File name: Pandora186s1_MadisonCT_20250217_L2Fit_fout2c2d20210922p1-8.txt File generation date: 20250218T051729.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 186 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora186_OF_v4d20210803.txt Instrument calibration file used: Pandora186s1_CF_v2d20210922.txt Level 1 file used: Pandora186s1_MadisonCT_20250217_L1_smca1c2d20210922p1-8.txt Full location name: Madison - Hammonasset State Park CTDEEP (USEPA AQS ID 09-009-9002) Short location name: MadisonCT Country of location: USA Location latitude [deg]: 41.2568 Location longitude [deg]: -72.5533 Location altitude [m]: 3 Local noon date: 20250217 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0092 305.1504 305.2917 305.4329 305.5741 305.7153 305.8565 305.9977 306.1389 306.2800 306.4212 306.5623 306.7034 306.8445 306.9856 307.1267 307.2678 307.4089 307.5499 307.6909 307.8320 307.9730 308.1140 308.2550 308.3960 308.5369 308.6779 308.8189 308.9598 309.1007 309.2416 309.3825 309.5234 309.6643 309.8052 309.9460 310.0869 310.2277 310.3685 310.5093 310.6501 310.7909 310.9317 311.0724 311.2132 311.3539 311.4946 311.6354 311.7761 311.9167 312.0574 312.1981 312.3387 312.4794 312.6200 312.7606 312.9012 313.0418 313.1824 313.3230 313.4636 313.6041 313.7447 313.8852 314.0257 314.1662 314.3067 314.4472 314.5876 314.7281 314.8685 315.0090 315.1494 315.2898 315.4302 315.5706 315.7109 315.8513 315.9917 316.1320 316.2723 316.4126 316.5529 316.6932 316.8335 316.9738 317.1140 317.2543 317.3945 317.5347 317.6749 317.8151 317.9553 318.0955 318.2356 318.3758 318.5159 318.6560 318.7961 318.9362 319.0763 319.2164 319.3565 319.4965 319.6366 319.7766 319.9166 320.0566 320.1966 320.3366 320.4765 320.6165 320.7565 320.8964 321.0363 321.1762 321.3161 321.4560 321.5959 321.7357 321.8756 322.0154 322.1552 322.2950 322.4348 322.5746 322.7144 322.8542 322.9939 323.1337 323.2734 323.4131 323.5528 323.6925 323.8322 323.9719 324.1115 324.2512 324.3908 324.5304 324.6700 324.8096 324.9492 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250217T123807.1Z 9179.526471 251 1 50.59 2 80.88 114.58 79.34 243.14 0.00 1 0.00 1 0 17 6.680e-01 1.926e-02 3.748e-01 1.149e-02 9.409679e-01 7.046169e-03 1.015422e-02 -6.000000e+00 4.072414e-01 224.97 -2.00 3.52 -2.00 322.18 0.00e+00 1.349958e-02 4.035264e-03 2.570616e-03 -6.000000e+00 2.210421e-02 275.16 -2.00 20.00 -2.00 321.76 0.00e+00 5.988 0.004 302.00 328.00 3 1.9994e+00 2.6659e-02 8.3595e-02 -6.0000e+00 1.0211e+00 6.0863e-01 4.1432e-02 6.9099e-02 -6.0000e+00 1.1244e+00 -7.5752e-01 4.5847e-02 3.0520e-02 -6.0000e+00 6.5140e-01 3.0822e-01 2.0732e-02 1.6338e-02 -6.0000e+00 2.6906e-01 6.2508e-05 -1.5517e-03 3.4243e-04 2.2249e-04 -6.0000e+00 2.1116e-02 