File name: Pandora135s1_ManhattanNY-CCNY_20210111_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20241023T064729.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v2d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20210111_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20210111 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210111T134832.0Z 7681.575370 105 1 47.90 2 77.23 134.18 70.37 155.00 0.00 1 0.00 1 0 25 3.362e-01 1.113e-02 2.502e-01 5.506e-03 6.125611e-01 2.988458e-03 7.128920e-03 -6.000000e+00 1.937386e-01 223.63 -2.00 3.51 -2.00 320.78 0.00e+00 5.549177e-03 1.213536e-03 1.633124e-03 -6.000000e+00 9.419851e-03 275.47 -2.00 20.00 -2.00 320.32 0.00e+00 4.404 0.001 302.00 328.00 3 4.1292e+00 9.2188e-03 5.5303e-02 -6.0000e+00 4.7904e-01 6.8537e-02 1.2256e-02 3.6294e-02 -6.0000e+00 5.2058e-01 -4.8187e-02 1.2943e-02 1.8004e-02 -6.0000e+00 3.0752e-01 1.3333e-02 6.4476e-03 9.5600e-03 -6.0000e+00 1.3699e-01 5.2722e-05 -1.0584e-03 1.5743e-04 7.3375e-05 -6.0000e+00 9.4407e-03 -4.6329e-02 3.8733e-05 12 8 8 10 0 0 99.75 19.15 0.05 -0.04633 -0.05428 22 6 1 5 0 2176.620 24.04 20.00 19.15 4.64 10.9 847.65 900000 900000 -57527 46782 900000 -217167 -158964 900000 -63693 58032 900000 900000 37289 56606 -89645 124077 123529 -59339 -24240 -42931 22982 -25457 18248 -41959 29851 8610 1643 8355 4397 -25714 -38436 3911 25941 8667 -25390 28092 12791 23989 13586 12311 11624 -9519 -2917 -8390 -459 8358 11284 4007 22946 9749 -1257 3705 3061 5924 -687 5492 -2586 -2226 -1825 347 7350 5783 1015 1919 389 -3821 1080 -858 -141 2520 523 775 761 -715 -727 4916 -2770 1451 -86 -2113 -655 1788 -3853 622 -1080 -586 -1193 -1036 1124 748 1186 1523 208 1021 92 32 -281 395 -950 -27 -674 625 -315 55 -1090 -223 -1538 -14 -871 573 -261 314 -137 -570 1453 -868 1043 -571 438 -951 -98 595 40 1173 -252 333 -763 1017 435 343 54 458 127 640 -334 -315 221 -67 -689 51 645 -923 900000 900000 -366 251 900000 -5622 -2557 900000 -519 311 900000 900000 200 315 -2453 665 662 -1821 -590 -1286 393 -683 329 -1435 575 208 43 202 111 -960 -1883 157 964 393 -1563 1044 610 1222 907 986 1051 -1108 -335 -1051 -56 964 1300 515 2554 1327 -205 642 585 1190 -155 1213 -634 -540 -430 79 1630 1446 304 637 133 -1372 361 -301 -53 1055 245 377 364 -327 -303 1800 -1024 523 -35 -1017 -363 1097 -2641 431 -813 -467 -1007 -896 946 608 893 1099 146 731 72 29 -286 454 -1164 -33 -786 644 -311 55 -1182 -246 -1810 -17 -1154 837 -410 515 -224 -899 2174 -1271 1508 -879 709 -1575 -160 951 62 1735 -363 472 -1054 1441 678 585 100 872 254 1347 -738 -729 520 -156 -1610 117 1417 -1936 SS 20210111T135535.4Z 7681.580271 108 1 46.90 2 76.28 135.55 69.85 156.56 0.00 1 0.00 1 0 25 3.362e-01 8.263e-03 1.983e-01 3.989e-03 5.747749e-01 2.102763e-03 6.738190e-03 -6.000000e+00 1.924469e-01 223.63 -2.00 3.51 -2.00 320.47 0.00e+00 4.635388e-03 7.799180e-04 1.265502e-03 -6.000000e+00 8.457726e-03 275.47 -2.00 20.00 -2.00 320.00 0.00e+00 4.120 0.001 302.00 328.00 3 3.9408e+00 6.2562e-03 5.1264e-02 -6.0000e+00 4.7480e-01 5.5383e-02 8.0325e-03 3.2650e-02 -6.0000e+00 5.1498e-01 -3.8702e-02 8.1194e-03 1.6325e-02 -6.0000e+00 3.0591e-01 9.3471e-03 4.1278e-03 7.8867e-03 -6.0000e+00 1.3364e-01 8.7369e-05 -1.1154e-03 1.1193e-04 6.2086e-05 -6.0000e+00 9.2039e-03 -4.5728e-02 1.5289e-05 11 8 0 10 0 0 99.59 19.15 0.20 -0.04573 -0.05411 27 8 1 5 0 1736.750 24.04 20.00 19.15 4.85 10.9 849.54 -15510 23820 -54774 -81062 900000 -176989 -13055 -50927 85540 -92360 276393 -37629 16583 27651 -66331 35904 3666 -20086 -29640 13647 -12463 26081 -16733 -14995 1496 -12401 677 -9413 16207 -34005 -8517 -12069 34252 -7562 -3575 474 5517 9364 -4645 4137 910 835 -6190 -3625 -5164 9433 626 7271 9582 6175 208 2218 2914 -172 4855 2213 544 -1845 2497 -727 6410 3563 -1005 2200 -1738 1386 -233 2094 -245 1466 -1481 1173 34 -1495 637 946 -228 673 403 -1825 699 -1053 -2053 -1193 -1624 -343 -275 -270 -6 1562 408 1169 -844 915 -242 558 461 348 -412 -517 -358 -301 270 -458 37 -738 -574 -175 -401 126 -177 527 -456 311 578 460 250 -270 56 -914 141 -123 553 323 -4 -121 244 556 362 -134 467 359 -62 257 -331 42 150 181 -688 19 145 -393 -80 96 -500 -934 900000 -4639 -77 -480 333 -1575 1075 -445 150 288 -2054 494 78 -601 -1016 333 -404 577 -591 -561 51 -510 25 -372 494 -1783 -424 -714 1521 -519 -228 30 365 685 -478 461 117 115 -965 -567 -836 1353 100 1123 1503 1067 41 473 674 -44 1249 606 155 -535 676 -201 1722 1089 -365 861 -711 551 -92 825 -106 712 -813 651 19 -793 302 416 -95 280 187 -988 429 -719 -1540 -939 -1369 -294 -248 -250 -6 1404 345 912 -640 699 -208 531 504 419 -539 -674 -433 -338 278 -483 41 -888 -703 -228 -552 192 -288 887 -769 496 889 677 371 -421 89 -1543 234 -198 876 495 -6 -177 342 808 572 -231 844 684 -124 525 -708 93 342 418 -1601 43 312 -823 SS 20210111T140641.9Z 7681.587985 111 1 45.76 2 74.84 137.76 69.09 159.03 0.00 1 0.00 1 0 25 2.392e-01 1.110e-02 1.781e-01 5.195e-03 5.257836e-01 2.716294e-03 6.208610e-03 -6.000000e+00 1.369576e-01 223.63 -2.00 3.51 -2.00 320.23 0.00e+00 4.123270e-03 9.306309e-04 9.174045e-04 -6.000000e+00 6.018919e-03 275.47 -2.00 20.00 -2.00 319.75 0.00e+00 3.752 0.001 302.00 328.00 3 4.7493e+00 7.9270e-03 4.6508e-02 -6.0000e+00 3.3790e-01 5.7590e-02 9.7994e-03 2.9088e-02 -6.0000e+00 3.6647e-01 -3.7341e-02 9.2945e-03 1.4597e-02 -6.0000e+00 2.1770e-01 7.7441e-03 4.8079e-03 6.7853e-03 -6.0000e+00 9.5123e-02 5.8168e-05 -1.0375e-03 1.4793e-04 5.6563e-05 -6.0000e+00 6.5505e-03 -4.6032e-02 5.5690e-05 12 8 8 10 0 0 98.55 19.15 0.05 -0.04603 -0.05383 15 4 1 5 0 3049.870 24.04 20.00 19.15 5.27 10.9 852.08 -45762 3059 -50776 -43782 900000 -161353 -26291 66404 -1108 -76566 136148 25883 5539 34343 -72271 26929 -15664 -21107 -21871 -8769 -4300 4642 -12483 -18213 23476 -5316 16432 3345 12023 -41576 -14621 -12403 31280 -2349 -2328 4124 441 15447 4413 1090 6083 -1778 -3187 -2473 -1173 7804 3621 5906 13339 7878 572 2407 4136 685 3402 2438 -2233 -1992 -1489 -1332 5798 3533 1300 2029 52 -24 694 -317 709 1054 -1484 812 -20 -661 -530 4412 -2110 2579 450 -2843 -1206 -490 -2061 -6 -1048 -508 -567 14 307 777 -15 1574 -841 964 689 48 610 -408 -886 -595 -208 -355 1114 -1296 -579 -185 -456 77 -1036 608 -728 717 -414 116 543 -15 23 116 135 -1082 -308 624 919 700 -6 185 -255 583 673 -89 -78 415 -66 2070 -635 -394 500 -79 -766 200 -233 -762 -513 24 -709 -570 900000 -5693 -276 336 -11 -1725 690 262 82 485 -3416 574 -569 -855 -960 -368 -176 174 -575 -922 869 -275 689 155 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