File name: Pandora186s1_MadisonCT_20250306_L2Fit_ffuh5c2d20210922p1-8.txt
File generation date: 20250307T050936.2Z
Data description: Level 2 spectral fitting results file
Data file version: ffuh5c2p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 186
Spectrometer number: 1
Processing software version used: BlickP v1.8.74
Instrument operation file used: Pandora186_OF_v4d20210803.txt
Instrument calibration file used: Pandora186s1_CF_v2d20210922.txt
Level 1 file used: Pandora186s1_MadisonCT_20250306_L1_smca1c2d20210922p1-8.txt
Full location name: Madison - Hammonasset State Park CTDEEP (USEPA AQS ID 09-009-9002)
Short location name: MadisonCT
Country of location: USA
Location latitude [deg]: 41.2568
Location longitude [deg]: -72.5533
Location altitude [m]: 3
Local noon date: 20250306
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 365 585
Nominal wavelengths inside fitting window [nm]: 328.5741 328.7134 328.8526 328.9919 329.1311 329.2703 329.4095 329.5487 329.6879 329.8270 329.9662 330.1053 330.2444 330.3835 330.5226 330.6617 330.8008 330.9399 331.0789 331.2179 331.3570 331.4960 331.6350 331.7740 331.9129 332.0519 332.1909 332.3298 332.4687 332.6076 332.7465 332.8854 333.0243 333.1632 333.3020 333.4409 333.5797 333.7185 333.8573 333.9961 334.1349 334.2737 334.4124 334.5512 334.6899 334.8286 334.9673 335.1060 335.2447 335.3834 335.5220 335.6607 335.7993 335.9379 336.0765 336.2151 336.3537 336.4923 336.6308 336.7694 336.9079 337.0464 337.1849 337.3234 337.4619 337.6004 337.7388 337.8773 338.0157 338.1541 338.2925 338.4309 338.5693 338.7077 338.8460 338.9844 339.1227 339.2610 339.3994 339.5377 339.6759 339.8142 339.9525 340.0907 340.2290 340.3672 340.5054 340.6436 340.7818 340.9199 341.0581 341.1962 341.3344 341.4725 341.6106 341.7487 341.8868 342.0249 342.1629 342.3010 342.4390 342.5770 342.7150 342.8530 342.9910 343.1290 343.2669 343.4049 343.5428 343.6807 343.8187 343.9566 344.0944 344.2323 344.3702 344.5080 344.6458 344.7837 344.9215 345.0593 345.1971 345.3348 345.4726 345.6103 345.7481 345.8858 346.0235 346.1612 346.2989 346.4365 346.5742 346.7118 346.8495 346.9871 347.1247 347.2623 347.3999 347.5374 347.6750 347.8125 347.9501 348.0876 348.2251 348.3626 348.5000 348.6375 348.7750 348.9124 349.0498 349.1873 349.3247 349.4620 349.5994 349.7368 349.8741 350.0115 350.1488 350.2861 350.4234 350.5607 350.6980 350.8353 350.9725 351.1097 351.2470 351.3842 351.5214 351.6586 351.7957 351.9329 352.0700 352.2072 352.3443 352.4814 352.6185 352.7556 352.8927 353.0297 353.1668 353.3038 353.4408 353.5778 353.7148 353.8518 353.9888 354.1257 354.2627 354.3996 354.5365 354.6734 354.8103 354.9472 355.0841 355.2209 355.3578 355.4946 355.6314 355.7682 355.9050 356.0418 356.1785 356.3153 356.4520 356.5887 356.7254 356.8621 356.9988 357.1355 357.2722 357.4088 357.5454 357.6821 357.8187 357.9553 358.0918 358.2284 358.3650 358.5015 358.6380 358.7746 358.9111
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Formaldehyde slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of formaldehyde slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Formaldehyde effective temperature [K]
Column 28: Independent uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective formaldehyde fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for formaldehyde [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful
Column 45: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Oxygen dimer effective temperature [K]
Column 50: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 56: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 57: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 58: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 59: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 60: Ozone effective temperature [K]
Column 61: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 62: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 63: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 64: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 65: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 66: Fitted Ring spectrum, -9e99=no fitting done or fitting not successful
Column 67: Independent uncertainty of fitted Ring spectrum, -9=fitting not successful
Column 68: Structured uncertainty of fitted Ring spectrum, -9=fitting not successful
Column 69: Common uncertainty of fitted Ring spectrum, -9=fitting not successful
Column 70: rms-based uncertainty of fitted Ring spectrum, -9=fitting not successful
Column 71: Effective Ring fitting wavelength [nm], -9=fitting not done or not successful
Column 72: Diffuse correction applied before fitting at effective Ring fitting wavelength [%], 0=no diffuse correction applied, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 73: Lower limit used for wavelength scaling [nm]
Column 74: Upper limit used for wavelength scaling [nm]
Column 75: Order of smoothing polynomial
Column 76: Smoothing polynomial coefficient, order 0
Column 77: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 78: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 79: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 80: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 81: Smoothing polynomial coefficient, order 1
Column 82: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 83: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 84: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 85: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 86: Smoothing polynomial coefficient, order 2
Column 87: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 88: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 89: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 90: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 91: Smoothing polynomial coefficient, order 3
Column 92: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 93: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 94: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 95: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 96: Smoothing polynomial coefficient, order 4
Column 97: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful
Column 98: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful
Column 99: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful
Column 100: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful
Column 101: Mean value of measured data inside fitting window [same units as measurements]
Column 102: Offset polynomial coefficient, order 0
Column 103: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful
Column 104: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful
Column 105: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful
Column 106: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful
Column 107: Offset polynomial coefficient, order 1
Column 108: Independent uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful
Column 109: Structured uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful
Column 110: Common uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful
Column 111: rms-based uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful
Column 112: Wavelength change polynomial coefficient, order 0
Column 113: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 114: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 115: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 116: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 117: Wavelength change polynomial coefficient, order 1
Column 118: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful
Column 119: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful
Column 120: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful
Column 121: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful
Column 122: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 123: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 124: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 125: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 126: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 127: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 128: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 129: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 130: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 131: Wavelength effective temperature [°C], 999=no effective temperature given
Column 132: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 133: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 134: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 135: Number of bright count cycles
Column 136: Number of dark count cycles
Column 137: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 138: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 139: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 140: Integration time [ms]
Column 141: Temperature at electronics board [°C], 999=no temperature signal
Column 142: Spectrometer control temperature [°C], 999=no temperature signal
Column 143: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 144: Temperature in head sensor [°C], 999=no temperature signal
Column 145: Humidity in head sensor [%], -9=no humidity signal
Column 146: Pressure in head sensor [hPa], -9=no pressure signal
Columns 147-367: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 368-588: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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