5.1509e-03 5.4649e-05 12 8 8 10 0 0 99.98 19.61 0.51 0.00515 -0.00651 144 27 1 5 0 350.870 22.29 15.00 19.61 3.30 27.0 907.20 -238338 900000 -108679 900000 900000 900000 900000 179202 900000 900000 900000 -245845 900000 -200296 900000 -162019 900000 -142319 900000 -143474 900000 -114327 14760 -7721 -32757 87113 -127621 900000 -81289 117415 -107555 900000 15533 900000 -42094 900000 13386 82621 6361 254087 33264 15067 19204 -10184 77764 -30587 76519 2508 272183 -7395 137040 26870 39142 21511 43161 33580 18143 5559 -521 14799 -1260 18326 8724 26666 3786 28092 6613 38843 5855 20063 -5103 17559 405 935 -343 2835 6614 -1349 10378 -1523 12491 -3401 5196 -7533 3105 -2865 2318 -2984 5835 739 3057 3515 -244 1207 -3441 -112 -2048 982 -1782 743 -3184 341 -3888 -142 -3823 -344 -2949 -838 -2678 -295 91 -1697 613 -1406 293 -1614 1761 -165 2188 -716 1943 -142 3003 545 722 354 89 726 -18 1017 750 675 -1159 -1 -761 1032 -342 907 -644 583 -846 -83 -970 -2662 900000 -1214 900000 900000 900000 900000 2002 900000 900000 900000 -3956 900000 -3789 900000 -3668 900000 -3619 900000 -4217 900000 -2519 165 -86 -366 973 -3389 900000 -1425 1311 -3393 900000 234 900000 -1204 900000 230 923 154 2838 822 477 620 -450 1554 -1734 1679 117 3040 -447 2407 1485 2133 1498 2613 2293 1450 493 -47 1137 -115 1527 914 2723 527 3216 947 4337 977 3317 -1179 3411 91 196 -66 477 1017 -233 1840 -365 3133 -1149 1802 -3161 1246 -1283 1030 -1431 2564 330 1261 1373 -98 508 -1736 -65 -1438 780 -1610 671 -2836 265 -2823 -96 -2790 -257 -2397 -726 -2649 -327 115 -2365 866 -2015 401 -2197 2342 -233 3150 -1082 2794 -198 3876 696 891 427 106 922 -26 1706 1419 1392 -2605 -2 -1939 2702 -923 2428 -1726 1472 -2014 -181 -2068 SS 20250217T124933.3Z 9179.534413 256 1 40.83 2 78.94 116.63 81.26 245.11 0.00 1 0.00 1 0 25 6.911e-01 1.198e-02 3.124e-01 5.091e-03 8.073525e-01 2.858477e-03 8.804947e-03 -6.000000e+00 4.037665e-01 224.97 -2.00 3.52 -2.00 321.74 0.00e+00 7.386036e-03 1.492888e-03 3.289816e-03 -6.000000e+00 1.799655e-02 275.16 -2.00 20.00 -2.00 321.29 0.00e+00 5.028 0.002 302.00 328.00 3 1.8697e+00 9.9907e-03 7.0328e-02 -6.0000e+00 1.0002e+00 2.7181e-01 1.4882e-02 5.5421e-02 -6.0000e+00 1.0896e+00 -3.0713e-01 1.6517e-02 2.4694e-02 -6.0000e+00 6.4647e-01 1.1957e-01 7.6655e-03 1.0699e-02 -6.0000e+00 2.6993e-01 2.1502e-04 -1.8245e-03 1.4768e-04 1.1672e-04 -6.0000e+00 2.0489e-02 7.9986e-03 -1.2469e-04 12 9 9 12 1 1 100.00 19.62 0.32 0.00800 -0.00571 198 46 1 5 0 205.160 22.40 14.99 19.62 3.47 27.1 909.27 -147518 -193693 -205763 -19967 -236003 -195981 -190470 -99082 -237514 900000 -242356 255776 -214480 190871 -146164 77596 -88161 -41842 -79047 194111 -18574 -50310 25179 -69496 96669 -80678 68514 -83308 64964 -87513 