File name: Pandora135s1_ManhattanNY-CCNY_20210407_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20241023T074926.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v2d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20210407_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20210407 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20210407T130907.9Z 7767.548009 228 1 7.89 2 60.85 107.24 59.89 168.09 0.00 1 0.00 1 0 17 1.985e-02 5.854e-03 8.087e-03 1.626e-03 3.576666e-01 8.340136e-04 4.308488e-03 -6.000000e+00 1.151188e-02 227.96 -2.00 3.51 -2.00 317.92 0.00e+00 6.477722e-04 1.416590e-04 1.597965e-04 -6.000000e+00 4.985589e-04 279.41 -2.00 20.00 -2.00 317.28 0.00e+00 2.044 0.000 302.00 328.00 3 3.0652e+00 2.2224e-03 2.7725e-02 -6.0000e+00 2.8663e-02 1.3552e-02 2.5020e-03 1.8485e-02 -6.0000e+00 3.0990e-02 -7.7784e-03 1.6318e-03 9.1830e-03 -6.0000e+00 1.8411e-02 8.1539e-04 8.5347e-04 2.6691e-03 -6.0000e+00 7.9730e-03 1.9774e-03 -3.2228e-04 4.5682e-05 2.7939e-05 -6.0000e+00 5.4068e-04 -2.9230e-02 8.8681e-05 12 1 1 12 1 1 86.80 20.45 0.11 -0.02923 -0.03165 30 53 1 5 0 248.810 25.28 20.00 20.45 18.82 12.4 953.25 1617 -7440 1318 -11018 -571 -10972 -3631 -276 -4929 -1959 -7623 -780 -3375 2067 -4298 1091 -2132 1043 385 -618 1054 -436 1462 -1186 1339 -1774 1025 -1950 373 -459 1613 1510 429 -1091 -3215 -974 -2405 866 -1540 -481 -1343 -343 -1137 280 249 -368 -144 -993 362 271 569 778 1517 626 1106 1065 378 344 132 1291 1091 2126 1557 1415 -198 154 -117 765 1025 683 307 -242 212 -247 106 -112 -256 -88 -185 -706 -884 -1575 -2193 -1076 -1094 -699 -415 -139 -173 396 601 155 626 558 781 212 672 -130 -25 -500 -828 -561 387 -247 -946 -789 -755 -262 -219 439 40 544 29 188 256 478 330 132 184 -273 -50 -65 327 598 544 -11 622 701 192 281 -99 396 -59 -63 -310 169 213 71 -229 -245 -509 -511 95 -523 86 -762 -32 -675 -225 -19 -392 -158 -656 -67 -348 239 -581 155 -333 167 65 -110 187 -78 267 -238 279 -395 219 -406 72 -92 347 363 114 -299 -850 -252 -699 274 -603 -204 -628 -167 -574 141 125 -187 -72 -497 179 138 295 436 902 378 687 680 247 223 84 807 711 1491 1151 1119 -159 114 -86 559 783 567 277 -218 196 -219 90 -85 -187 -63 -144 -601 -817 -1552 -2227 -1137 -1238 -810 -504 -166 -205 463 673 166 621 555 840 247 839 -169 -34 -669 -1068 -682 462 -298 -1196 -1049 -1013 -368 -317 656 63 872 45 282 367 648 452 191 274 -415 -76 -101 487 882 765 -15 824 953 275 421 -153 623 -96 -103 -527 299 386 127 -411 -438 -898 -862 SU 20210407T131327.2Z 7767.551010 231 1 46.46 2 60.07 108.08 59.72 169.24 0.00 1 0.00 1 0 17 4.398e-02 2.107e-02 2.223e-02 3.237e-03 3.726331e-01 1.658366e-03 4.535127e-03 -6.000000e+00 2.550251e-02 227.96 -2.00 3.51 -2.00 318.65 0.00e+00 -2.903380e-04 3.448746e-04 8.850956e-04 -6.000000e+00 1.104873e-03 279.41 -2.00 20.00 -2.00 318.02 0.00e+00 1.996 0.000 302.00 328.00 3 5.6153e+00 4.4987e-03 2.8160e-02 -6.0000e+00 6.3497e-02 7.9173e-02 5.1292e-03 1.9889e-02 -6.0000e+00 6.8659e-02 -1.7424e-02 3.5963e-03 9.7047e-03 -6.0000e+00 4.0789e-02 -5.9792e-03 1.9059e-03 2.7997e-03 -6.0000e+00 1.7659e-02 1.5374e-04 2.3551e-04 9.2885e-05 2.8839e-05 -6.0000e+00 1.1983e-03 -2.8262e-02 5.2336e-05 12 8 8 10 0 0 99.99 20.46 0.24 -0.02826 -0.02649 53 15 1 5 0 876.030 25.28 20.00 