File name: Pandora135s1_ManhattanNY-CCNY_20210525_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20241023T083205.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v2d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20210525_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20210525 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20210525T134052.6Z 7815.570053 413 1 47.15 2 44.96 101.13 141.81 298.17 0.00 1 0.00 1 0 17 1.130e-02 1.215e-02 2.842e-03 1.485e-03 2.022636e-01 7.715856e-04 2.451287e-03 -6.000000e+00 6.637770e-03 231.69 -2.00 3.51 -2.00 316.02 0.00e+00 2.979381e-04 8.084696e-05 1.386865e-04 -6.000000e+00 2.900849e-04 284.55 -2.00 20.00 -2.00 315.32 0.00e+00 1.411 0.000 302.00 328.00 3 5.3560e+00 2.0141e-03 1.7695e-02 -6.0000e+00 1.6646e-02 6.9999e-02 2.2331e-03 1.0538e-02 -6.0000e+00 1.7941e-02 -2.0372e-02 1.2885e-03 5.1219e-03 -6.0000e+00 1.0658e-02 2.5719e-03 6.0000e-04 1.4169e-03 -6.0000e+00 4.5925e-03 4.7926e-04 3.2333e-04 4.2218e-05 1.7077e-05 -6.0000e+00 3.0831e-04 -1.7782e-02 1.4224e-04 12 9 8 11 8 0 99.95 20.95 0.40 -0.01778 -0.01535 53 15 1 5 0 889.450 25.68 20.00 20.95 23.06 13.3 983.49 -905 -1064 -3434 -3223 -1305 -1809 -715 2368 -1261 -1187 -2492 -406 571 837 -68 -1095 1267 416 1192 694 838 560 637 903 759 496 -670 70 -337 636 27 2178 679 -834 -1387 -821 16 361 54 -604 -408 -812 -853 -1393 -181 -625 -804 -1196 -458 552 410 1564 918 1128 943 1546 200 469 444 826 1360 1330 843 117 -297 -773 179 702 1339 523 575 77 258 -298 -369 -416 -1072 -611 -931 -670 -1280 -1341 -1792 -820 -632 -417 -233 -137 -203 -157 -187 -471 -142 499 369 684 866 382 138 -136 -596 -689 -98 -218 -983 -427 -821 -238 190 536 562 483 319 99 612 376 484 490 678 -15 17 112 222 596 417 259 252 970 626 629 249 902 690 -7779 563 536 896 597 340 306 -38 -514 -205 -255 -828 -704 -250 -339 -142 514 -308 -295 -612 -101 156 249 -23 -392 454 154 451 272 329 218 253 376 331 221 -293 28 -127 243 11 889 298 -366 -571 -349 7 185 32 -408 -284 -587 -628 -1030 -132 -451 -582 -839 -310 372 292 1169 701 892 762 1264 167 387 359 667 1138 1160 793 112 -283 -672 147 565 1168 501 574 79 263 -292 -344 -357 -866 -473 -770 -600 -1243 -1373 -1942 -897 -741 -506 -296 -173 -255 -192 -217 -508 -144 496 391 772 1046 492 179 -177 -740 -814 -112 -257 -1262 -556 -1121 -326 273 788 856 729 457 137 797 466 607 647 937 -22 25 161 308 807 553 325 311 1211 811 841 346 1264 986 -11957 844 840 1433 950 543 488 -58 -792 SU 20210525T135451.3Z 7815.579760 419 1 46.57 2 42.38 104.02 144.01 301.95 0.00 1 0.00 1 0 17 7.363e-03 5.380e-03 1.945e-03 1.138e-03 1.833408e-01 5.950423e-04 2.213357e-03 -6.000000e+00 4.326164e-03 231.69 -2.00 3.51 -2.00 315.60 0.00e+00 2.510572e-04 5.711515e-05 4.478422e-05 -6.000000e+00 1.890503e-04 284.55 -2.00 20.00 -2.00 314.94 0.00e+00 1.352 0.000 302.00 328.00 3 5.0502e+00 1.5463e-03 1.6607e-02 -6.0000e+00 1.0849e-02 3.7877e-02 1.7099e-03 9.5556e-03 -6.0000e+00 1.1693e-02 -3.2150e-03 9.8223e-04 4.6399e-03 -6.0000e+00 6.9465e-03 2.7168e-04 4.4967e-04 1.2888e-03 -6.0000e+00 2.9932e-03 7.2091e-04 1.3427e-04 3.2240e-05 1.5696e-05 -6.0000e+00 2.0093e-04 -1.7906e-02 1.4951e-04 11 1 0 11 8 0 99.96 20.96 0.27 -0.01791 -0.01690 51 14 1 5 0 912.930 25.68 20.00 20.96 23.68 13.3 