File name: Pandora135s1_ManhattanNY-CCNY_20210211_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20241023T070803.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v2d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20210211_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20210211 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210211T174838.1Z 7712.742107 209 1 4.11 2 55.32 191.42 60.50 189.59 0.00 1 0.00 1 0 17 1.627e-02 7.997e-03 1.629e-02 7.191e-03 2.259613e-01 3.658544e-03 2.789975e-03 -6.000000e+00 9.342058e-03 224.75 -2.00 3.51 -2.00 316.43 0.00e+00 6.757811e-04 4.190478e-04 4.080786e-05 -6.000000e+00 4.018366e-04 275.14 -2.00 20.00 -2.00 315.90 0.00e+00 1.752 0.000 302.00 328.00 3 5.1627e+00 9.4635e-03 2.0859e-02 -6.0000e+00 2.3126e-02 2.7436e-02 1.0538e-02 1.1564e-02 -6.0000e+00 2.5053e-02 6.2307e-03 6.2061e-03 5.7525e-03 -6.0000e+00 1.4882e-02 -6.1309e-03 3.0158e-03 1.7263e-03 -6.0000e+00 6.4882e-03 4.0607e-04 -2.3549e-04 2.0422e-04 1.9529e-05 -6.0000e+00 4.4206e-04 -5.0625e-02 7.6547e-05 12 9 1 12 1 1 999.00 19.25 0.36 -0.05062 -0.05239 1 7 1 5 0 1967.770 24.14 20.00 19.25 5.75 11.2 858.20 -5869 -526 -3658 -6253 3781 -6009 3457 4019 2781 -3276 -516 -4291 1140 -1857 -1724 -1983 1769 329 -150 1878 -245 3117 646 3628 1520 433 411 2730 200 8 2433 -306 4118 -2995 -806 -44 1513 268 -759 -1314 -1532 -554 -2489 -518 -304 594 -881 47 -643 553 286 -58 -359 277 385 352 -464 572 643 802 2364 1501 614 797 -940 -173 322 784 -473 2453 -544 913 -179 -1452 1003 -23 -27 298 236 156 374 -2484 -1405 -1118 -586 -1268 -431 -305 1027 -45 -1026 122 -508 1888 748 698 16 121 -271 -140 -96 -374 919 -978 -626 -559 -257 -225 -187 319 -405 854 494 646 -848 626 13 1442 -357 -706 -110 47 506 567 306 -251 187 312 579 -258 270 252 -468 223 -137 -129 -91 785 -885 50 -737 151 -1034 -95 -689 -1124 568 -947 523 680 509 -661 -100 -883 247 -474 -481 -603 538 105 -50 629 -85 1038 224 1281 560 166 156 980 69 3 840 -117 1621 -1243 -317 -17 618 126 -407 -793 -1007 -366 -1718 -353 -206 409 -602 31 -415 353 192 -41 -267 214 296 276 -372 451 511 634 1847 1270 553 738 -876 -151 264 638 -406 2247 -532 915 -181 -1432 945 -20 -22 229 190 136 357 -2549 -1478 -1230 -669 -1527 -531 -387 1283 -55 -1221 133 -534 1878 794 776 19 154 -357 -186 -121 -446 1056 -1161 -785 -725 -347 -309 -264 465 -612 1310 729 921 -1147 801 16 1908 -494 -1024 -162 69 730 784 412 -330 237 397 764 -360 383 365 -693 334 -213 -206 -150 1280 -1475 83 -1182 236 SS 20210211T175406.3Z 7712.745906 212 1 24.57 2 55.54 193.01 60.66 191.03 0.00 1 0.00 1 0 17 8.418e-03 5.514e-03 1.521e-03 7.043e-04 2.322691e-01 3.591443e-04 2.860389e-03 -6.000000e+00 4.835363e-03 224.75 -2.00 3.51 -2.00 316.33 0.00e+00 2.983679e-04 3.993356e-05 4.498589e-05 -6.000000e+00 2.079739e-04 275.14 -2.00 20.00 -2.00 315.79 0.00e+00 1.762 0.000 302.00 328.00 3 3.1100e+00 9.2646e-04 2.1101e-02 -6.0000e+00 1.1970e-02 1.8239e-02 1.0315e-03 1.1819e-02 -6.0000e+00 1.2966e-02 -5.8204e-03 6.0610e-04 5.8873e-03 -6.0000e+00 7.7017e-03 1.2964e-03 2.9255e-04 1.7172e-03 -6.0000e+00 3.3588e-03 3.1240e-03 3.4394e-05 1.9962e-05 2.0183e-05 -6.0000e+00 2.2868e-04 -5.0976e-02 1.4985e-04 12 1 1 12 1 1 99.96 19.25 0.17 -0.05098 -0.05072 131 71 1 5 0 184.780 24.14 