File name: Pandora186s1_MadisonCT_20250507_L2Fit_fout2c2d20210922p1-8.txt File generation date: 20250508T051600.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 186 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora186_OF_v4d20210803.txt Instrument calibration file used: Pandora186s1_CF_v2d20210922.txt Level 1 file used: Pandora186s1_MadisonCT_20250507_L1_smca1c2d20210922p1-8.txt Full location name: Madison - Hammonasset State Park CTDEEP (USEPA AQS ID 09-009-9002) Short location name: MadisonCT Country of location: USA Location latitude [deg]: 41.2568 Location longitude [deg]: -72.5533 Location altitude [m]: 3 Local noon date: 20250507 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0092 305.1504 305.2917 305.4329 305.5741 305.7153 305.8565 305.9977 306.1389 306.2800 306.4212 306.5623 306.7034 306.8445 306.9856 307.1267 307.2678 307.4089 307.5499 307.6909 307.8320 307.9730 308.1140 308.2550 308.3960 308.5369 308.6779 308.8189 308.9598 309.1007 309.2416 309.3825 309.5234 309.6643 309.8052 309.9460 310.0869 310.2277 310.3685 310.5093 310.6501 310.7909 310.9317 311.0724 311.2132 311.3539 311.4946 311.6354 311.7761 311.9167 312.0574 312.1981 312.3387 312.4794 312.6200 312.7606 312.9012 313.0418 313.1824 313.3230 313.4636 313.6041 313.7447 313.8852 314.0257 314.1662 314.3067 314.4472 314.5876 314.7281 314.8685 315.0090 315.1494 315.2898 315.4302 315.5706 315.7109 315.8513 315.9917 316.1320 316.2723 316.4126 316.5529 316.6932 316.8335 316.9738 317.1140 317.2543 317.3945 317.5347 317.6749 317.8151 317.9553 318.0955 318.2356 318.3758 318.5159 318.6560 318.7961 318.9362 319.0763 319.2164 319.3565 319.4965 319.6366 319.7766 319.9166 320.0566 320.1966 320.3366 320.4765 320.6165 320.7565 320.8964 321.0363 321.1762 321.3161 321.4560 321.5959 321.7357 321.8756 322.0154 322.1552 322.2950 322.4348 322.5746 322.7144 322.8542 322.9939 323.1337 323.2734 323.4131 323.5528 323.6925 323.8322 323.9719 324.1115 324.2512 324.3908 324.5304 324.6700 324.8096 324.9492 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250507T104647.1Z 9258.449156 128 1 50.20 2 78.92 77.09 124.28 314.98 0.00 1 0.00 1 0 17 5.574e-01 1.651e-02 3.284e-01 9.259e-03 7.386449e-01 5.254979e-03 8.340714e-03 -6.000000e+00 3.344642e-01 230.41 -2.00 3.52 -2.00 321.51 0.00e+00 7.356499e-03 2.730878e-03 1.759011e-03 -6.000000e+00 1.547777e-02 282.54 -2.00 20.00 -2.00 320.97 0.00e+00 5.018 0.002 302.00 328.00 3 3.2669e+00 1.8678e-02 6.4461e-02 -6.0000e+00 8.3586e-01 3.9284e-01 2.5321e-02 4.0693e-02 -6.0000e+00 9.0593e-01 -3.9611e-01 2.4772e-02 2.2605e-02 -6.0000e+00 5.3671e-01 1.4709e-01 1.1636e-02 1.0417e-02 -6.0000e+00 2.2418e-01 5.3552e-05 -5.0971e-04 2.7537e-04 1.5264e-04 -6.0000e+00 1.6587e-02 