468 16 403 370 130 -136 32 141 602 673 538 276 168 -119 -69 114 52 395 485 408 889 566 522 88 -335 -295 -77 -56 -229 -52 72 -199 -261 -17 -316 -482 -33 -323 -179 -718 -861 -168 -8 207 252 35 -169 -229 -153 -95 93 -97 -181 141 323 264 409 754 785 528 395 334 -55 -295 230 265 854 699 897 -109 -1011 -761 -853 -644 -112 -441 -896 -940 -733 -411 -463 -443 -607 -585 -362 221 366 574 780 1026 561 655 943 495 430 563 985 1121 1030 511 188 -233 -75 -198 326 423 250 -28 -58 41 285 168 -268 -353 -53 -187 -974 -1485 -1921 -1839 -1324 -644 -270 -323 43 85 109 41 191 455 564 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