988.49 155 -741 -2215 -2718 -1265 -1991 815 1450 -120 -1371 -639 -287 163 558 -213 -458 33 992 439 709 628 499 830 790 688 232 -350 145 155 505 1056 1676 771 -1369 -1296 -978 -702 -140 -311 -662 -1216 -956 -916 -651 -186 -470 -521 -783 -430 420 232 798 1111 681 869 979 125 411 598 950 1337 1622 1250 228 -249 -528 -168 421 836 395 345 236 278 61 184 -46 -495 -368 -606 -960 -1128 -1615 -1596 -946 -791 -525 -184 -68 105 135 213 28 199 435 201 383 365 234 89 -123 -470 -550 169 -507 -667 -566 -593 -355 110 333 204 273 133 -41 148 244 240 241 284 -143 122 206 284 717 452 133 583 501 236 251 -18 171 -91 -188 -156 -76 382 121 -306 -213 -370 -743 40 -206 -614 -688 -292 -449 192 381 -34 -396 -179 -82 51 190 -81 -185 14 414 190 304 271 221 361 361 329 114 -167 66 66 210 455 766 376 -672 -593 -446 -354 -80 -199 -468 -898 -728 -710 -503 -143 -367 -394 -571 -312 304 171 622 879 562 728 835 108 352 502 797 1164 1470 1188 227 -240 -475 -143 349 752 379 348 245 286 62 177 -41 -409 -300 -510 -882 -1122 -1705 -1728 -1040 -933 -644 -231 -87 133 167 248 30 206 442 212 431 442 295 116 -156 -567 -646 192 -599 -834 -726 -793 -479 155 483 299 406 188 -55 188 300 298 308 382 -200 175 289 396 947 583 166 712 621 304 334 -25 234 -126 -267 -229 -117 583 189 -479 -333 -560 -1115 SU 20210525T135847.8Z 7815.582498 422 1 43.67 2 41.66 104.87 144.62 303.08 0.00 1 0.00 1 0 17 7.212e-03 5.614e-03 6.636e-04 4.205e-04 1.792872e-01 2.207225e-04 2.184049e-03 -6.000000e+00 4.237506e-03 231.69 -2.00 3.51 -2.00 315.28 0.00e+00 2.276016e-04 1.991215e-05 3.260797e-05 -6.000000e+00 1.851777e-04 284.55 -2.00 20.00 -2.00 314.64 0.00e+00 1.337 0.000 302.00 328.00 3 3.1510e+00 5.7169e-04 1.6377e-02 -6.0000e+00 1.0627e-02 2.0977e-02 6.3120e-04 9.3837e-03 -6.0000e+00 1.1453e-02 -4.2353e-03 3.6238e-04 4.5589e-03 -6.0000e+00 6.8042e-03 9.4316e-04 1.6421e-04 1.2667e-03 -6.0000e+00 2.9318e-03 4.9655e-03 1.4627e-04 1.1887e-05 1.6264e-05 -6.0000e+00 1.9681e-04 -1.7722e-02 1.5346e-04 12 1 1 12 1 1 99.96 20.97 0.19 -0.01772 -0.01662 263 81 1 5 0 162.870 25.68 20.01 20.97 23.89 13.4 990.36 -475 -984 -1783 -2540 -1531 -682 810 1235 165 -1245 -935 -180 -2 874 85 -287 88 567 722 855 581 709 642 809 531 148 -170 -391 300 746 1477 1652 343 -1433 -1222 -963 -564 -103 -452 -873 -1010 -820 -914 -629 -409 -524 -817 -875 -388 433 541 744 1042 651 795 849 506 481 760 1030 1164 1361 1081 506 -378 -212 -178 700 969 411 290 -5 108 -79 -34 -133 -252 -186 -348 -836 -1107 -1619 -1669 -1193 -812 -608 -415 -183 -87 262 221 31 551 833 434 471 474 142 -65 -308 -525 -380 241 -302 -715 -606 -636 -328 101 259 146 234 61 128 244 508 317 353 250 -188 -122 130 192 584 487 176 770 727 397 244 -14 240 59 -728 -124 -40 273 -15 -300 -178 -449 -473 -139 -305 -547 -712 -414 -177 223 381 51 -398 -290 -57 -1 340 37 -122 38 250 327 398 273 329 304 401 277 79 -88 -188 145 351 721 792 176 -737 -585 -460 -298 -64 -310 -636 -789 -660 -750 -514 -332 -421 -637 -657 -281 312 409 596 873 568 662 718 434 408 674 914 1007 1263 1016 496 -360 -194 -160 612 862 413 296 -5 112 -79 -34 -117 -214 -151 -300 -761 -1123 -1688 -1833 -1293 -942 -714 -512 -230 -108 327 253 34 583 863 452 538 564 176 -83 -383 -641 -428 279 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