4.7824e-03 1.6607e-04 12 8 8 10 0 0 99.96 19.81 0.38 0.00478 0.00095 31 6 1 5 0 1618.800 22.50 15.01 19.81 16.31 28.8 1028.33 -242720 900000 -187243 262304 -252622 900000 -179007 -171439 -147717 900000 -140167 -57109 -68839 44535 42107 -77099 87834 39910 89910 -19722 5116 -66224 24643 -69846 900000 21304 18962 -7245 36945 -62998 18024 41697 38782 13217 -26164 14172 -24098 116032 -9310 56991 2157 27227 11380 42108 27963 7598 15859 -6124 17677 2810 25518 5108 25463 -802 20393 9710 15454 1913 8748 2537 10404 7200 9260 6488 3702 9294 5680 7162 2245 6188 -842 3380 -4197 3640 -3282 -1887 -4611 -5229 -2948 -2230 -131 -1240 973 -623 139 -2863 706 -1415 1054 -850 1172 -2488 -629 -1996 1336 -594 2048 -12 -583 -69 -1300 -88 -1956 1022 -3459 -748 -2333 158 -1908 1217 -1731 1314 -1180 701 568 -353 -1147 125 320 -271 1092 1269 1616 -218 1440 -598 1531 756 286 1319 786 279 -164 -293 -420 -366 -362 488 -131 675 -272 -149 -1252 -5603 900000 -3427 2367 -8110 900000 -2758 -2638 -1977 900000 -1967 -515 -676 402 380 -1665 793 370 811 -368 77 -1957 314 -2267 900000 322 298 -145 486 -2276 358 802 895 422 -1209 439 -1133 1670 -517 1994 143 1543 790 2267 1757 593 1180 -585 1417 278 2242 609 2747 -121 2659 1457 2245 316 1318 399 1554 1207 1722 1398 881 2111 1332 1710 612 1839 -296 1196 -1590 1211 -1070 -549 -1288 -1488 -912 -808 -55 -598 507 -352 83 -1862 465 -978 711 -566 721 -1492 -359 -1194 862 -451 1760 -12 -639 -77 -1382 -84 -1750 876 -3251 -725 -2424 172 -2324 1606 -2597 2036 -1899 1084 845 -512 -1683 188 504 -443 1747 1956 2391 -317 1988 -815 2007 1043 442 2260 1486 565 -351 -666 -1013 -921 -930 1255 -337 1660 -637 -329 -2724 SS 20250507T112926.7Z 9258.478781 150 1 50.60 2 71.01 83.77 129.34 326.13 0.00 1 0.00 1 0 17 1.654e-01 7.730e-03 1.625e-01 6.637e-03 4.686790e-01 3.531560e-03 5.359097e-03 -6.000000e+00 9.876646e-02 230.41 -2.00 3.52 -2.00 319.99 0.00e+00 9.853511e-04 1.140043e-03 5.010299e-04 -6.000000e+00 4.334462e-03 282.54 -2.00 20.00 -2.00 319.32 0.00e+00 3.036 0.000 302.00 328.00 3 5.2003e+00 1.0353e-02 3.9327e-02 -6.0000e+00 2.4674e-01 1.0499e-01 1.2480e-02 2.4715e-02 -6.0000e+00 2.6717e-01 -2.3701e-02 1.0408e-02 1.2442e-02 -6.0000e+00 1.5882e-01 -3.0811e-03 5.3307e-03 3.8406e-03 -6.0000e+00 6.6600e-02 7.4218e-05 4.3692e-04 2.0898e-04 4.6542e-05 -6.0000e+00 4.9432e-03 1.7226e-03 2.6299e-04 11 8 0 10 0 0 99.98 19.77 0.37 0.00172 0.00501 16 3 1 5 0 3161.960 22.50 15.00 19.77 17.01 28.9 1034.48 900000 -27986 -35588 -10134 5563 -39649 -12558 127186 -10205 93997 -37492 -41365 9505 -7 36615 26074 11872 8197 7085 -16971 21434 -9887 29819 42 -11425 -1589 -2114 -10363 1783 853 -7480 -6100 750 6494 -9333 -1381 -1030 2857 244 5667 -1244 -493 -2121 -2940 -4463 246 -271 141 