39201 -40595 19538 -25648 12058 -21762 -12353 546 -9696 30320 8650 19757 486 38849 2907 22498 -6266 26291 -4865 19937 9912 16823 7352 10201 5481 6397 8752 2429 10144 -2822 13818 -199 9834 2586 10513 1748 4514 2202 3239 6706 2857 2931 723 4574 2118 3358 -2758 3088 -3462 3345 -2395 -1708 -2357 -919 -1967 -115 -585 1074 3 629 1961 -106 -338 -1581 -96 -2160 1482 -790 619 -1586 409 -1425 -500 -1301 -420 -1841 -1210 -217 -871 223 -373 269 -581 855 -776 331 -413 290 134 390 -484 716 676 309 704 603 585 440 1561 -141 259 -424 580 -541 195 -265 207 212 29 144 -62 -293 -946 -732 -1451 -1929 -99 -2851 -1565 -1482 -492 -3420 900000 -4235 1270 -4208 947 -2640 385 -1369 -479 -1403 964 -205 -752 190 -1345 480 -1929 420 -2102 420 -2558 429 -1141 374 -814 272 -663 -368 17 -386 986 390 874 27 1592 170 1134 -428 1403 -369 1308 794 1420 750 1106 663 799 1099 323 1226 -378 1627 -29 1498 481 1969 362 921 480 767 1746 853 915 229 1317 571 810 -666 724 -972 1048 -938 -764 -1174 -483 -1108 -68 -361 668 2 380 1103 -57 -180 -894 -60 -1611 1247 -779 657 -1744 419 -1348 -428 -1099 -368 -1728 -1197 -229 -1023 293 -547 419 -931 1330 -1179 484 -610 442 214 635 -784 1098 997 443 969 807 770 612 2419 -251 508 -896 1285 -1284 488 -693 550 567 78 365 -148 -663 -2091 SS 20250217T125515.9Z 9179.538378 259 1 2.16 2 77.98 117.67 82.23 246.08 0.00 1 0.00 1 0 17 4.591e-01 1.332e-02 2.653e-01 7.705e-03 7.461577e-01 4.106499e-03 8.419270e-03 -6.000000e+00 2.684272e-01 224.97 -2.00 3.52 -2.00 320.72 0.00e+00 3.627360e-03 1.687484e-03 1.932572e-03 -6.000000e+00 1.164003e-02 275.16 -2.00 20.00 -2.00 320.23 0.00e+00 4.658 0.002 302.00 328.00 3 1.5584e+00 1.2518e-02 6.0631e-02 -6.0000e+00 6.6369e-01 2.1538e-01 1.6434e-02 3.9365e-02 -6.0000e+00 7.2209e-01 -2.3472e-01 1.6746e-02 2.2443e-02 -6.0000e+00 4.2960e-01 8.9534e-02 8.2658e-03 8.8772e-03 -6.0000e+00 1.7982e-01 4.5059e-04 1.9790e-04 2.0993e-04 1.1724e-04 -6.0000e+00 1.3605e-02 2.5339e-03 2.3019e-04 12 9 9 12 1 1 71.09 19.61 0.26 0.00253 0.00402 5 26 1 5 0 358.530 22.40 15.00 19.61 3.59 27.0 910.82 -131264 -42110 -7910 -206068 -111458 -206195 -85149 -176821 -86789 -215013 -117979 -124029 -103361 -70228 -21959 -60244 -71896 -52355 -50737 31635 -70155 -5464 -8813 -16663 -55196 40233 1246 -893 -39713 -24883 -16616 9983 4404 -22925 39457 -5281 2731 -22037 12648 -10398 16034 17770 931 10772 1740 4608 18149 4350 4730 10428 -1005 10707 3712 10228 4491 13728 -1064 8709 950 2110 1116 2574 9023 6601 3876 2596 1789 -166 1419 -975 3175 286 2829 -596 -1495 -1313 -65 -3918 -666 -465 -2018 -1209 -744 -3200 -2023 196 -1387 806 -303 -29 -1269 1280 -1692 -925 -573 -34 518 -241 -172 42 373 -1241 -594 -42 -605 -1366 -158 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