File name: Pandora135s1_ManhattanNY-CCNY_20200930_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20241023T051933.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v2d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20200930_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20200930 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200930T124043.5Z 7578.528281 791 1 47.02 2 70.83 112.08 125.59 293.18 0.00 1 0.00 1 0 17 1.417e-01 2.860e-02 8.483e-02 6.855e-03 3.330723e-01 3.517611e-03 3.961266e-03 -6.000000e+00 8.187332e-02 227.49 -2.00 3.51 -2.00 319.24 0.00e+00 2.194176e-03 8.857575e-04 6.734386e-04 -6.000000e+00 3.660941e-03 285.93 -2.00 20.00 -2.00 318.49 0.00e+00 3.010 0.000 302.00 328.00 3 5.5277e+00 9.8167e-03 3.4760e-02 -6.0000e+00 2.0314e-01 -2.3326e-02 1.1438e-02 1.8646e-02 -6.0000e+00 2.1969e-01 7.5493e-02 8.3873e-03 8.6005e-03 -6.0000e+00 1.3108e-01 -2.8599e-02 4.4121e-03 3.7397e-03 -6.0000e+00 5.6947e-02 7.0385e-05 5.8900e-05 2.0348e-04 3.2185e-05 -6.0000e+00 3.8666e-03 -6.7193e-04 3.1298e-04 12 8 8 10 0 0 99.99 20.81 0.22 -0.00067 -0.00023 83 23 1 5 0 559.700 25.47 20.01 20.81 21.79 10.0 957.66 54247 -10411 16398 -58793 104371 -46580 25457 -44279 27823 -15071 -20865 -13584 -10325 23999 -20410 7387 -7458 7754 -2712 8783 -7501 7996 1906 2717 -4119 -3742 12824 1526 11367 -12311 13441 -4159 10558 -3929 -781 -1166 866 6968 -8131 2141 -4107 3378 -5115 -123 -676 -442 1593 -1849 1440 2285 -371 -1623 1747 -1062 4965 2213 47 -684 468 2738 4004 4617 -604 2157 845 2034 -465 1593 -533 -1181 -474 -735 1945 -763 2276 -572 1662 -4163 354 -1322 -1705 -1776 -1929 -643 -2071 -188 -501 1339 122 2698 529 3554 -32 -101 -1327 -991 -630 -596 277 -560 1209 -1823 398 -1310 22 -246 209 419 -697 997 -720 558 -960 -156 -485 -647 -1132 -855 -262 -501 695 870 738 1070 265 -355 999 -680 251 -1029 -1384 -540 -1390 19333 -1840 -770 -946 -511 -1371 105 -739 -1224 986 -380 464 -3158 1134 -2029 640 -2357 823 -683 -1017 -676 -588 1203 -1789 543 -678 643 -263 794 -810 742 196 296 -510 -476 1362 173 1131 -1612 1511 -623 1487 -641 -117 -179 147 1337 -2104 573 -1271 1019 -1734 -40 -224 -147 516 -615 465 760 -137 -657 729 -480 2182 1028 23 -328 218 1260 1919 2412 -365 1342 523 1154 -257 876 -333 -810 -348 -555 1407 -539 1480 -344 903 -2388 214 -930 -1357 -1502 -1734 -603 -2115 -201 -566 1512 137 2825 522 3218 -28 -90 -1312 -1058 -751 -783 375 -740 1447 -2059 442 -1514 27 -319 283 596 -1071 1622 -1212 928 -1605 -240 -692 -888 -1590 -1267 -414 -831 1144 1393 1146 1585 377 -500 1341 -966 372 -1663 -2357 -934 -2498 29747 -3596 -1551 -1953 -1067 -2871 216 -1471 -2350 SU 20200930T124315.5Z 7578.530041 802 1 47.01 2 70.39 112.56 126.01 293.72 0.00 1 0.00 1 0 17 6.905e-02 8.276e-03 6.203e-02 5.785e-03 3.525855e-01 2.966809e-03 4.162088e-03 -6.000000e+00 3.985527e-02 227.49 -2.00 3.51 -2.00 319.30 0.00e+00 1.380360e-04 7.619932e-04 1.451043e-04 -6.000000e+00 1.782885e-03 285.93 -2.00 20.00 -2.00 318.55 0.00e+00 2.946 0.000 302.00 328.00 3 4.1155e+00 8.3200e-03 3.4546e-02 -6.0000e+00 9.8887e-02 -3.7697e-03 9.7208e-03 1.8404e-02 -6.0000e+00 1.0696e-01 6.2305e-02 7.2382e-03 9.1159e-03 -6.0000e+00 6.3820e-02 -3.4658e-02 3.8161e-03 2.6447e-03 -6.0000e+00 2.7713e-02 2.9983e-04 5.7328e-04 