File name: Pandora135s1_ManhattanNY-CCNY_20210109_L2Fit_fnvs4c15d20200411p1-8.txt File generation date: 20241023T064811.6Z Data description: Level 2 spectral fitting results file Data file version: fnvs4c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v2d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20210109_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20210109 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 929 1474 Nominal wavelengths inside fitting window [nm]: 400.1108 400.2430 400.3752 400.5073 400.6394 400.7716 400.9037 401.0358 401.1678 401.2999 401.4320 401.5640 401.6960 401.8280 401.9600 402.0920 402.2240 402.3559 402.4879 402.6198 402.7517 402.8836 403.0155 403.1474 403.2792 403.4111 403.5429 403.6747 403.8065 403.9383 404.0701 404.2018 404.3336 404.4653 404.5970 404.7287 404.8604 404.9921 405.1237 405.2554 405.3870 405.5186 405.6502 405.7818 405.9134 406.0450 406.1765 406.3081 406.4396 406.5711 406.7026 406.8341 406.9655 407.0970 407.2284 407.3598 407.4912 407.6226 407.7540 407.8854 408.0167 408.1481 408.2794 408.4107 408.5420 408.6733 408.8045 408.9358 409.0670 409.1983 409.3295 409.4607 409.5919 409.7230 409.8542 409.9853 410.1164 410.2476 410.3787 410.5097 410.6408 410.7719 410.9029 411.0339 411.1649 411.2959 411.4269 411.5579 411.6888 411.8198 411.9507 412.0816 412.2125 412.3434 412.4743 412.6051 412.7360 412.8668 412.9976 413.1284 413.2592 413.3900 413.5207 413.6515 413.7822 413.9129 414.0436 414.1743 414.3050 414.4356 414.5663 414.6969 414.8275 414.9581 415.0887 415.2192 415.3498 415.4803 415.6109 415.7414 415.8719 416.0024 416.1328 416.2633 416.3937 416.5242 416.6546 416.7850 416.9153 417.0457 417.1761 417.3064 417.4367 417.5670 417.6973 417.8276 417.9579 418.0882 418.2184 418.3486 418.4788 418.6090 418.7392 418.8694 418.9995 419.1297 419.2598 419.3899 419.5200 419.6501 419.7801 419.9102 420.0402 420.1702 420.3003 420.4302 420.5602 420.6902 420.8201 420.9501 421.0800 421.2099 421.3398 421.4697 421.5995 421.7294 421.8592 421.9890 422.1188 422.2486 422.3784 422.5082 422.6379 422.7677 422.8974 423.0271 423.1568 423.2864 423.4161 423.5457 423.6754 423.8050 423.9346 424.0642 424.1937 424.3233 424.4528 424.5824 424.7119 424.8414 424.9709 425.1003 425.2298 425.3592 425.4887 425.6181 425.7475 425.8769 426.0062 426.1356 426.2649 426.3942 426.5235 426.6528 426.7821 426.9114 427.0406 427.1699 427.2991 427.4283 427.5575 427.6867 427.8158 427.9450 428.0741 428.2032 428.3323 428.4614 428.5905 428.7195 428.8486 428.9776 429.1066 429.2356 429.3646 429.4936 429.6225 429.7515 429.8804 430.0093 430.1382 430.2671 430.3960 430.5248 430.6537 430.7825 430.9113 431.0401 431.1689 431.2976 431.4264 431.5551 431.6838 431.8125 431.9412 432.0699 432.1985 432.3272 432.4558 432.5844 432.7130 432.8416 432.9702 433.0987 433.2273 433.3558 433.4843 433.6128 433.7413 433.8698 433.9982 434.1267 434.2551 434.3835 434.5119 434.6403 434.7686 434.8970 435.0253 435.1536 435.2819 435.4102 435.5385 435.6667 435.7950 435.9232 436.0514 436.1796 436.3078 436.4360 436.5641 436.6922 436.8204 436.9485 437.0766 437.2047 437.3327 437.4608 437.5888 437.7168 437.8448 437.9728 438.1008 438.2287 438.3567 438.4846 438.6125 438.7404 438.8683 438.9962 439.1240 439.2518 439.3797 439.5075 439.6353 439.7630 439.8908 440.0186 440.1463 440.2740 440.4017 440.5294 440.6571 440.7847 440.9124 441.0400 441.1676 441.2952 441.4228 441.5503 441.6779 441.8054 441.9329 442.0604 442.1879 442.3154 442.4429 442.5703 442.6977 442.8252 442.9525 443.0799 443.2073 443.3347 443.4620 443.5893 443.7166 443.8439 443.9712 444.0985 444.2257 444.3529 444.4801 444.6073 444.7345 444.8617 444.9889 445.1160 445.2431 445.3702 445.4973 445.6244 445.7515 445.8785 446.0055 446.1326 446.2596 446.3865 446.5135 446.6405 446.7674 446.8943 447.0213 447.1481 447.2750 447.4019 447.5287 447.6556 447.7824 447.9092 448.0360 448.1628 448.2895 448.4163 448.5430 448.6697 448.7964 448.9231 449.0497 449.1764 449.3030 449.4296 449.5562 449.6828 449.8094 449.9359 450.0625 450.1890 450.3155 450.4420 450.5685 450.6950 450.8214 450.9478 451.0743 451.2007 451.3271 451.4534 451.5798 451.7061 451.8324 451.9588 452.0851 452.2113 452.3376 452.4638 452.5901 452.7163 452.8425 452.9687 453.0948 453.2210 453.3471 453.4733 453.5994 453.7255 453.8515 453.9776 454.1037 454.2297 454.3557 454.4817 454.6077 454.7337 454.8596 454.9855 455.1115 455.2374 455.3633 455.4891 455.6150 455.7408 455.8667 455.9925 456.1183 456.2441 456.3698 456.4956 456.6213 456.7470 456.8727 456.9984 457.1241 457.2497 457.3754 457.5010 457.6266 457.7522 457.8778 458.0034 458.1289 458.2544 458.3799 458.5054 458.6309 458.7564 458.8819 459.0073 459.1327 459.2581 459.3835 459.5089 459.6342 459.7596 459.8849 460.0102 460.1355 460.2608 460.3861 460.5113 460.6365 460.7618 460.8870 461.0121 461.1373 461.2625 461.3876 461.5127 461.6378 461.7629 461.8880 462.0131 462.1381 462.2631 462.3881 462.5131 462.6381 462.7631 462.8880 463.0130 463.1379 463.2628 463.3877 463.5125 463.6374 463.7622 463.8871 464.0119 464.1367 464.2614 464.3862 464.5109 464.6357 464.7604 464.8851 465.0097 465.1344 465.2591 465.3837 465.5083 465.6329 465.7575 465.8821 466.0066 466.1311 466.2557 466.3802 466.5047 466.6291 466.7536 466.8780 467.0024 467.1269 467.2512 467.3756 467.5000 467.6243 467.7487 467.8730 467.9973 468.1216 468.2458 468.3701 468.4943 468.6185 468.7427 468.8669 468.9911 469.1152 469.2394 469.3635 469.4876 469.6117 469.7357 469.8598 469.9838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 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