File name: Pandora135s1_ManhattanNY-CCNY_20210210_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20241023T070719.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v2d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20210210_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20210210 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210210T142930.9Z 7711.603830 106 1 17.89 2 66.34 136.97 68.51 153.39 0.00 1 0.00 1 0 17 5.023e-02 1.959e-02 3.988e-02 5.897e-03 3.684191e-01 2.996223e-03 4.530863e-03 -6.000000e+00 2.879698e-02 224.70 -2.00 3.51 -2.00 318.57 0.00e+00 1.149495e-03 6.010861e-04 7.039509e-04 -6.000000e+00 1.239550e-03 275.14 -2.00 20.00 -2.00 318.02 0.00e+00 2.474 0.000 302.00 328.00 3 5.4965e+00 8.0539e-03 3.1112e-02 -6.0000e+00 7.1274e-02 8.1349e-02 9.1433e-03 1.9139e-02 -6.0000e+00 7.7262e-02 -4.2127e-02 6.4369e-03 9.6633e-03 -6.0000e+00 4.5897e-02 3.7409e-03 3.4406e-03 2.8475e-03 -6.0000e+00 1.9982e-02 1.1333e-04 -1.8512e-03 1.6915e-04 3.0972e-05 -6.0000e+00 1.3663e-03 -5.0292e-02 -3.6389e-04 12 9 9 12 9 1 94.60 19.08 0.01 -0.05029 -0.06420 4 4 1 5 0 3542.430 24.04 20.00 19.08 3.72 11.1 843.88 -20443 12596 -17708 -8609 15117 -32201 -389 1938 2373 -10135 17981 -8594 1959 -2871 -8497 562 2746 2361 -3131 -3219 -3280 5594 -3256 -5187 2477 -432 -351 -973 3025 -1984 -2669 1719 10350 -4357 385 -1204 3475 6060 5050 336 40 -998 -2717 -1587 -1551 -244 -1623 910 830 3080 -1857 2039 261 1293 771 465 262 -1430 370 -19 4714 2101 1174 432 -1764 -407 52 789 794 2149 -249 1241 -649 105 -2743 714 -196 242 -1068 -1203 455 599 -1348 -790 148 -934 -880 -1032 -1130 -20 -435 -508 -490 1398 379 1103 873 901 -577 -149 -541 -297 830 -841 -508 -873 -822 -791 -342 338 499 327 71 137 894 1207 1085 1614 1018 -45 -591 206 187 343 -193 -465 191 998 755 417 1254 1466 743 -10496 730 1209 883 1135 6 1068 183 -115 -1070 542 -1022 -426 551 -1765 -17 95 128 -629 881 -567 135 -248 -907 61 313 285 -419 -448 -465 722 -472 -816 385 -72 -58 -153 435 -304 -451 311 1891 -945 75 -237 714 1437 1460 114 15 -398 -1138 -664 -650 -101 -677 367 334 1247 -846 969 131 678 421 261 150 -827 205 -10 2566 1274 767 305 -1283 -274 34 505 536 1623 -204 1039 -548 84 -2144 498 -126 151 -723 -904 382 541 -1293 -792 157 -1040 -1032 -1211 -1320 -23 -475 -508 -467 1297 383 1204 1043 1166 -784 -199 -694 -355 950 -981 -638 -1132 -1115 -1098 -503 521 798 535 116 209 1286 1681 1512 2341 1547 -71 -950 322 290 510 -283 -651 261 1372 1100 648 1997 2409 1261 -19867 1312 2272 1706 2175 11 2044 337 -207 SS 20210210T143704.9Z 7711.609084 109 1 33.73 2 65.38 138.69 67.89 155.10 0.00 1 0.00 1 0 17 3.535e-02 6.321e-03 1.486e-02 2.649e-03 3.347955e-01 1.339627e-03 4.052813e-03 -6.000000e+00 2.029866e-02 224.70 -2.00 3.51 -2.00 318.25 0.00e+00 1.038196e-03 2.474449e-04 1.030854e-04 -6.000000e+00 8.732503e-04 275.14 -2.00 20.00 -2.00 317.70 0.00e+00 2.384 0.000 302.00 328.00 3 4.9959e+00 3.5703e-03 2.9230e-02 -6.0000e+00 5.0243e-02 1.7351e-02 4.0366e-03 1.7177e-02 -6.0000e+00 5.4431e-02 -5.6231e-03 2.7373e-03 8.6299e-03 -6.0000e+00 3.2333e-02 -1.8475e-03 1.4531e-03 2.6804e-03 -6.0000e+00 1.4100e-02 2.1874e-04 -4.7435e-04 7.5752e-05 2.7810e-05 -6.0000e+00 9.6053e-04 -5.1349e-02 7.5268e-05 12 1 1 12 1 1 99.87 19.08 