1.7110e-04 2.8873e-05 -6.0000e+00 1.8836e-03 5.8325e-04 2.0979e-04 11 8 0 10 0 0 99.99 20.81 0.06 0.00058 0.00489 69 19 2 5 0 681.270 25.47 19.97 20.81 21.77 10.0 957.14 -5537 42155 -38960 -5807 19628 -11454 -14052 -634 504 -16884 7877 -11129 29220 -150 -828 -3807 12017 -9604 833 -127 -3706 3266 -3006 4005 -11906 3965 65 16040 1993 -4216 -1094 -617 3621 -5795 -1680 -94 5567 2566 1158 -5602 1603 -1166 -1432 -2411 574 -3541 -1559 -1884 -1752 5623 -2557 2257 -2495 2088 1511 3878 -1118 105 635 134 3923 2576 2378 409 1541 -1440 1739 -236 0 -43 -235 488 -76 -144 700 2079 -1266 -1158 445 455 -1229 -1535 -1267 -460 -1075 -1034 439 -253 694 -645 845 -39 665 977 -172 489 -447 777 67 76 -406 -270 -218 -346 -1000 -176 -949 253 -56 -199 480 -216 204 -838 404 -155 114 67 484 -1114 191 695 -331 2062 -833 61 186 837 252 512 -362 284 282 -566 138 -176 745 -319 127 376 -117 -1201 -161 828 -1665 -172 434 -336 -472 -21 19 -744 288 -522 1121 -9 -57 -297 850 -863 74 -12 -363 302 -312 419 -1502 458 8 1521 211 -493 -138 -86 529 -892 -245 -14 885 489 270 -1605 463 -363 -460 -788 183 -1179 -504 -608 -568 1769 -947 863 -1069 901 679 1755 -539 50 292 62 1851 1351 1370 254 924 -827 924 -131 0 -29 -171 360 -55 -103 453 1191 -696 -638 267 313 -970 -1287 -1124 -428 -1081 -1109 486 -287 768 -685 815 -36 575 861 -168 515 -532 1007 91 98 -488 -308 -242 -408 -1236 -227 -1292 358 -86 -316 796 -361 336 -1294 571 -212 160 100 763 -1860 314 1110 -517 3007 -1194 85 252 1179 376 823 -616 493 506 -1043 268 -358 1534 -675 265 756 -234 -2330 SU 20200930T124624.8Z 7578.532232 814 1 47.66 2 69.84 113.16 126.53 294.40 0.00 1 0.00 1 0 17 3.845e-01 5.538e-02 1.515e-01 1.245e-02 3.485296e-01 6.368163e-03 4.128532e-03 -6.000000e+00 2.218258e-01 227.49 -2.00 3.51 -2.00 318.83 0.00e+00 3.027979e-03 1.432551e-03 7.059584e-04 -6.000000e+00 9.924898e-03 285.93 -2.00 20.00 -2.00 318.08 0.00e+00 2.871 0.000 302.00 328.00 3 6.6944e+00 1.7399e-02 3.3736e-02 -6.0000e+00 5.5038e-01 1.5678e-01 2.0038e-02 1.7992e-02 -6.0000e+00 5.9545e-01 6.7708e-03 1.4098e-02 9.3561e-03 -6.0000e+00 3.5529e-01 -5.6663e-03 7.4367e-03 3.5147e-03 -6.0000e+00 1.5420e-01 2.2194e-05 -7.9987e-04 3.5990e-04 3.4850e-05 -6.0000e+00 1.0494e-02 1.4863e-03 8.9413e-05 12 9 8 11 8 0 99.91 20.81 0.09 0.00149 -0.00452 12 3 1 5 0 3970.560 25.47 20.03 20.81 21.68 9.9 956.73 129511 -6333 8144 -28064 340494 -29267 -3581 47807 -11756 39880 -35848 58258 10600 68589 -41921 28195 13334 7848 17316 -7096 24068 300 8044 -10149 -2346 -7337 13609 33256 19209 5700 -29758 236 8073 284 -15043 6344 -2817 13754 -6556 8060 8419 -4438 1800 -10118 1892 -11024 9166 -7643 16292 7636 -4976 2769 2751 2860 4966 13589 -9959 6017 -3273 4413 4425 8944 -495 1699 -903 -3202 3380 -8221 1706 -4380 5082 -3378 2410 -3465 3654 3108 -6064 -3240 -986 288 -3368 4815 -2093 2592 -5069 -1049 1660 2548 145 -35 1684 -2865 1941 -2245 532 -3169 2415 -951 1183 71 312 -2068 -2465 -964 -1667 2439 -2555 3123 -1124 2690 1662 1419 -352 -1545 724 -2487 1598 -3285 3221 -3217 3938 539 2355 1172 -1745 -2100 -1766 -1062 -1418 -1567 -1221 1736 -634 206518 -1510 189 939 -819 445 -1128 612 -662 1632 -302 349 -1538 4132 -1470 -157 1461 -659 1417 -2655 1990 643 2884 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