File name: Pandora135s1_ManhattanNY-CCNY_20210722_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20241023T091758.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v2d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20210722_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20210722 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210722T134421.7Z 7873.572474 290 1 42.06 2 46.63 100.93 153.00 295.05 0.00 1 0.00 1 0 17 7.926e-03 5.528e-03 2.902e-04 1.565e-04 2.125605e-01 8.177762e-05 2.565553e-03 -6.000000e+00 4.662303e-03 232.65 -2.00 3.51 -2.00 315.95 0.00e+00 2.784238e-04 8.604901e-06 7.131764e-05 -6.000000e+00 2.078909e-04 289.65 -2.00 20.00 -2.00 315.18 0.00e+00 1.454 0.000 302.00 328.00 3 9.5412e-01 2.1335e-04 1.8423e-02 -6.0000e+00 1.1698e-02 -6.4314e-03 2.3627e-04 1.1132e-02 -6.0000e+00 1.2598e-02 6.6235e-05 1.3603e-04 5.3910e-03 -6.0000e+00 7.5016e-03 -3.7161e-04 6.3212e-05 1.4792e-03 -6.0000e+00 3.2330e-03 3.7514e-02 -1.7711e-04 4.4393e-06 1.7808e-05 -6.0000e+00 2.1657e-04 -1.3450e-03 8.1895e-05 10 0 0 10 0 0 40.96 21.41 0.26 -0.00135 -0.00268 2212 624 1 5 0 18.500 26.11 20.00 21.41 28.46 15.2 1017.99 -321 -911 -1923 -3192 -2267 -1591 376 863 -254 -1810 -1346 -604 -148 677 142 -129 147 777 849 980 512 699 663 850 690 354 -114 -310 223 689 1487 1562 46 -1806 -1660 -1486 -890 -51 -251 -728 -889 -673 -780 -340 -289 -480 -749 -836 -440 365 560 759 993 626 780 829 481 414 609 1005 1192 1612 1449 756 -216 -256 -313 628 811 404 311 103 141 -74 -97 -371 -640 -552 -616 -938 -1164 -1686 -1662 -1139 -700 -458 -220 34 193 397 256 -13 442 577 208 469 536 232 -31 -304 -615 -568 94 -539 -744 -692 -610 -363 120 326 251 368 136 129 132 341 261 201 180 -90 126 303 382 649 474 24 538 499 304 188 15 161 -38 -317 -187 6 270 21 -269 -218 -487 -514 -74 -223 -466 -709 -450 -310 78 202 -65 -476 -347 -162 -41 209 49 -47 55 300 339 402 212 287 259 350 298 156 -49 -134 90 277 628 709 21 -812 -756 -686 -424 -29 -156 -478 -624 -488 -576 -250 -212 -349 -530 -573 -294 246 398 574 787 517 617 668 392 334 482 798 990 1440 1312 713 -197 -226 -256 510 726 384 317 108 145 -73 -93 -320 -537 -451 -543 -876 -1142 -1805 -1768 -1271 -792 -553 -278 41 245 476 298 -14 452 587 229 535 642 304 -40 -397 -744 -670 109 -668 -946 -923 -806 -499 173 472 376 544 191 174 171 425 330 270 248 -131 177 437 534 862 631 30 686 619 405 252 20 228 -55 -458 -287 8 421 33 -428 -336 -762 -777 SS 20210722T135114.0Z 7873.577246 294 1 42.04 2 45.36 102.31 154.10 297.21 0.00 1 0.00 1 0 17 7.811e-03 5.548e-03 2.784e-04 1.540e-04 2.075714e-01 8.057519e-05 2.509210e-03 -6.000000e+00 4.595007e-03 232.65 -2.00 3.51 -2.00 315.85 0.00e+00 2.878967e-04 8.296112e-06 6.842855e-05 -6.000000e+00 2.048920e-04 289.65 -2.00 20.00 -2.00 315.08 0.00e+00 1.421 0.000 302.00 328.00 3 9.6338e-01 2.1022e-04 1.8008e-02 -6.0000e+00 1.1530e-02 -5.6831e-03 2.3299e-04 1.0886e-02 -6.0000e+00 1.2416e-02 1.8718e-06 1.3372e-04 5.2734e-03 -6.0000e+00 7.3933e-03 3.4277e-05 6.1680e-05 1.4474e-03 -6.0000e+00 3.1863e-03 3.8730e-02 -1.7223e-04 4.3658e-06 1.7497e-05 -6.0000e+00 2.1345e-04 -1.1435e-03 8.3571e-05 10 0 0 10 0 0 58.72 21.43 0.27 -0.00114 -0.00244 2214 624 1 5 0 18.480 26.11 20.00 21.43 28.98 15.3 1021.76 -294 -804 -1857 -3037 -2303 -1393 429 798 -178 -1732 -1410 -618 -52 651 173 -136 163 741 829 1021 477 745 669 854 668 306 -141 -240 279 778 1378 1541 150 -1759 -1747 -1436 -872 -78 -300 -748 -864 -702 -771 -376 -323 -477 -752 -811 -480 366 564 800 972 627 808 813 456 445 601 1019 1186 1557 1446 730 -164 -245 -340 614 823 384 309 115 143 -67 -89 -353 -653 -563 -653 -947 -1168 -1681 -1637 -1133 -716 -448 -190 38 212 387 248 -12 403 542 207 435 541 242 -33 -334 -621 -574 58 -553 -757 -702 -643 -360 140 345 269 386 176 117 125 338 233 175 175 -63 140 297 340 637 469 52 566 484 305 222 6 195 -45 -316 -172 20 269 13 -285 -207 -490 -540 -72 -191 -475 -711 -483 -286 94 196 -48 -439 -382 -174 -15 211 63 -52 64 298 344 402 190 294 272 365 300 140 -63 -99 117 322 602 666 70 -813 -757 -629 -426 -45 -192 -505 -623 -522 -584 -284 -243 -355 -545 -569 -327 251 409 616 785 495 650 666 378 365 484 823 1003 1416 1331 700 -152 -219 -283 505 745 369 319 115 149 -67 -82 -308 -555 -466 -546 -894 -1156 -1814 -1755 -1274 -816 -544 -242 47 270 468 290 -12 415 555 228 500 651 302 -42 -437 -754 -680 67 -652 -966 -892 -853 -496 193 500 404 572 246 158 163 420 296 235 241 -88 197 430 476 847 624 66 683 601 406 298 8 274 -64 -455 -263 30 418 21 -451 -319 -765 -814 SS 20210722T135629.8Z 7873.580900 297 1 41.76 2 44.39 103.39 154.93 298.95 0.00 1 0.00 1 0 17 7.713e-03 5.543e-03 2.650e-04 1.488e-04 2.041149e-01 7.790803e-05 2.467083e-03 -6.000000e+00 4.536978e-03 232.65 -2.00 3.51 -2.00 315.79 0.00e+00 2.973895e-04 7.912892e-06 6.421519e-05 -6.000000e+00 2.023069e-04 289.65 -2.00 20.00 -2.00 315.02 0.00e+00 1.397 0.000 302.00 328.00 3 9.2214e-01 2.0322e-04 1.7708e-02 -6.0000e+00 1.1384e-02 -6.8405e-03 2.2508e-04 1.0705e-02 -6.0000e+00 1.2260e-02 1.2777e-04 1.2921e-04 5.1859e-03 -6.0000e+00 7.3001e-03 8.2491e-05 5.9427e-05 1.4241e-03 -6.0000e+00 3.1459e-03 4.1596e-02 -1.7362e-04 4.2271e-06 1.7410e-05 -6.0000e+00 2.1077e-04 -9.1874e-04 8.0402e-05 10 0 0 10 0 0 51.97 21.44 0.27 -0.00092 -0.00222 2316 653 1 5 0 17.550 26.11 20.00 21.44 29.34 15.3 1023.37 -308 -734 -1740 -2978 -2021 -1361 545 833 -51 -1782 -1214 -621 31 661 233 -207 154 738 685 1007 447 783 657 896 696 302 -160 -353 308 699 1439 1556 70 -1808 -1725 -1543 -813 -78 -298 -741 -893 -726 -813 -331 -345 -463 -799 -797 -508 370 561 787 984 611 806 824 439 405 593 1013 1188 1530 1405 743 -228 -225 -336 582 809 433 314 119 144 -62 -91 -337 -635 -562 -656 -943 -1195 -1684 -1622 -1150 -707 -431 -188 27 208 403 245 0 403 582 211 459 512 255 -33 -328 -604 -570 40 -552 -766 -708 -594 -402 115 340 271 378 149 116 103 323 222 181 173 -77 101 311 351 655 472 56 543 472 315 192 14 191 -40 -338 -172 53 263 28 -283 -204 -488 -528 -78 -180 -421 -720 -437 -288 123 211 -14 -466 -338 -165 9 220 86 -81 62 304 269 406 182 316 273 391 319 141 -73 -149 131 296 640 684 33 -850 -759 -688 -404 -42 -193 -507 -653 -548 -625 -254 -263 -349 -587 -566 -351 257 412 613 803 487 655 683 368 335 482 826 1014 1405 1305 719 -213 -202 -282 483 737 418 326 120 151 -62 -84 -296 -542 -467 -551 -894 -1188 -1724 -1746 -1298 -810 -526 -228 34 253 489 288 0 416 597 220 529 617 318 -43 -408 -734 -676 46 -652 -979 -902 -790 -555 158 494 407 560 208 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