0.08 -0.05135 -0.05491 17 7 1 5 0 1864.030 24.04 20.00 19.08 3.80 11.1 844.63 -6080 -1104 -7179 -12567 16339 -26569 2031 -6106 6872 -12657 6425 -2635 783 2018 -4559 862 -1393 2662 -1926 1496 -54 1974 -3226 -1371 605 -865 -180 -1522 2201 -2295 -334 -1149 5225 -2013 -352 -1060 74 798 178 -338 -1206 -546 -2304 -729 -2139 671 -1003 563 861 1781 -218 494 1671 350 1676 1000 802 -508 814 744 2305 1845 1043 1197 -613 -110 -610 1140 626 705 -37 232 -145 -446 524 35 35 495 -11 -254 -750 -1226 -2109 -1379 -898 -835 -595 -108 70 638 251 475 195 1156 625 619 549 227 -489 -644 -253 -796 699 -426 -558 -770 -671 -517 -99 193 -101 75 -16 -69 266 715 496 375 343 -365 -203 135 428 649 -24 61 791 422 484 91 -109 457 -309 290 -366 -37 145 416 -452 -102 -72 -804 -342 -66 -466 -813 740 -1715 105 -388 427 -1005 425 -201 66 200 -543 109 -191 369 -294 229 -9 306 -540 -239 110 -166 -34 -279 381 -417 -65 -241 1126 -480 -78 -241 18 222 58 -130 -496 -235 -1043 -329 -982 301 -452 255 386 808 -104 254 907 197 966 596 487 -311 481 437 1378 1199 728 896 -471 -79 -421 764 442 549 -31 207 -129 -381 423 26 24 325 -8 -197 -645 -1143 -2126 -1411 -977 -947 -711 -128 83 744 279 496 189 1121 635 683 661 297 -670 -872 -327 -966 810 -502 -711 -1015 -925 -728 -143 293 -161 121 -26 -106 385 998 692 535 510 -567 -319 213 653 973 -35 86 1050 569 688 137 -175 734 -512 488 -642 -68 267 780 -856 -191 -130 -1427 SS 20210210T145051.8Z 7711.618655 117 1 47.60 2 63.71 141.89 66.87 158.26 0.00 1 0.00 1 0 17 2.929e-02 2.277e-02 1.081e-02 2.248e-03 3.355267e-01 1.137464e-03 4.102108e-03 -6.000000e+00 1.681605e-02 224.70 -2.00 3.51 -2.00 318.06 0.00e+00 3.543982e-04 1.979119e-04 5.768107e-04 -6.000000e+00 7.234302e-04 275.14 -2.00 20.00 -2.00 317.51 0.00e+00 2.245 0.000 302.00 328.00 3 5.1547e+00 3.0167e-03 2.8176e-02 -6.0000e+00 4.1623e-02 7.6406e-02 3.4005e-03 1.7228e-02 -6.0000e+00 4.5093e-02 -4.3128e-02 2.2369e-03 8.6284e-03 -6.0000e+00 2.6786e-02 5.1150e-03 1.1777e-03 2.5133e-03 -6.0000e+00 1.1680e-02 2.1007e-04 1.7950e-04 6.4227e-05 2.6758e-05 -6.0000e+00 7.9581e-04 -5.1109e-02 6.7704e-05 12 8 8 10 0 0 99.13 19.09 0.23 -0.05111 -0.04976 27 8 1 5 0 1762.700 24.04 20.00 19.09 4.11 11.1 846.76 -2774 -2498 -6264 -12363 8428 -21378 -4488 -1189 269 -6570 -4615 187 1396 1903 -5238 981 621 518 -463 1768 -45 418 -190 -2325 1428 -2258 -161 -1073 -1490 -1430 -1440 911 3711 -1902 -828 -188 797 3115 1030 45 -60 -736 -1126 -782 -714 -709 -862 -310 1053 1300 1034 1276 1632 1162 1291 1064 666 435 392 673 1513 1291 880 469 -1241 -877 181 787 1078 1020 288 598 -391 -699 -982 -515 -801 -703 -285 -160 -247 -853 -1707 -765 -646 -958 -395 -707 -692 -595 -821 -625 -148 715 989 1295 1495 961 145 -70 -222 -665 334 -267 -808 -1044 -904 -754 -272 598 601 408 115 235 867 1155 987 998 1357 266 23 -87 29 89 -176 -327 268 1244 1093 875 901 1387 1287 -13254 1157 1219 1732 1383 514 682 358 -79 -179 -177 -470 -923 479 -1515 -299 -87 21 -567 -392 16 134 214 -733 143 96 84 -79 308 -8 75 -35 -465 293 -499 -34 -219 -289 -277 -302 207 894 -496 -202 -45 205 927 363 19 -26 -341 -538 -375 -342 -340 -408 -144 478 601 511 679 923 673 772 654 418 272 239 420 933 862 647 358 -965 -656 125 535 790 820 246 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