20.00 19.25 5.90 11.2 860.10 -1157 -1411 -2276 -3785 -2417 -2380 468 494 -10 -2075 -1204 -738 -634 589 262 62 -46 864 835 1126 446 865 799 781 488 205 -213 -544 260 683 1182 1616 802 -1325 -1629 -908 -750 76 -292 -675 -957 -824 -890 -408 -251 -388 -695 -558 -459 430 526 749 977 582 784 798 461 295 708 1031 1282 1465 1181 832 -316 -152 -165 779 1022 458 55 2 -4 -120 -114 -66 -165 -32 -96 -728 -1068 -1576 -1744 -1338 -936 -672 -544 -294 -103 227 145 54 736 1087 611 458 577 326 -51 -436 -428 -513 333 -26 -719 -622 -715 -448 27 249 9 99 124 124 196 604 382 446 235 -137 -278 137 128 425 538 112 659 785 388 234 -67 263 -32 -87 -271 -63 232 59 -463 -162 -423 -458 -210 -278 -456 -716 -403 -377 76 90 -2 -449 -255 -159 -151 159 74 19 -15 280 281 389 158 302 284 291 193 84 -86 -208 92 235 424 624 335 -575 -665 -360 -323 38 -162 -404 -625 -561 -622 -285 -175 -269 -473 -368 -295 275 353 536 737 461 594 617 364 231 543 840 1002 1228 1076 754 -287 -135 -135 614 861 411 54 2 -4 -118 -105 -57 -140 -26 -81 -645 -998 -1627 -1919 -1447 -1077 -781 -668 -371 -129 273 171 58 761 1085 647 504 703 414 -69 -581 -533 -620 380 -31 -883 -808 -973 -601 38 371 13 148 187 174 264 763 483 588 334 -198 -412 200 182 607 729 145 852 1016 507 328 -94 374 -47 -131 -412 -100 379 98 -784 -267 -674 -702 SS 20210211T175902.2Z 7712.749331 215 1 16.34 2 55.76 194.44 60.83 192.32 0.00 1 0.00 1 0 17 8.198e-03 5.497e-03 1.252e-03 5.911e-04 2.338713e-01 3.004931e-04 2.878090e-03 -6.000000e+00 4.708455e-03 224.75 -2.00 3.51 -2.00 316.24 0.00e+00 3.206155e-04 3.279932e-05 4.563680e-05 -6.000000e+00 2.025261e-04 275.14 -2.00 20.00 -2.00 315.71 0.00e+00 1.772 0.000 302.00 328.00 3 2.3787e+00 7.7536e-04 2.1225e-02 -6.0000e+00 1.1655e-02 1.2480e-02 8.6299e-04 1.1897e-02 -6.0000e+00 1.2626e-02 -6.9376e-03 5.0630e-04 5.9205e-03 -6.0000e+00 7.4999e-03 1.3992e-03 2.4387e-04 1.7234e-03 -6.0000e+00 3.2704e-03 6.4308e-03 -1.2057e-04 1.6727e-05 2.0423e-05 -6.0000e+00 2.2273e-04 -5.0626e-02 1.2534e-04 12 1 1 12 1 1 99.71 19.25 0.24 -0.05063 -0.05153 166 136 1 5 0 96.810 24.14 20.00 19.25 6.03 11.2 860.57 -1172 -949 -2286 -3279 -2825 -1727 40 197 77 -2134 -1595 -1007 -181 378 145 -400 264 533 718 997 497 748 902 953 569 313 -463 -267 94 791 1430 1779 572 -1350 -1279 -1000 -707 -26 -188 -750 -1014 -822 -904 -352 -385 -282 -763 -584 -360 316 614 845 1087 730 743 836 494 421 585 1020 1193 1395 1292 690 -294 -133 -315 511 893 688 229 5 -96 -132 -21 24 -203 -149 -177 -754 -990 -1583 -1727 -1327 -855 -744 -504 -372 -95 174 185 43 664 973 480 464 484 241 -130 -410 -532 -346 394 -28 -719 -653 -622 -410 22 237 126 77 19 146 187 671 436 462 158 -112 -276 100 216 476 482 134 713 885 422 145 -97 289 1 -141 -198 -87 207 -8 -346 -239 -520 -414 -216 -190 -467 -629 -482 -277 7 37 16 -471 -346 -222 -44 104 41 -126 86 178 247 354 180 268 328 364 231 131 -193 -104 34 279 526 705 246 -603 -536 -408 -313 -12 -108 -462 -683 -577 -608 -254 -277 -202 -536 -398 -239 209 425 624 790 557 583 669 403 341 465 802 966 1211 1141 649 -276 -115 -268 419 781 639 219 5 -96 -127 -20 20 -167 -116 -145 -651 -961 -1600 -1860 -1493 -967 -901 -610 -463 -118 207 215 48 674 1014 499 532 582 304 -174 -541 -655 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