1454 -498 738 -637 -555 -126 -771 979 6549 738 2388 2060 905 670 1011 1520 345 2182 2894 725 -770 342 -609 970 -1287 1777 -3272 -2028 673 -1494 -1521 400 -2728 -983 -355 -1602 -377 -170 28 772 562 -623 -125 -357 475 1058 -180 350 1266 407 654 -553 -617 163 -347 1614 -611 -29 -1970 61 -1177 973 294 827 -852 -51 296 -120 146 203 -260 159 -202 444 403 -48 745 -543 869 -610 340 41 238 -535 -166 -58 -344 146 -408 406 339 -428 87 472 -413 900000 -469 -693 -156 70 -725 -185 823 -183 694 -999 -1218 199 0 851 781 453 350 327 -1042 944 -597 1264 3 -823 -110 -151 -787 116 57 -589 -539 70 611 -1017 -137 -109 334 35 920 -245 -104 -474 -681 -1060 56 -63 33 339 -123 192 -184 -174 -42 -273 353 2302 276 863 739 336 267 442 721 172 1043 1322 338 -387 190 -378 623 -848 1096 -1973 -1101 328 -724 -781 228 -1829 -724 -283 -1365 -338 -162 28 786 575 -626 -118 -313 390 860 -157 340 1368 493 843 -723 -768 187 -374 1718 -702 -36 -2535 81 -1687 1473 478 1383 -1433 -82 446 -173 209 301 -408 258 -334 715 631 -73 1079 -766 1174 -850 504 66 408 -963 -308 -112 -700 309 -887 888 741 -920 179 929 -804 SS 20250507T120621.5Z 9258.504416 168 1 50.60 2 64.08 89.70 132.66 337.04 0.00 1 0.00 1 0 17 1.935e-02 4.505e-03 5.709e-03 7.118e-04 3.638104e-01 3.684607e-04 4.252069e-03 -6.000000e+00 1.153574e-02 230.42 -2.00 3.52 -2.00 318.82 0.00e+00 6.389162e-04 8.289892e-05 1.706960e-04 -6.000000e+00 5.054753e-04 282.55 -2.00 20.00 -2.00 318.10 0.00e+00 2.274 0.000 302.00 328.00 3 2.4432e+00 1.0168e-03 2.9862e-02 -6.0000e+00 2.8818e-02 3.1829e-02 1.1662e-03 1.9028e-02 -6.0000e+00 3.1199e-02 -1.1524e-02 8.0888e-04 9.3353e-03 -6.0000e+00 1.8562e-02 -2.0463e-03 4.1916e-04 2.6643e-03 -6.0000e+00 7.7322e-03 2.8999e-03 -6.3937e-05 2.2184e-05 3.1451e-05 -6.0000e+00 5.7426e-04 4.1416e-03 8.2771e-05 10 0 0 10 0 0 99.96 19.77 0.27 0.00414 0.00366 327 61 1 5 0 154.710 22.50 15.00 19.77 17.96 29.0 1044.18 -5615 -5979 -5725 -7315 -5695 -9436 -5110 -6493 -4159 -4489 -3079 -6325 -932 -2880 -690 -1703 -714 -10 -17 806 -91 1495 -150 1206 -827 256 -1792 -464 -2057 1090 341 918 624 -324 -2057 -2130 -1085 -1308 -960 -1196 -1192 -1148 -753 -677 -231 -366 -418 -613 -99 -48 942 1212 951 1033 661 1013 911 501 338 850 964 1397 1187 1193 396 97 -21 -74 587 858 372 275 80 -67 165 -335 -128 -466 -340 -420 -854 -1312 -1639 -1561 -797 -771 -316 84 107 231 268 464 254 746 602 580 533 565 82 -185 -418 -623 -323 94 -484 -881 -537 -559 -107 191 205 -46 -5 1 132 362 558 362 233 -73 -245 -77 44 94 195 497 193 901 539 292 9 -230 -261 -88 -221 -137 -40 177 -5 -115 13 -114 -252 -194 -237 -241 -307 -217 -353 -188 -269 -189 -221 -154 -341 -53 -198 -54 -154 -70 -1 -2 91 -11 174 -18 151 -113 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