File name: Pandora135s1_ManhattanNY-CCNY_20210116_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20241023T064736.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v2d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20210116_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20210116 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210116T143903.6Z 7686.610458 106 1 47.14 2 70.41 143.67 92.26 106.06 0.00 1 0.00 1 0 17 1.667e-01 8.944e-03 1.179e-01 4.662e-03 4.647416e-01 2.404150e-03 5.513111e-03 -6.000000e+00 9.534182e-02 223.79 -2.00 3.51 -2.00 319.71 0.00e+00 1.422859e-03 6.930327e-04 3.583385e-04 -6.000000e+00 4.118003e-03 275.20 -2.00 20.00 -2.00 319.21 0.00e+00 2.950 0.000 302.00 328.00 3 5.0651e+00 6.7515e-03 3.7869e-02 -6.0000e+00 2.3550e-01 6.3230e-02 8.0272e-03 2.4201e-02 -6.0000e+00 2.5535e-01 1.9683e-02 6.9390e-03 1.2368e-02 -6.0000e+00 1.5180e-01 -1.5229e-02 3.6785e-03 4.1968e-03 -6.0000e+00 6.6259e-02 9.4915e-05 -3.0346e-04 1.3308e-04 4.2843e-05 -6.0000e+00 4.5306e-03 -4.2437e-02 1.8807e-04 11 8 0 10 0 0 99.98 19.80 0.30 -0.04244 -0.04472 68 19 1 5 0 693.150 24.65 20.01 19.80 11.65 11.4 897.94 -2955 -23156 -34516 -52727 132544 -100735 20707 7608 9399 -37931 9129 23556 -7183 18730 -24385 20134 -2227 -11443 -2315 -733 761 -9035 -1374 -13626 3748 -6623 1268 1434 1371 -18595 -7752 -2805 9488 -7518 -6755 3884 4097 4296 786 639 -468 -738 -105 -546 1212 2720 2061 3 4677 1287 1011 -1114 1642 414 1314 1600 -999 -524 -1258 1338 2561 2685 88 1563 -21 -169 -145 214 1298 776 367 639 380 -929 675 1214 -176 13 -1175 -1358 -910 -256 -2451 -376 -955 -353 -301 801 635 937 752 310 -500 143 28 -289 237 -232 -433 74 -475 -481 350 -670 -823 -391 -933 6 -68 655 -232 379 -420 111 348 145 -497 -776 655 -771 445 192 419 804 172 -87 -224 584 214 -152 366 144 -445 3146 -690 -578 358 -149 -652 363 -322 -824 -40 -434 -730 -1281 603 -3558 255 118 161 -1068 173 424 -203 525 -1219 743 -113 -684 -135 -44 46 -607 -89 -1037 269 -552 98 106 99 -1700 -720 -285 959 -904 -771 411 476 573 132 127 -104 -175 -26 -137 301 673 516 1 1170 348 299 -369 552 150 495 621 -407 -211 -497 529 998 1143 43 819 -11 -87 -72 106 700 479 249 433 264 -620 407 652 -89 7 -644 -864 -661 -199 -2105 -333 -909 -356 -318 861 678 956 713 272 -430 123 25 -299 276 -295 -588 99 -592 -559 377 -747 -991 -494 -1244 8 -99 1031 -385 643 -703 180 523 208 -717 -1172 1038 -1297 740 311 653 1200 256 -124 -304 811 318 -248 640 262 -814 5844 -1416 -1242 779 -321 -1403 772 -653 -1589 SS 20210116T155132.8Z 7686.660796 158 1 1.57 2 63.99 160.68 79.77 117.85 0.00 1 0.00 1 0 17 4.977e-02 1.131e-02 4.123e-02 8.272e-03 3.496754e-01 4.182445e-03 4.252912e-03 -6.000000e+00 2.845455e-02 223.79 -2.00 3.51 -2.00 317.89 0.00e+00 5.829172e-04 7.076872e-04 1.033457e-04 -6.000000e+00 1.229112e-03 275.20 -2.00 20.00 -2.00 317.34 0.00e+00 2.267 0.000 302.00 328.00 3 3.7674e+00 1.1045e-02 2.8718e-02 -6.0000e+00 7.0284e-02 1.7337e-02 1.2450e-02 1.7804e-02 -6.0000e+00 7.6218e-02 1.1751e-02 8.1931e-03 8.9500e-03 -6.0000e+00 4.5310e-02 -3.2446e-03 4.3235e-03 2.6732e-03 -6.0000e+00 1.9771e-02 8.0788e-04 -3.4109e-04 2.3320e-04 2.8606e-05 -6.0000e+00 1.3527e-03 -4.1599e-02 1.2651e-04 12 9 9 12 1 1 999.00 19.88 0.10 -0.04160 -0.04416 