20.46 18.87 12.4 953.79 9378 -10598 -5385 -21419 2009 -33228 -15264 4568 -10833 -2928 -3589 -481 -6411 3474 -3998 4564 2345 880 12 -3461 642 260 915 -3503 798 -1565 2214 2376 1572 -2213 -3074 748 1818 -497 -4180 2110 -1310 2933 746 386 -76 -597 -1995 -3206 689 -1012 20 -1625 2114 1515 700 344 1856 880 1586 1878 -507 -70 378 985 1953 2152 520 730 -839 -1319 86 -509 2220 1377 1051 1003 40 -904 -615 -541 -1778 -441 -255 -519 -1010 -178 -1540 90 -869 14 -104 -494 -1026 -119 -780 -1136 -801 388 462 784 1453 671 243 -111 -750 -878 -283 -305 -1297 -914 -1072 -163 -239 594 303 830 174 417 765 355 837 478 987 17 296 -5 423 387 -329 -574 54 1251 960 1615 771 1732 809 -11413 1063 1240 1532 1394 349 575 266 -661 351 -529 -259 -1123 79 -1764 -741 209 -641 -167 -209 -29 -483 280 -389 452 252 101 1 -454 82 33 121 -522 122 -253 351 355 226 -337 -520 136 345 -98 -833 396 -284 703 221 133 -28 -229 -795 -1301 278 -415 8 -656 823 614 308 159 903 456 845 1027 -288 -39 205 528 1079 1291 348 503 -581 -885 54 -323 1508 1033 855 841 33 -721 -463 -364 -1111 -268 -169 -393 -842 -162 -1470 89 -927 16 -119 -581 -1199 -135 -823 -1136 -745 359 464 852 1759 879 336 -150 -970 -1033 -326 -356 -1649 -1217 -1452 -229 -360 929 504 1387 282 647 1092 484 1148 691 1519 26 469 -8 648 567 -464 -794 72 1680 1410 2477 1260 2882 1357 -22060 1927 2343 2949 2730 688 1091 496 -1189 SU 20210407T131855.6Z 7767.554810 235 1 47.13 2 59.09 109.17 59.53 170.70 0.00 1 0.00 1 0 25 1.402e-02 5.135e-03 1.854e-03 4.015e-04 3.395683e-01 2.056036e-04 4.096649e-03 -6.000000e+00 8.133413e-03 227.96 -2.00 3.51 -2.00 317.83 0.00e+00 4.927069e-04 3.401162e-05 1.496564e-04 -6.000000e+00 3.522811e-04 279.41 -2.00 20.00 -2.00 317.19 0.00e+00 1.939 0.000 302.00 328.00 3 2.1743e+00 5.4645e-04 2.6309e-02 -6.0000e+00 2.0251e-02 1.0391e-02 6.1413e-04 1.7540e-02 -6.0000e+00 2.1896e-02 -5.1250e-03 3.9475e-04 8.7069e-03 -6.0000e+00 1.3008e-02 2.2728e-04 2.0527e-04 2.5073e-03 -6.0000e+00 5.6328e-03 5.4889e-03 -3.3331e-04 1.1346e-05 2.6934e-05 -6.0000e+00 3.8205e-04 -2.8939e-02 7.9082e-05 10 0 0 10 0 0 98.52 20.47 0.23 -0.02894 -0.03144 705 199 1 5 0 66.090 25.28 20.00 20.47 19.01 12.5 955.37 -2777 -3621 -3683 -6132 -5505 -6279 -3520 -2213 -2849 -3703 -4104 -2654 -1722 137 -772 -333 -134 463 373 628 18 129 489 399 67 -726 -881 -1188 -369 331 1023 1546 253 -1571 -2185 -1508 -1339 -65 -319 -652 -1010 -681 -735 -361 -117 -148 -617 -605 -358 523 727 876 1136 785 874 895 472 376 515 1030 1341 1650 1506 1028 -19 146 -98 719 973 552 242 61 79 -155 -48 -95 -347 -271 -296 -800 -958 -1567 -1745 -1273 -920 -590 -464 -127 -24 275 373 137 655 780 425 391 524 121 -107 -478 -619 -498 190 -335 -752 -711 -682 -359 88 290 114 253 61 203 208 515 342 255 61 -305 -104 130 230 495 485 101 655 671 308 180 -77 272 -43 239 -248 -87 183 -7 -372 -204 -456 -334 -185 -266 -275 -436 -353 -397 -235 -166 -238 -326 -365 -248 -185 17 -112 -53 -23 82 69 120 4 25 98 86 15 -174 -208 -266 -78 70 236 395 71 -419 -604 -413 -406 -21 -126 -299 -468 -330 -366 -181 -59 -74 -306 -296 -174 259 385 502 692 506 582 568 306 242 348 689 931 1151 1153 842 -16 111 -70 512 758 457 218 56 72 -136 -41 -74 -247 -188 -222 -689 -872 -1584 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