1 19 1 5 0 695.190 24.75 20.01 19.88 12.53 11.4 903.28 -9362 -9578 -15354 -2381 -5318 -29742 23887 -17107 17269 -13773 4376 -11493 9177 -6100 374 -4913 -4317 5168 -1470 4632 -2890 1845 -852 3907 280 -5009 1589 -726 3834 -1868 -170 -1627 6999 -2744 -581 -1393 -301 1581 -1304 -2298 -1071 1321 -360 185 -4048 1202 1666 610 -265 1843 2079 -758 2199 -2133 2835 813 1417 -1235 2026 1098 1646 2481 1161 2066 261 -408 -1706 1222 -632 2246 236 -484 -462 -690 298 1605 1365 398 -110 -1545 -594 -1288 -2253 -1634 -1732 -1135 -78 -1243 -1407 1756 -900 622 780 1314 791 280 -428 111 -622 194 234 -738 739 49 -93 -543 -642 -608 -222 63 976 554 -1006 928 -203 128 -472 8 -170 225 268 14 147 646 1216 -798 821 285 762 -573 -582 647 -592 4222 -409 52 -491 -107 -1007 -315 -685 -532 -602 -682 -1189 -152 -317 -2199 1149 -1366 1091 -1248 334 -1094 822 -730 49 -757 -682 809 -251 798 -530 332 -157 736 58 -1146 338 -150 743 -387 -36 -396 1718 -739 -149 -357 -84 498 -496 -998 -490 622 -178 92 -2102 594 811 297 -130 907 1094 -433 1303 -1359 1782 522 921 -819 1305 709 1094 1728 878 1621 209 -316 -1254 889 -485 1854 212 -444 -429 -614 248 1241 990 283 -83 -1307 -538 -1272 -2351 -1743 -1935 -1320 -92 -1533 -1729 2046 -1018 662 785 1305 832 316 -525 145 -847 262 301 -907 865 59 -118 -715 -868 -847 -321 96 1542 877 -1594 1373 -291 177 -654 11 -253 346 417 21 220 945 1715 -1093 1098 383 1082 -863 -909 1029 -959 6818 -696 91 -882 -194 -1821 -558 -1183 -907 SS 20210116T160521.5Z 7686.670388 167 1 47.03 2 63.20 164.18 77.51 120.27 0.00 1 0.00 1 0 17 2.337e-01 1.729e-02 1.107e-01 9.589e-03 3.599117e-01 4.869617e-03 4.317211e-03 -6.000000e+00 1.334707e-01 223.79 -2.00 3.51 -2.00 318.69 0.00e+00 1.759501e-03 1.013661e-03 2.430884e-04 -6.000000e+00 5.768578e-03 275.20 -2.00 20.00 -2.00 318.15 0.00e+00 2.205 0.000 302.00 328.00 3 7.0009e+00 1.3099e-02 2.8566e-02 -6.0000e+00 3.2966e-01 1.3518e-01 1.4942e-02 1.8257e-02 -6.0000e+00 3.5765e-01 -1.4253e-02 1.0602e-02 9.3176e-03 -6.0000e+00 2.1262e-01 -1.3978e-03 5.6592e-03 3.0208e-03 -6.0000e+00 9.2659e-02 3.1314e-05 -1.9113e-03 2.7587e-04 3.2086e-05 -6.0000e+00 6.3565e-03 -3.8491e-02 -8.1551e-05 12 9 8 11 8 0 99.99 19.89 0.30 -0.03849 -0.05285 17 5 1 5 0 2765.930 24.75 19.99 19.89 12.91 11.4 906.31 20770 2425 20694 -6344 240634 -78843 9651 36899 20331 -13202 29449 28795 2879 17002 -35095 31621 8211 -607 -1688 -6417 10281 -703 -1736 -13615 5555 336 2239 1722 4238 -21303 -12032 -9562 25690 -3748 -7569 3890 3293 7362 4302 4698 1504 -173 -1242 -4356 4690 4204 3756 -1288 8197 6000 -847 1145 2087 1332 -474 4056 -2904 -410 -1266 -1798 6336 3476 -867 2680 -734 -1162 -2661 -2304 -2729 1040 -2109 2130 1190 -1583 1484 -551 87 -436 -813 -2328 -1607 204 -2893 2899 -770 37 -454 1343 1599 2398 -466 -215 -5116 -323 -2445 -693 -152 961 368 34 516 -1355 -1497 -2264 -378 634 -687 -650 -502 1467 671 1128 -557 486 1364 -1675 -1366 -1454 1126 -460 1305 1217 1628 1236 -960 -180 -1110 -112 393 330 -145 -206 -1163 1551 -602 70 1325 1054 -512 294 -400 -2279 741 115 838 -316 2250 -6819 381 1252 901 -824 1254 1316 198 1213 -4758 2460 861 -73 -216 -896 1232 -93 -239 -2237 800 53 342 251 596 -3777 -2129 -1846 3968 -767 -1522 713 640 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